Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. An industrial chemist studying this reaction fills a 1.5 L flask with 0.59 atm of sulfur dioxide gas and 2.9 atm of oxygen gas at 35.0 °C. He then raises the temperature, and when the mixture has come to equilibrium measures the partial pressure of sulfur trioxide gas to be 0.53 atm.
Calculate the pressure equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. Round your answer to 2 significant digits.
Kp=_______.

Answer:

The balanced equation is: Zn(s) + 2H⁺(aq) → Zn²⁺(aq) + H₂(g)

Explanation:

Zn(s) is a simple substance (its oxidation number is zero) and it is oxidized to Zn²⁺. It loses two electrons, so the half reaction is the following:

Zn(s) → Zn²⁺(aq) + 2 e-   (oxidation reaction)

Hydrogen ion (H⁺) is reduced to hydrogen gas (H₂). The oxidation number is decreased from +1 to 0 (because H₂ is a simple substance). H⁺ gains 1 electron per H atom, so the half reaction is the following:

2H⁺(aq) + 2 e- → H₂(g) (reduction reaction)

We obtain the overall reaction from the addition of the two half reactions. We write the reduction reaction first and then the oxidation reaction, as follows:

2H⁺(aq) + 2 e- → H₂(g)

+

Zn(s) → Zn²⁺(aq) + 2 e-

---------------------------------

Zn(s) + 2H⁺(aq) → Zn²⁺(aq) + H₂(g)

The two electrons at both sides of the equation (2 e-) are canceled. The overall reaction is in acidic solution due to the presence of H⁺ ions. The net charge at both sides is the same : +2, so the mass and the charge are balanced.

Answer:

For carbon, the effective nuclear charge is 3.25 and the valence electrons will reside in the orbitals 2s^2 and 2p^2

For silicon, the effective nuclear charge is 4.15 and its valance electrons will reside in the orbitals 3s^2 and 3p^2

Explanation:

Carbon

The effective nuclear charge of carbon is 3.25

To get the orbitals in which it’s valence electron reside, let’s write the electronic configuration

The atomic number of carbon is 6

So the configuration will be;

1s^2 2s^2 2p^2

So the valence electrons will reside in the orbitals 2s^2 and 2p^2

For silicon;

It’s effective nuclear charge is +4.15

The electronic configuration of silicon with atomic number 14 is;

1s^2 2s^2 2p^6 3s^2 3p^2

So the valence electrons will reside in the orbitals 3s^2 and 3p^2

Answer:

b) rate = kAB.

Explanation:

Hello,

In this case, considering the given statement, we can notice that the rate law of the overall reaction will be determined for the slowest step, that is:

[tex]A+B \rightarrow AB\ \ (slow)[/tex]

In such a way, we can infer that the rate law will contain both the concentration of A and B to the first power both, since their stoichiometric coefficients in the chemical equation are both one:

[tex]rate=k[A][B][/tex]

Thereby, answer is b) rate = kAB, that should be better rate = k[A][B] by expressing the concentrations.

Best regards.

Answer:

D

Explanation:

Double Displacement reaction

Both sides are balanced with option D

The balanced form of the chemical equation shown below is [tex]\rm Ca(OH)_2(aq) + Na_2CO_3(aq) \rightarrow CaCO_3(s) + 2NaOH(aq).[/tex] The correct option is D.

A balanced equation is where the reactant and the product have the number of moles of elements. According to the law, the reaction, and the product have the same number of moles after the reaction, so balancing an equation is important.

To balance an equation, it is significant to see the number of moles of reactant and the same number of moles is in the product side. Here the moles of sodium has to be balanced.

Thus, the correct option is D, [tex]\rm Ca(OH)_2(aq) + Na_2CO_3(aq) \rightarrow CaCO_3(s) + 2NaOH(aq).[/tex]

Learn more about the balanced equation, here:

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Answer:

21.2 mL

Explanation:

Step 1: Write the balanced equation.

