The SNArreaction requires 1 mmol methyl 4-fluoro-3-nitrobenzoateand 2 mmol of 4-chlorobenzyl amine. Calculate the mass (mg) of both reagents.(2

Answer:

The mass number of the stable daughter product is 208

Explanation:

First thing's first, we have to write out the equation of the reaction. This is given as;

²³²₉₀Th → 6 ⁴₂α  +  4 ⁰₋₁ β + X

In order to obtain the identity of X, we have to obtain it's mass numbers and atomic number.

There is conservation of matter so we expect the mass number to remain the same in both the reactant and products.

Mass Number

Reactant = 232

Product = (6* 4 = 24) + (4 * 0 = 0) + x = 24 + x

since reactant = product

232 = 24 + x

x = 232 - 24 = 208

Atomic Number

Reactant = 90

Product = (6* 2 = 12) + (4 * -1 = -4) + x = 8 + x

since reactant = product

90 = 8 + x

x = 90 - 8 = 82

Answer:

Lewis acid- Fe3+

Lewis base- water molecule

Explanation:

Acids and bases have been defined in diverse ways. There have been definitions put forward by Arrhenius, Brownstead and Lowry as well as Lewis. Each definition his useful in its own way.

Lewis acids are lone pair acceptors such as metal ions. This implies that in the particular instance of this reaction, Fe3+ is the lewis acid.

Similarly, a Lewis base is a lone pair donor, all ligands are lone pair donors since they donate one or more lone pairs of electrons to Lewis acids. In the particular instance of this reaction, the Lewis base is the water molecule.

The branch of science which deals with the chemicals bond is called chemistry.

The correct answer is Lewis acid [tex]Fe^{3+[/tex]  and the lewis base is a water molecule.

Those chemicals which release the H+ ion when reacting with water are called acids. Those chemicals which release OH- ion, when reacted with the water is called a base. These definitions are given by the Lewis

Lewis acids are lone pair acceptors such as metal ions. This implies that in the particular instance of this reaction, Fe3+ is the lewis acid.

Similarly, a Lewis base is a lone pair donor, all ligands are lone pair donors since they donate one or more lone pairs of electrons to Lewis acids. In the particular instance of this reaction, the Lewis base is the water molecule.

Hence, the correct answer is Fe3+.

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Answer:

it will decrease

Explanation:

force of gravity is inversely proportional to the distance

Answer:

It shall decrease! -w-ll

Explanation:

because of the gravitational pull

Answer:

Explanation:

Let the monoprotic acid be HX

HX ⇄ H⁺ + X⁻

pH = 2.53

Hydrogen ion concentration

[tex][ H^+]=10^{-2.53}[/tex]

[tex][ X^-]=10^{-2.53}[/tex]

Concentration of undissociated acid will remain almost the same as it is a weak acid

So

Ka = concentration of H⁺ x concentration of Cl⁻ / concentration of acid

=  [ H⁺] x [Cl⁻ ] / [ HX]

[tex]k_a=\frac{10^{-2.53}\times 10^{-2.53}}{.0166}[/tex]

[tex]k_a=\frac{.00295^2}{.0166}[/tex]

= 5.24 x 10⁻⁴ M .

Answer:

NH4Br + AgNO3 —> AgBr + NH4NO3

Explanation:

When ammonium bromide and silver(I) nitrate react, the following are obtained as shown below:

NH4Br(aq) + AgNO3(aq) —>

In solution, NH4Br(aq) and AgNO3(aq) will dissociate as follow:

NH4Br(aq) —> NH4+(aq) + Br-(aq)

AgNO3(aq) —> Ag+(aq) + NO3-(aq)

The double displacement reaction will occur as follow:

NH4+(aq) + Br-(aq) + Ag+(aq) + NO3-(aq) —> Ag+(aq) + Br-(aq) + NH4+(aq) + NO3-(aq)

NH4Br(aq) + AgNO3(aq) —> AgBr(s) + NH4NO3(aq)

Answer:

reduces the greenhouse effect

Answer:

1. b.) The wavelength gets shorter as the frequency increases  

2. X-rays < Ultraviolet radiation < Visible light < Infrared radiation

3. 2 × 10⁵ J

Explanation:

1. Wavelength vs frequency

fλ= c

f = c/λ

Thus, frequency and wavelength are inversely proportional.

