Given the initial rate data for the reaction being A + B + C --> D determine the rate expression for the reaction and the (k) rate constant. (The units of [A] [B] and [C] are all moles/liter and the units of IRR is moles/liter seconds). If the [A]=[B]=[C]=.30M, what would the IRR be? [A] [B] [C] IRR 0.20 0.10 0.40 .20 0.40 0.20 0.20 1.60 0.20 0.10 0.20 .20 0.20 0.20 0.20 .80

Answers

Answer 1

Answer:

k = 100 mol⁻² L² s⁻¹, r= k[A][B]²

Explanation:

A + B + C --> D

[A] [B] [C] IRR

0.20 0.10 0.40 .20

0.40 0.20 0.20 1.60

0.20 0.10 0.20 .20

0.20 0.20 0.20 .80

Comparing the third and fourth reaction, the concentrations of A and C are constant. Doubling the concentration of B causes a change in the rate of the reaction by a factor of 4.

This means the rate of reaction is second order with respect to B.

Comparing reactions 2 and 3, the concentrations of B and C are constant. Halving the concentration of A causes a change in the rate of the reaction by a factor of 2.

This means the rate of reaction is first order with respect to A.

Comparing reactions 1 and 3, the concentrations of A and B are constant. Halving the concentration of A causes no change in the rate of the reaction.

This means the rate of reaction is zero order with respect to C.

The rate expression for this reaction is given as;

r = k [A]¹[B]²[C]⁰

r= k[A][B]²

In order to obtain the value of the rate constant, let's work with the first reaction.

r = 0.20

[A] = 0.20 [B] = 0.10

k = r / [A][B]²

k = 0.20 / (0.20)(0.10)²

k = 100 mol⁻² L² s⁻¹


Related Questions

For carbon: What is the effective nuclear charge? In which orbitals do the valence electrons reside? For silicon: What is the effective nuclear charge? In which orbitals do the valence electrons reside?

Answers

Answer:

For carbon, the effective nuclear charge is 3.25 and the valence electrons will reside in the orbitals 2s^2 and 2p^2

For silicon, the effective nuclear charge is 4.15 and its valance electrons will reside in the orbitals 3s^2 and 3p^2

Explanation:

Carbon

The effective nuclear charge of carbon is 3.25

To get the orbitals in which it’s valence electron reside, let’s write the electronic configuration

The atomic number of carbon is 6

So the configuration will be;

1s^2 2s^2 2p^2

So the valence electrons will reside in the orbitals 2s^2 and 2p^2

For silicon;

It’s effective nuclear charge is +4.15

The electronic configuration of silicon with atomic number 14 is;

1s^2 2s^2 2p^6 3s^2 3p^2

So the valence electrons will reside in the orbitals 3s^2 and 3p^2

The vapor pressure of pure water at 250C is 23.77 torr. What is the vapor pressure of water above a solution that is 1.500 m glucose, C6H12O6?

Answers

Answer:

Vapor pressure of water = 23.14torr

Explanation:

When you made a solution, vapor pressure decreases following Raoult's law:

[tex]P_{solution} = X_{solvent} P_{solvent}[/tex]

Where P is vapor pressure and X mole fraction

As vapor pressure of water is 23.77torr we must find the mole fraction of water knowing the solution is 1.500m glucose (That is 1.500 moles of glucose per kg of water = 1000g of water).

1000g of H₂O are, in moles (Molar mass: 18.02g/mol):

1000g H₂O ₓ (1mole / 18.02g) = 55.5 moles of H₂O.

As we know now the solution contains 55.5 moles of water and 1.5 moles of glucose. Thus, mole fraction of water (Solvent) is:

[tex]X_{H_2O} = \frac{55.5molesH_2O}{55.5molesH_2O + 1.5 molesGlucose} = 0.9737[/tex]

Replacing in Raoult's law, pressure of water above the solution is:

[tex]P_{solution} = X_{solvent} P_{solvent}[/tex]

[tex]P_{solution} = 0.9737*23.77torr[/tex]

Vapor pressure of water = 23.14torr

1. Rank the following compounds in order of decreasing acid strength using periodic trends. Rank the acids from strongest to weakest.
A. HCl
B. H2S
C. HBr
D. BH3
2. Without consulting the table of acid-dissociation constants, match the following acids to the given Ka1 values.
1. H2S
2. H2SO3
3. H2SO4
A. Kal = 1.7 x 10^-7
B. Kal = 1.7 x 10^-2
C. Kal = very large

Answers

Answer:

ESCALAS MAYORES (D, E, G, A, B) Porfavor necesito ayuda,te lo agradecería muchísimo!!

Es urgente

BeH2 has no lone pairs of electrons. What's the structure of this molecule?

Answers

The shape of BeH2 is linear.