NaOH + HBr ⇒ NaBr + H₂O

Step 2: Calculate the reacting moles of HBr

25.0 mL of 0.0720 M hydrobromic acid react.

[tex]0.0250 L \times \frac{0.0720mol}{L} = 1.80 \times 10^{-3} mol[/tex]

Step 3: Calculate the reacting moles of NaOH

The molar ratio of NaOH to HBr is 1:1. The reacting moles of NaOH are 1/1 × 1.80 × 10⁻³ mol = 1.80 × 10⁻³ mol.

Step 4: Calculate the required volume of NaOH

[tex]1.80 \times 10^{-3} mol \times\frac{1,000mL}{0.0850mol} = 21.2 mL[/tex]

Radiologists are medical doctors that treat injuries using medical imaging (radiology)

Answer:

a person who uses X-rays or other high-energy radiation, especially a doctor specializing in radiology.

Explanation:

Answer:

2284.2 g.

Explanation:

The following data were obtained from the question:

Percentage yield = 47%

Theoretical yield = 4860 g

Actual yield =?

The percentage yield is simply defined as the ratio of actual yield to the theoretical yield multiplied by 100. Mathematically, it is expressed as:

Percentage yield = Actual yield /Theoretical yield x 100

With the above formula, we can obtain the actual yield as follow:

Percentage yield = Actual yield /Theoretical yield x 100

47% = Actual yield /4860

Cross multiply

Actual yield = 47% × 4860

Actual yield = 47/100 x 4860

Actual yield = 2284.2 g

Therefore, the actual yield is 2284.2 g.

Answer:

A) linear / linear

Explanation:

In this case, we have a triple bond beetween the atoms (See figure 1). If we have this triple bond we will have an Sp hybridization (in both carbons). We have to remember the relationship between the geometry and the hybridization:

-) Sp3 = Tetrahedral

-) Sp2 = Trigonal

-) Sp = Linear

Due to the hybridization, we will have a linear structure between the atoms. The angle between the atoms is 180º (See figure 2).

So, if we have a hybridization Sp for both carbons, we will have a linear geometry in each carbon. Therefore, the answer is A.

Answer:

A

Explanation:

If we intend to achieve the anti addition of Hex-3-yne to yield (E) Hex-3-ene, the we must use Na/NH3. The first step of the reaction involves the transfer of an electron from sodium to the alkene; this yields a radical anion. Strong electron replusion ensues between the single electron and the lone pair on the carbon. This now forces the both to be found at a trans position to each other and this is the basis of the stereochemistry of the product.

Secondly, the radical anion abstracts a proton from ammonia. Another sodium atom transfers an electron leading to the formation of a vinyl carbanion, the alkyl groups are now trans to each other.

This carbanion now abstracts a proton from ammonia and the final product is formed.

Answer:

The correct answers are:

c. The concentrations of the products decrease

d. The equilibrium constant decreases

Explanation:

Changes in temperature shift the equilibrium. In this problem, the reaction is endothermic, so it absorbs heat so heat is considered as a reactant:

Reactants + heat ⇒ Products

If the temperature is decreased, the heat is decreased, so reactants are removed from the reaction at equilibrium. According to Le Chaterlier's principle, the system will try to compensate the produced change. If reactants are removed, the systems will form reactants and the equilibrium will shift toward the left (formation of more reactants). In consequence, the amount of products will be decreased.

Thus, acorrect option is: c. The concentrations of the products decrease.

Since the equilibrium constant is given by the ratio of concentration of products over concentration of reactants, if the concentration of products decrease, the equilibrium constant also decreases. So, another correct option is: d. The equilibrium constant decreases.