The wavelength increases (gets longer) as the frequency decreases.

2. Order of increasing wavelength

X-rays < Ultraviolet radiation < Visible light < Infrared radiation  

3. Energy of green light

(a) Energy of 1 photon

λ = 5 × 10² nm = 5  × 10² × 10⁻⁹ m = 5 × 10⁻⁷ m

fλ = c

f = c/λ = (2.998 × 10⁸ m·s⁻¹)/(5 × 10⁻⁷ m) = 6 × 10¹⁴ s⁻¹

E = hf = 6.626 × 10⁻³⁴ J·s × 6 × 10¹⁴ s⁻¹ = 4 × 10⁻¹⁹ J

(b) Energy  of 1.0 mol of photons

[tex]\text{Energy} = \text{1.0 mol photons} \times \dfrac{6.022 \times 10^{23}\text{ photons }}{\text{1 mol photons }} \times \dfrac{4 \times 10^{-19}\text{ J}}{\text{1 photon }} = \mathbf{2 \times 10^{5}} \textbf{ J}\\\\\text{The energy of 1.0 mol of photons of green light is $\large \boxed{\mathbf{2 \times 10^{5}}\textbf{ J}}$}[/tex]

Note: The answer can have only one significant figure because that is all you gave for the wavelength of the light.

B. it means the compound is dissolved in water

Answer:

b

Explanation:

a p e x :)

Answer:

0.0590 M⁻¹

Explanation:

Kc represents the equilibrium constant. It is given as;

Kc = [products] / [reactants]

For the reaction; 2SO2(g) + O2(g) <--> 2SO3

Products = SO3

Reactants = SO2 and O2

Kc is given as;

Kc = [SO3]² / [SO2]² [O2]

Kc = 0.120² / (0.860)² (0.330)

Kc = 0.0144 / 0.2440 = 0.0590 M⁻¹

Answer:

0.3 mol

Explanation:

Assuming HCl is in excess and Zn is the limiting reagent,

from the balanced equation, we can see the mole ratio of Zn:H2 = 1:1,

which means, each mole of zinc reacted gives 1 mole of H2.

So, if 0.30 mol Zn is added, the no. of moles of H2 produced will also be 0.3 mol, since the ratio is 1:1.

Answer:

The given statement is false.

Explanation:

So that the given is incorrect.

Answer:

filtration, drying, and weighing

Explanation:

The procedures that would facilitate the measurement of the actual yield of the solid would be filtration of the precipitate, drying of the precipitate, and weighing of the precipitate respectively.

The liquid/solid mixture resulting from the reaction can be separated by the process of filtration using a filter paper. The residue in the filter paper would be the solid while the filtrate would be the liquid portion of the reaction's product.

The residue can then be allowed to dry, and then weighed using a laboratory-grade weighing balance. The weight of the solid represents the actual yield of the solid.

Answer:

Option B. S

Explanation:

All of the options except sulphur, S is metal.

Metals tend to lose electron in order to form ion. Non metals on the other hand gain electron to form ion.

Sulphur, S has atomic number of 16 with electronic configuration as:

S (16) => 1s² 2s²2p⁶ 3s²3p⁴

From the above illustration, we can see that sulphur needs two more electrons to complete it's octet configuration.

Therefore, sulphur, S will gain two electrons to form ion.

As stated earlier, the rest option given are all metals which will form ion by losing electron(s).

Answer

B) Sulphur (S)

Explanation

Here in the options we have been provided with elements like Nickel (Ni), Sulphur (S), Sodium (Na), Chromium (Cr) and Beryllium (Be) but except for Sulphur all the other ones are metals.