Answer:

linear

Explanation:

nothing bends off

A student is given an antacid tablet that weighs 5.8400 g. The tablet is crushed and 4.2800 g of the antacid is added to 200. mL of simulated stomach acid. It is allowed to react and then filtered. It is found that 25.00 mL of this partially neutralized stomach acid required 11.6 mL of a NaOH solution to titrate it to a methyl red end point. It takes 29.0 mL of this NaOH solution to neutralize 25.00 mL of the original stomach acid. How much of the original 200. mL of stomach acid (in mL) is neutralized by the 4.2800 g crushed sample of the tablet

Answers

Answer:

Explanation:

Given that:

mass of the antacid tablet = 5.8400 g

required mass of the antacid tablet = 4.2800 g was added to 200. mL of simulated stomach acid.

The amount of the  original 200. mL of stomach acid (in mL) needed to  neutralize the 4.2800 g crushed sample of the tablet can be calculated as:

= 11.6 mL of NaOH × 25.00 mL /29.0 mL NaOH

= 10.00 mL original stomach acid

Now; since it requires 11.6  mL of  NaOH o neutralize 10.00 mL of  original acid , then:

the antacid neutralized = 200 mL - 10.00 mL

the antacid neutralized = 190.00 mL

Write the condensed formula from left to right, starting with (CH3)x where x is a number.

Answers

Complete question:

Write the condensed formula from left to right, starting with (CH3)x where x is a number.

See attached image for the structure formula of the compound

Answer:

(CH₃)₂CHC(CH₃)₃ named as 2,2,3-Trimethylbutane

Explanation:

If we number the longest chain of the carbon starting from the left, we will observe that there are four carbons in the straight chain as shown in the image.

Starting from first carbon from the left of the carbon chain, at carbon number number 2, there two alkyl group, that is two methyl (CH3 is two). Also at carbon number 3, there are three alkyl group, that is three methyl (CH3 is three).

The condensed formula will be written as;

(CH₃)₂CHC(CH₃)₃

This compound is named as 2,2,3-Trimethylbutane, an isomer of Heptane

Which of the following reagents should be used to convert to Question 2 options: A) Na, NH3 B) H2, Pt C) H2, Lindlar's catalyst D) HgSO4, H2O

Answers

Answer:

A

Explanation:

If we intend to achieve the anti addition of Hex-3-yne to yield (E) Hex-3-ene, the we must use Na/NH3. The first step of the reaction involves the transfer of an electron from sodium to the alkene; this yields a radical anion. Strong electron replusion ensues between the single electron and the lone pair on the carbon. This now forces the both to be found at a trans position to each other and this is the basis of the stereochemistry of the product.

Secondly, the radical anion abstracts a proton from ammonia. Another sodium atom transfers an electron leading to the formation of a vinyl carbanion, the alkyl groups are now trans to each other.

This carbanion now abstracts a proton from ammonia and the final product is formed.

what is the differences between amorphous solid and crystalline solid​

Answers

Answer:

Crystalline solids have well-defined edges and faces, diffract x-rays, and tend to have sharp melting points.

 In contrast, amorphous solids have irregular or curved surfaces, do not give well-resolved x-ray diffraction patterns, and melt over a wide range of temperatures.

This substituent deactivates the benzene ring towards electrophilic substitution but directs the incoming group chiefly to the ortho and para positions.
A) -F
B) -OCH2CH3
C) -CF3
D) -NHCOCH3
E) -NO2

Answers

Answer:

F

Explanation:

Halogens may interact with the benzene ring via inductive or resonance effects. Halogens deactivate the benzene ring by inductive effect rather than by resonance effects.

The lone pairs of electrons present on the halogen atoms may be donated to the ring by resonance, but an opposite effect, the inductive pull (-I inductive effect) of the halogen atoms on electrons away from the benzene ring due to the high electro negativity of the halogens leads to a deactivation of the ring towards electrophilic substitution.

Hence inductive electron withdrawal by the halogen atom predominates over electron donation by resonance effect and the benzene ring g is deactivated towards electrophilic substitution at the ortho and para positions.

what bsic difference is between NMR and MS spectroscopic techniques?​

Answers

Answer:

The Nuclear magnetic resonance is the process this technique does not use radiation.

The  ms is an sensitive technology can be a massive number and small sample of the blood.

Explanation:

The Nuclear magnetic resonance we look at the both side of that coin.

The technique provides that fatty acid composition and various including amino acids.

These are contain the complementary these biomarkers, that are suitable for all kinds of studies. there are many types of research:-

(1) A powerful tool metabolic (2) A versatile tool research (3) Quick analysis (4) Low cost analysis.

The MS is an extremely sensitive technology using a very small number of the blood.

(1) Powerful techniques (2) Highly method (3) Large number of metabolites (4)Small sample volume

MS can be fine mapping metabolic pathways to sign analytical strategy.