Answer:

Explanation:

The given formula is empirical formula

Let the molecular formula of first be

[tex]( CCl )_n[/tex]

molecular weight = n x ( 12 + 35.5 )

= 47.5 n

Given molecular weight = 189.83 so

47.5 n = 189.83

n = 3.99 or 4 approx

Molecular formula =

[tex]( CCl )_4[/tex]

= C₄ Cl₄

Let the molecular formula of second compound  be

[tex]( C_3H_2N)_n[/tex]

molecular weight = n x ( 3 x 12 +2+14 )

= 52 n

Given molecular weight = 156.23  so

52 n = 156.23

n = 3.0044 or 3 approx

Molecular formula =

[tex]( C_3H_2N )_3[/tex]

= C₉H₆ N₃

Answer:

35%

Explanation:

Percentage yield = actual yield / theoretical yield × 100.

Given:

Actual yield = 63.07g

Theoretical yield = ?

Mole ratio of C7H6O3 to C4H6O3 = 1 : 1

1 mole of C7H6O3 - 138.1g

Which implies that only 1 mole s[tex]\frac{63.07}{180.2} * 100[/tex]hould be used up in the reaction, yielding 180.2 g of C9H8O4. ⇒ Theoretical yield = 180.2g

∴ % Yield = [tex]\frac{63.07}{180.2} * 100[/tex]

= 35% yield.

Let me know if you found this easy to understand.

Answer:

The Empirical Formular is given as; Ti₆Al₄V

Explanation:

The percent composition of the material is 64.39% titanium, 24.19% aluminum, and 11.42% vanadium.

Elements                        Titanium            Aluminium        Vanadium

Percentage                    64.39                 24.19                   11.42

Divide all through by their molar mass

                                     64.39 / 47.87      24.19 / 27               11.42 / 50.94

                                       =  1.345                = 0.896                 = 0.224

Divide all though  by the smallest number (0.224)

                                     1.345 / 0.224        0.896 / 0.224       0.224 / 0.224

                                     = 6                         = 4                             = 1

The Empirical Formular is given as; Ti₆Al₄V

Using the stepwise procedure for obtaining the empirical formula of a compound, the empirical formula is [tex] T_{6}Al_{4}V[/tex]

Titanium :

Divide by Molar mass : = 64.39/47.87 = 1.345

Aluminum :

Divide by Molar mass : = 24.19/27 = 0.896

Vanadium :

Divide by Molar mass : = 11.42/50.94 = 0.224

Divide by the smallest :

Titanium = 1.345 / 0.224 = 6.00

Aluminum = 0.896 / 0.224 = 4

Vanadium = 0.224 / 0.224 = 1

Hence, the empirical formula is [tex] T_{6}Al_{4}V[/tex]

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Answer:

question is not clear please send clear question

Answer:

[tex]\boxed{\sf Option \ E}[/tex]

Explanation:

All the gases at the same temperature and mass have the same average kinetic energy.

If the masses were different, then the different gases will have different velocities. If the temperature was higher then there would be a greater motion, if the temperature was lower, then there would be less motion.

Answer:

option E

Explanation:

Answer:

4NH₃(g)  + 5O₂(g)  →  4NO(g)  +  6H₂O

2NO(g) + O₂(g) → 2 NO₂

Explanation:

First of all, we need to consider the reaction for production of ammonia. In this reaction we have as reactants, nitrogen and hydroge.

3H₂ (g) +  N₂(g)  →  2NH₃ (g)

Afterwards, ammonia reacts to oxygen, to produce NO and H₂O

The equation for the process will be:

4NH₃(g)  + 5O₂(g)  →  4NO(g)  +  6H₂O

Then, we take the nitric oxide to make it react, to produce NO₂, in order to produce nitric acid, for the final reaction:

2NO(g) + O₂(g) → 2 NO₂

3NO₂(g) + H₂O(g) → 2 HNO₃ (g) + NO(g)

Answer:

r = k [X]²

Explanation:

X + Y → Z

Generally, the rate of reaction depends on the concentration of reactants. However, the question stated that the rate depends only on reactant X.

The plot of 1/X versus time giving a straight line signifies that this is a second order reaction.

For a second-order reaction, a plot of the inverse of the concentration of a reactant versus time is a straight line with a slope of k.