Now, let us understand what is a metal and a non-metal.

So, sulphur being the only non metal will accept electron to complete its octate and to stablize itself and form a Anion.

Now let us also look at the electronic configuration of Sulphur to get the picture more clearly

        [tex]S\rightarrow 1s^2\; 2s^2\;2p^6\;3s^2\;3p^4[/tex]

so here the p-subshell is incomplete and is in need of 2 electrons.

Therefore the element which is most likely to gain electrons, forming an Anion will be sulphur.

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Answer:

The reaction given in the question is:  

2CH₃OH (l) + 3O₂ (g) ⇒ 2CO₂ (g) + 4H₂O (g)

The values of ΔH°formation and ΔS° of the reactants and products given in the reaction based on the thermodynamics data is:

ΔH°formation values of CH3OH (l) is -238.4 kJ/mol, CO2(g) is -393.52 kJ/mol, H2O (g) is -241.83 kJ/mol and O2 (g) is 0.  

The S° values of CH3OH (l) is 127.19 J/molK, CO2(g) is 213.79 J/molK, H2O (g) is 188.84 J/moleK, and O2 (g) is 205.15 J/molK.  

Now the values of ΔH° and ΔS° are,  

ΔH°rxn = 2 * ΔH°formation CO2 (g) + 4 * ΔH°formation H2O (g) - 2*ΔH°formation CH3OH (l)

ΔH°rxn = 2 * (-393.52) + 4 (-241.83) -2 * (-238.4)

ΔH°rxn = -1277.56 kJ/mole

ΔS°rxn = 2 * S° CO2 (g) + 4 * S° H2O (g) - 2*S° CH3OH (l) - 3 * S° O2 (g)

ΔS°rxn = 2 * 213.79 + 4 * 188.84 - 2 * 127.19 - 3*205.15

ΔS°rxn = 313.11 J/mole/K

Now the formula for calculating ΔG°rxn is,  

ΔG°rxn = ΔH°rxn - TΔS°rxn

ΔG°rxn = -1277.56 * 1000 J/mole - 298 * 313.11 J/mole

ΔG°rxn = -1370.86 kJ/mol

Answer:

a) Specific Rotation of (R)-carvone = -61°

b) The enantiomeric excess of (R)-carvone in the mixture = 90.2%

c) The percentage of (S)-carvone in the mixture = 4.9%

Explanation:

a) The specific rotation of the enantiomer of a substance is given simply as the negative of the specific rotation of that substance.

Hence, the specific rotation of (R)-carvone is simply the negative of the specific rotation of (S)-carvone.

Specific Rotation of (R)-carvone = -(61°) = -61°

b) Enantiometic excess is used to measure the optical purity of an enantiomeric mixture.

The enantiomeric excess is given mathematically as

ee% = (Observed rotation × 100)/(Specific rotation)

Hence, to calculate the enantiomeric excess of (R)-carvone,

Observed rotation of the mixture = -55°

Specific Rotation of (R)-carvone = -61°

ee% = (-55×100)/(-61) = 90.16% = 90.2%

c) An enantiomeric excess of 90.2% for (R)-carvone indicates that it's actual percentage is 90.2% more than the percentage of its enantiomeric partner, (S)-carvone, in the mixture.

Let the percentage of (R)-carvone in the mixture be x

Let the percentage of (S)-carvone in the mixture be y

x + y = 100

x - y = 90.2

2x = 190.2

x = (190.2/2) = 95.1%

y = 100 - x = 100 - 95.1 = 4.9%

Hence, the percentage of (R)-carvone in the mixture = 95.1%

The percentage of (S)-carvone in the mixture = 4.9%

Hope this Helps!!!

a) Specific Rotation of (R)-carvone = -61°

b) The enantiomeric excess of (R)-carvone in the mixture = 90.2%

c) The percentage of (S)-carvone in the mixture = 4.9%

The specific rotation of the enantiomer of a substance is given simply as the negative of the specific rotation of that substance.