From this, our rate law is r = k [X]²

The question is incomplete, the complete question is;

What is the purpose of reacting 2.0mL of HNO3 with 2.0 mL of H2SO4 in a separate test tube, prior to adding it to the solution containing the substrate? more than one answer is possible

A) The release of a water molecule that acts as an electrophile in the reaction with methyl benzoate.

B) The formation of nitronium ion, which acts an electrophile in the reaction with methylbenzoate.

C)The formation of bisulfate (hydrogen sulfate), which acts as an electrophile in the reaction with methylbenzoate.

D)The release of a water molecule that acts as a nucleophile in the reaction with methyl benzoate.

Answer:

B) The formation of nitronium ion, which acts an electrophile in the reaction with methylbenzoate.

Explanation:

The benzene ring is known to be stable hence it can only undergo a substitution reaction with the aromatic ring still intact. When the substitution reaction involves an electrophile we refer to the process as electrophillic aromatic substitution. Electrophilic aromatic substitution is a useful synthetic route for many organic compounds.

In the electrophilic substitution of methyl benzoate using the 1:1 volume ratio mixture of H2SO4/HNO3, the nitronium ion (NO2+) is the electrophile generated in the test tube. It is this NO2+ that now reacts with the methyl benzoate to yield the reaction product.

Answer:

An addiction could occur, maybe an overdose?, this could lead to death and maybe you would do unreasonable things which could get you fined or arrested.

Explanation:

Answer:

Hope this helped,

Kavitha

Answer:

Chemical reaction B governs the process

Explanation:

The first part of the question asks to convert the mass of the calcium carbonate given to number of moles.

Mathematically;

Number of moles = mass/molar mass

Molar mass of CaCO3 = 100 g/mol

So the number of moles of CaCO3 will be 2.49/100 = 0.0249 moles

The second part of the question asks to convert the mass of carbon iv oxide to moles of carbon iv oxide

Mathematically;

That is same as ;

Number of moles = mass/molar mass

molar mass of CO2 is 44 g/mol

Number of moles of CO2 = 1.13/44 = 0.0256 moles

Now, if we compare the values of these number of moles, we can see that there are almost equal.

What this means is that the number of moles of calcium carbonate reacted is equal to the number of moles of carbon iv oxide produced.

So what we conclude here is that we have an equal mole ratio between the two compounds.

So the reaction that would be the correct answer will present equal number of moles of carbon iv oxide and calcium carbonate

Thus, we can see that reaction B is the one that governs this process as it is the only reaction out of the three options that present the two compounds with equal number of moles.

Answer:

Vapor pressure of water = 23.14torr

Explanation:

When you made a solution, vapor pressure decreases following Raoult's law:

[tex]P_{solution} = X_{solvent} P_{solvent}[/tex]

Where P is vapor pressure and X mole fraction

As vapor pressure of water is 23.77torr we must find the mole fraction of water knowing the solution is 1.500m glucose (That is 1.500 moles of glucose per kg of water = 1000g of water).

1000g of H₂O are, in moles (Molar mass: 18.02g/mol):

1000g H₂O ₓ (1mole / 18.02g) = 55.5 moles of H₂O.

As we know now the solution contains 55.5 moles of water and 1.5 moles of glucose. Thus, mole fraction of water (Solvent) is:

[tex]X_{H_2O} = \frac{55.5molesH_2O}{55.5molesH_2O + 1.5 molesGlucose} = 0.9737[/tex]

Replacing in Raoult's law, pressure of water above the solution is:

[tex]P_{solution} = X_{solvent} P_{solvent}[/tex]

[tex]P_{solution} = 0.9737*23.77torr[/tex]

Answer:

∆H=  438 KJ/mol

Explanation:

First, we have to find the energy bond values for each compound:

-) Cl-Cl = 243 KJ/mol

-) F-F = 159 KJ/mol

-) F-Cl = 193 KJ/mol

If we check the reaction we can calculate the number of bonds:

[tex]Cl_2_(_g_)~+~3F_2_(_g_)~->~2ClF_3_(_g_)[/tex]