Hence, the specific rotation of (R)-carvone is simply the negative of the specific rotation of (S)-carvone.

Specific Rotation of (R)-carvone = -(61°) = -61°

b) Calculation for Enantiomeric excess:

The enantiomeric excess is given mathematically as

ee% = (Observed rotation × 100)/(Specific rotation)

Hence, to calculate the enantiomeric excess of (R)-carvone,

Observed rotation of the mixture = -55°

Specific Rotation of (R)-carvone = -61°

ee% = (-55×100)/(-61) = 90.16% = 90.2%

c) Calculation of percentage:

Let the percentage of (R)-carvone in the mixture be x

Let the percentage of (S)-carvone in the mixture be y

x + y = 100

x - y = 90.2

2x = 190.2

x = (190.2/2) = 95.1%

y = 100 - x = 100 - 95.1 = 4.9%

Hence, the percentage of (R)-carvone in the mixture = 95.1%

The percentage of (S)-carvone in the mixture = 4.9%

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Answer:

The osmotic pressure of ocean water is about 27 atm.

Explanation:

Pure water is water that contains no impurities. Ocean water is 96.5% pure with only about 3.5% of its content, salt water.

Osmotic pressure occurs when solutions that have different concentrations are isolated by a membrane. This osmotic pressure makes water move towards the solution that has the highest concentration, which means that if the concentration or temperature of the solution is high, the osmotic pressure becomes higher.

The equation for osmotic pressure is pi = iMRT.

Answer:

It will take 6486.92 minutes  for [H2O2] to fall from 0.95 M to 0.33 M

Explanation:

The order of reaction is defined as the sum of the powers of the concentration terms in the equation. Order of a reaction is given by the number of atoms or molecule whose concentration change during the reaction and determine the rate of reaction.

In first order reaction;

[tex]In \dfrac{a}{a_o-x}= k_1 t[/tex]

where;

a = concentration at time t

[tex]a_o[/tex] = initial concentration

and k = constant.

[tex]In (\dfrac{0.33}{0.95})= -1.63 \times 10^{-4} \times t[/tex]

[tex]-1.05736933 = -1.63 \times 10^{-4} \times t[/tex]

[tex]t = \dfrac{-1.05736933}{ -1.63 \times 10^{-4} }[/tex]

t = 6486.92 minutes

Answer:

71.1

Explanation:

1 mol Fe = 10.4 g/55.85 g/mol = 0.186

1 mol AgNo3 = 28.4 g/169.87 g/mol = 0.178 mol AgNo3

then since Ag:Fe is 1:3, AgNo3 is the limiting reactant

So now

0.178 moles * 1/3 * 241.83 g/mol Fe(NO3)3 = 14.35 g Fe(NO3)3

Excess reactant: 0.178 moes AgNO3 * 1/3 = 0.059

0.186 - 0.059 = 0.127 moles Fe * 55.85 g/mol Fe = 7.1 g Fe excess

The given question is incomplete, the complete question is:

A chemistry student weighs out 0.0349g of formic acid HCHO2 into a 250.mL volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with 0.1500M NaOH solution. Calculate the volume of NaOH solution the student will need to add to reach the equivalence point. Round your answer to 3 significant digits.

Answer:

The correct answer is 5.06 ml.

Explanation:

Based on the given information, the weight of formic acid given is 0.0349 grams. The volume of formic acid of V1 given is 250 ml. The molecular mass of formic acid is 46 grams per mole. Now the molarity of formic acid will be,  

[HCOOH] = weight * 1000 / molecular mass * volume (ml)

= 0.0349 * 1000 / 46 * 250

= 0.003035 M or M1

The molarity of NaOH given is 0.1500 M or M2

Let us assume that the volume needed to attain equivalence point is V2 ml.  The volume V2 can be determined by using the dilution equation,  

M1V1 = M2V2

V2 = M1V1/M2  

V2 = 0.003035 * 250 / 0.1500

V2 = 5.06 ml.  

Hence, the volume of NaOH needed is 5.06 ml.  

Answer:

[tex]\boxed{From \ +6 \ to \ 0}[/tex]

Explanation:

2 Fe2O3(s) + 3 C(s) → 4 Fe(s) + 3 CO2(g)

In the given reaction, Iron in the reactants side have the oxidation number of +6. This is because [tex]O_{3}[/tex] with [tex]Fe_{2}O_{3}[/tex] has oxidation state -6, So any atom with it would have an oxidation state of +6 to give the resultant of zero.

In the products side, Iron acts as a free element reacting with no other atom. So, as per the rule of oxidation states, the oxidation state of Iron in the products side will be zero.

So, the oxidation number changes from +6 to 0 .

Extra Info: Decrease in oxidation state is Reduction , So Iron is being reduced here.

The change in the oxidation number of the iron atom in the reaction is from +3 to 0

Oxidation is simply defined as the the loss of electron. However, Oxidation number simply talks about the number of electrons that is either gained or lossed during bond formation.

The change in the oxidation number of iron in the reaction can be obtained as follow:

2Fe₂O₃(s) + 3C(s) → 4Fe(s) + 3CO₂(g)

Oxidation number of Fe₂O₃ = 0 (ground state)

Oxidation number of oxygen = –2

Fe₂O₃ = 0

2Fe + 3O = 0

2Fe + 3(–2) = 0

2Fe – 6 = 0

Collect like term

2Fe = 6

Divide both side by 2

Fe = 6/2

Thus, the oxidation number of Fe in Fe₂O₃ is +3

Therefore, the change in the oxidation number of the iron, Fe, atom in the reaction is from +3 to 0

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Answer:

[tex]7.48X10^3~mL[/tex]

Explanation:

For this question we have:

-) A solution NaOH 0.25 M

-) 500 g of glyceryl tripalmitoleate (tripalmitolein)

We can start with the reaction between NaOH and tripalmitolein. NaOH is a base and tripalmitolein is a triglyceride, therefore we will have a saponification reaction. The products of this reaction are glycerol and (E)-hexadec-9-enoate.

Now, with the reaction in mind, we can calculate the moles of NaOH that we need if we use the molar ratio between NaOH and tripalmitolein (3:1) and the molar mass of tripalmitolein (801.3 g/mol). So:

[tex]500~g~tripalmitolein\frac{1~mol~tripalmitolein}{801.3~g~tripalmitolein}\frac{3~mol~NaOH}{1~mol~tripalmitolein}=1.87~mol~NaOH[/tex]

With the moles of NaOH we can calculate the volume (in litters) if we use the molarity equation and the Molarity value:

[tex]M=\frac{mol}{L}[/tex]

[tex]0.25~M=\frac{1.87~mol~NaOH}{L}[/tex]

[tex]L=\frac{1.87~mol~NaOH}{0.25~M}[/tex]

[tex]L=7.48[/tex]

Now we can do the conversion to mL:

[tex]7.48~L~\frac{1000~mL}{1~L}=~7.48X10^3~mL[/tex]

I hope it helps!

Answer:

Three isomers of hexane are: 2-methylpentane, 3-methylpentane, and 2,3-dimethylbutane.

They are constitutional isomers because they each contain exactly the same number and type of atoms, in this case, six carbons and 14 hydrogens and no other atoms.

Explanation:

Hope it helps.

Answer:

P SO₂ = 0.06atm

P O₂ = 2.635atm

P SO₃ = 0.53atm

Kp = 29.6

Explanation:

The reaction of Sulfur dioxide and oxygen react to form sulfur trioxide is as follows:

2SO₂(g) + O₂(g) ⇄ 2SO₃(g)

And Kp is defined as:

[tex]Kp = \frac{P_{SO_3}^2}{P_{SO_2}^2P_{O_2}}[/tex]

Where P represents the pressure at equilibrium of each reactant.