In total we will have:

-) Cl-Cl = 1

-) F-F = 3

-) F-Cl = 6

With this in mind. we can calculate the total energy for each bond:

-) Cl-Cl = (1*243 KJ/mol) = 243 KJ/mol

-) F-F = (3*159 KJ/mol) = 477 KJ/mol

-) F-Cl = (6*193 KJ/mol) = 1158 KJ/mol

Now, we can calculate the total energy of the products and the reagents:

Reagents = 243 KJ/mol + 477 KJ/mol = 720 KJ/mol

Products = 1158 KJ/mol

Finally, to calculate the total enthalpy change we have to do a subtraction between products and reagents:

∆H= 1158 KJ/mol-720 KJ/mol = 438 KJ/mol

I hope it helps!

The approximate enthalpy change is:

∆H=  438 KJ/mol

First, we have to find the energy bond values for each compound:

Cl-Cl = 243 KJ/mol

F-F = 159 KJ/mol

F-Cl = 193 KJ/mol

Balanced chemical reaction:

Cl₂ (g) + 3F₂ (g) ⟶ 2ClF₃ (g)

Total number of bond for each:

Cl-Cl = 1

F-F = 3

F-Cl = 6

Total bond energy will be:

Cl-Cl = (1*243 KJ/mol) = 243 KJ/mol

F-F = (3*159 KJ/mol) = 477 KJ/mol

F-Cl = (6*193 KJ/mol) = 1158 KJ/mol

Now, we can calculate the total energy of the products and the reactants:

Reactants = 243 KJ/mol + 477 KJ/mol = 720 KJ/mol

Products = 1158 KJ/mol

Finally, to calculate the total enthalpy change we have to do a subtraction between products and reagents:

∆H= 1158 KJ/mol-720 KJ/mol = 438 KJ/mol

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Answer:

Benzoic acid: 1.288g

Sodium benzoate: 124.48g

Explanation:

Benzoic acid, HC7H5O2 is in equilibrium with its conjugate base, C7H5O2⁻ producing a buffer. The pH of the buffer can be determined following H-H equation:

pH = pKa + log [C7H5O2⁻] / [HC7H5O2] (1)

Where pH is desire pH = 6.10 pKa is -log Ka = 4.187 and [] are molar concentrations of the buffer.

As you want to prepare 2.5L of a 0.35M of buffer, moles of buffer are:

2.5L ₓ (0.35mol / L) = 0.875moles of buffer.

And you can write:

0.875 moles = [C7H5O2⁻] + [HC7H5O2] (2)

Replacing (2) in (1)

pH = pKa + log [C7H5O2⁻] / [HC7H5O2]

6.10 = 4.187 + log [C7H5O2⁻] / [HC7H5O2]

1.913 =  log [C7H5O2⁻] / [HC7H5O2]

81.846 = 0.875mol - [HC7H5O2] / [HC7H5O2]

81.846 [HC7H5O2] = 0.875mol - [HC7H5O2]

82.846 [HC7H5O2] = 0.875mol

And moles of the benzoate, [C7H5O2⁻]:

[C7H5O2⁻] = 0.875mol - 0.01056mol =

Using molar mass of benzoic acid and sodium benzoate, amount of each compound you must add to prepare 2.5L of the buffer are:

Benzoic acid: 0.01056mol ₓ (122.01g/mol) = 1.288g

Sodium benzoate: 0.8644mol ₓ (144.01g/mol) = 124.482g

Answer:

53.1% of hydrogen reacts

Explanation:

The mixture of 2 atoms of H with 1 atom of O produce 1 molecule of H₂.

The mass of hydrogen in 2.32g of H₂O could be obtained using molar mass of H₂O (18.01g/mol) and molar mass of hydrogen (1.01g/mol) as follows:

Moles H₂O: 2.32g H₂O × (1mole / 18.01g) = 0.1288 moles of water

1 mole of H₂O contains 2 moles of H, moles of hydrogen in 0.1288 moles of water are:

0.1288 moles H₂O × (2 moles H / 1 mole H₂O) = 0.2576 moles of H

In mass:

0.2576 moles H × (1.01g/ mol H) = 0.260g H you have in the formed water

As before reaction you had 0.485g of H and just 0.260g reacted, mass percent is:

(Mass that reacts / Mass added) × 100

(0.260g / 0.485g) × 100 =

Answer:

V2 = 4.48L

Explanation:

using charles law

V1/T1=V2/T2

3.4/283=V2/373

0.012=V2/373

V2= 0.012 x 373

V2 = 4.48L

Answer:

C. To determine how efficient reactions are.

D. To determine how much reactant they need.

Explanation:

When you are doing a reaction, you are hoping for a percent yield to close of 100%. You make the reaction and determine how many product you obtain. If you know the percent yield of a reaction you can calculate the amount of reactant you need to obtain a determined amount of product.

Having this in mind:

A. To balance the reaction equation.  false. To calculate percent yield you need to balance the reaction before. You don't use percent yield to balance the reaction

B. To determine how much product they will need.  false. You determine how much product you obtain after the reaction. How much product you need is independent of percent yield

C. To determine how efficient reactions are.  true. A way to determine efficience of a reaction is with percent yield. An efficient reaction has a high percent yield.

D. To determine how much reactant they need. true. If you know percent yield of a reaction you can know how many reactant you must add to obtain  the amount of product you want.

Answer:

592 K or 319° C

Explanation:

From the statement of Charles law we know that the volume of a given mass of gas is directly proportional to its absolute temperature at constant pressure. Thus;

V1/T1= V2/T2

Initial volume V1 = 1.75 L

Initial temperature T1= 23.0 +273 = 296 K

Final volume V2= 3.50 L

Final temperature T2 = the unknown

T2= V2T1/V1= 3.50 × 296 / 1.75

T2 = 592 K or 319° C

Answer:

1. 6.92 g of H2O

2i. - 46 KJ of energy.

ii. Option A. Evolved.

Explanation:

1. Determination of the mass of H2O that would be made to react if 110 kJ of energy were provided.

This can be obtained as follow:

The equation for the reaction is given below

2H2O(l) —> 2H2(g) + O2(g) H = 572 kJ

Next, we shall determine the mass of H2O required to produce 572 kJ from the balanced equation.

Molar mass of H2O = (2x1) + 16 = 18 g/mol

Mass of H2O from the balanced equation = 2 x 18 = 36 g

From the balanced equation above, 36 g of H2O reacted to produce 572 kJ of energy.

Finally, we shall determine the mass of water (H2O) needed to produce 110 kJ of energy.

This is illustrated below:

From the balanced equation above, 36 g of H2O reacted to produce 572 kJ of energy.

Therefore, Xg of H2O will react to 110 kJ of energy i.e

Xg of H2O = (36 x 110)/572

Xg of H2O = 6.92 g

Therefore, 6.92 g of H2O is needed to react in order to produce 110 KJ of energy.

2i. Determination of the energy.

The balanced equation for the reaction is given below:

CO(g) + 3H2(g) —> CH4(g) + H2O(g) H = -206 kJ

Next, we shall determine the mass of CO that reacted to produce -206 kJ of energy from the balanced equation.

This is illustrated below:

Molar mass of CO = 12 + 16 = 28 g/mol

Mass of CO from the balanced equation = 1 x 28 = 28 g

From the balanced equation above,

28 g of CO reacted to produce -206 kJ of energy.

Finally, we shall determine the amount of energy produced by reacting 6.27 g of CO. This is illustrated below:

From the balanced equation above,

28 g of CO reacted to produce -206 kJ of energy.

Therefore, 6.27 g of CO will react to produce = (6.27 x -206)/28 = - 46 KJ of energy.

Therefore, - 46 KJ of energy were produced from the reaction.

2ii. Since the energy obtained is negative, it means heat has been given off to the surroundings.

Therefore, the heat is evolved.