If you add, in the first, 0.59atm of SO₂ and 2.9atm of O₂, the equilibrium pressures will be:

P SO₂ = 0.59atm - 2X

P O₂ = 2.9atm - X

P SO₃ = 2X

Where X represents the reaction coordiante.

As equilibrium pressure of SO₃ is 0.53atm:

0.53atm = 2X

0.265atm = X

Replacing, equilibrium pressures of each species will be:

P SO₂ = 0.59atm - 2×0.265atm

P O₂ = 2.9atm - 0.265atm

P SO₃ = 2×0.265atm

And Kp will be:

[tex]Kp = \frac{P_{SO_3}^2}{P_{SO_2}^2P_{O_2}}[/tex]

[tex]Kp = \frac{0.53^2}{{0.06}^2*{2.635}}[/tex]

Answer: C. Metals tend to easily lose their valence electrons.

Explanation:

Metals are those substances which have tendency to loose their valence electrons to attain noble gas configuration and forms positive ions called as cations.

Example: Gold, potassium etc

[tex]M\rightarrow M^++e^-[/tex]

Non metals are those substances which have tendency to gain valence electrons to attain noble gas configuration and form negative ions called as anions.

Example: Sulphur, Chlorine

[tex]N+e^-\rightarrow N^-[/tex]

Answer:

[tex][OH^-]=0.01165M[/tex]

Explanation:

Hello,

In this case, for the dissociation of methylamine:

[tex]CH_3NH_2(aq)+H_2O(l)\rightleftharpoons CH_3NH_3^+(aq)+OH^-(aq)[/tex]

We can write the basic dissociation constant as:

[tex]Kb=\frac{[CH_3NH_3^+][OH^-]}{[CH_3NH_2]}[/tex]

That in terms of the reaction extent [tex]x[/tex], turns out:

[tex]Kb=\frac{x*x}{[CH_3NH_2]_0-x}[/tex]

[tex]4.4x10^{-4}=\frac{x^2}{0.32M-x}[/tex]

That has the following solution for [tex]x[/tex]:

[tex]x_1=-0.01209M\\x_2=0.01165M[/tex]

Yer 0.01165M is valid only as no negative concentrations are eligible. It means that it is the concentration of hydroxyl ions in the solution:

[tex][OH^-]=0.01165M[/tex]

Best regards.

Answer:

I think its B

Explanation:

Precipitation reactions leave a solid behind. The solid is called a precipitate.

Answer:

B

Explanation:

An insoluble solid will form when ions in dissolved compounds switch places.

Answer:

CH3CH=NH2+>CH3CH2NH3+

Explanation:

If we look at the both species under review, we will realize that they are both amines hence they possess the polar N-H bond.

Electrons are ordinarily attracted towards the nitrogen atom hence making both compounds acidic. It is worthy of note that certain features of a compound may make it more acidic than another of close structural proximity. 'More acidic' simply means that the proton is more easily lost.

CH3CH=NH2+ contains an sp2 hybridized carbon atom which is highly electronegative and further withdraws electron density from the N-H bond thereby leading to a greater acidity of CH3CH=NH2+ compared to CH3CH2NH3+

Answer:76 grams

Explanation:

Fe+H₂SO₄-->FeSO₄+H₂

For one mole of Fe we get 1 mole of feso4, therefore for 0.5 moles of Fe we get 0.5 moles of feso4.

The molar mass of feso4 is AFe+AS+4AO(A is atomic mass)

56+32+4*16=152grams/mole

Now, we need to multiply the number of moles by the molar mass to get the mass that reacts

152*0.5=76 grams

Answer:

Osmolarity of solution of KCI = 0.40 osmol

Explanation:

Given:

KCL ⇒ K⁺ + Cl⁻

Find:

Osmolarity of solution of KCI

When M = 0.20 M

Computation:

1 mole of KCL = 2 osmol

1 M of KCl = 2 Osmolarity

So,

Osmolarity of solution of KCI = 2 × 0.20

Osmolarity of solution of KCI = 0.40 osmol