Stote 4 ways in which excesine alcohol conscuption is
harmful to humans​

Answers

Answer:

An addiction could occur, maybe an overdose?, this could lead to death and maybe you would do unreasonable things which could get you fined or arrested.

Explanation:

Answer:

Excessive alcohol is harmful because you could get addicted.Alcohol can affect your nervous system.Your sugar levels will not be good.Parts of your body and organs will become inflamed.You can get a larger amount of muscle cramps.Also you will not be able to get enough vitamins in your body.Accidents that lead to deaths could occur.You would do crazy actions with things such as theft or breaking into a house which could get you fined or arrested.Too much alcohol can lead to high blood pressure, disease and even strokes.You can have birth defectsWith excessive alcohol you can get osteoporosis.You can also get your immune system weakened.Finally, alcohol can lead to cancer.

Hope this helped,

Kavitha

Ethane burns according to the following reaction: 2C2H6 + 7O2 → 4CO2 + 6H2O + 2.86 x 103 kJ How much heat can be generated when 185 grams of oxygen gas (MW = 32 g/mol) are consumed?

Answers

Answer:

question is not clear please send clear question

Find the molecular formula of each compound CCl , 189.83 g/mol C3H2N , 156.23 g/mol

Answers

Answer:

Explanation:

The given formula is empirical formula

Let the molecular formula of first be

[tex]( CCl )_n[/tex]

molecular weight = n x ( 12 + 35.5 )

= 47.5 n

Given molecular weight = 189.83 so

47.5 n = 189.83

n = 3.99 or 4 approx

Molecular formula =

[tex]( CCl )_4[/tex]

= C₄ Cl₄

Let the molecular formula of second compound  be

[tex]( C_3H_2N)_n[/tex]

molecular weight = n x ( 3 x 12 +2+14 )

= 52 n

Given molecular weight = 156.23  so

52 n = 156.23

n = 3.0044 or 3 approx

Molecular formula =

[tex]( C_3H_2N )_3[/tex]

= C₉H₆ N₃

Which equation best represents the net ionic equation for the reaction that occurs when aqueous solutions of potassium phosphate and iron(II) nitrate are mixed? Question 8 options: 3Fe2+(aq) + 2PO43–(aq) → Fe3(PO4)2(s) 2K+(aq) + Fe(NO3)2(aq) → 2KNO3(aq) + Fe2+(aq) 3Fe2+(aq) + 2PO43–(aq) → Fe3(PO4)2(aq) 2K3PO4(aq) + 3Fe2+(aq) → Fe3(PO4)2(s) + (K+)6(aq) 2K3PO4(aq) + 3Fe(NO3)2(aq) → Fe3(PO4)2(s) + 6KNO3(aq)

Answers

Answer:

2PO₄³⁻ + 3Fe²⁺ → Fe₃(PO₄)₂(s)

Explanation:

In a net ionic equation you list only the ions that are participating in the reaction.

When potassium phosphate, K₃PO₄, reacts with iron (II) nitrate, Fe(NO₃)₂ producing iron (II) phosphate, Fe₃(PO₄)₂ that is an insoluble salt. The reaction is:

2K₃PO₄ + 3 Fe(NO₃)₂ → Fe₃(PO₄)₂(s) + 6NO₃⁻ + 6K⁺

The ionic equation is:

6K⁺ + 2PO₄³⁻ + 3Fe²⁺ + 6NO₃⁻→ Fe₃(PO₄)₂(s) + 6NO₃⁻ + 6K⁺

Subtracting the K⁺ and NO₃⁻ ions that are not participating in the reaction, the net ionic equation is:

2PO₄³⁻ + 3Fe²⁺ → Fe₃(PO₄)₂(s)

what is radiologist​

Answers

Radiologists are medical doctors that treat injuries using medical imaging (radiology)

Answer:

a person who uses X-rays or other high-energy radiation, especially a doctor specializing in radiology.

Explanation:

Limiting Reagent

1.) A student chose the wrong result of the two calculations of BaSO4, namely, the higher value. What would you expect to happen to the value of the % yield? Explain.

2.) In the process of filtration, what do you think has happened to the excess reagent which has not reacted? Where does it go, and do you think you could recover it, if needed? Explain.

Answers

Answer:

a) the percentage yield will exceed 100%

b) the excess reactant is filtered along with the barium sulphate precipitate. It is possible to recover the excess reactant by carefully washing the precipitate with water.

Explanation:

In the precipitation of barium sulphate, the ions in the reactants exchange partners in the product leading to an insoluble product.

In every reaction, there is a limiting reactant whose amount determines the amount of product that can be obtained. The reactant in excess remains in the system even after the reaction is completed and may be recovered alongside the product which leads to a percentage yield above 100%.

If the excess reactant is soluble in water, it can be recovered from the precipitate if needed by washing the precipitate with water.

If 50 ml of 1.00 M of H2SO4 and 50 ml of 2.0 M KOH are mixed what is the concentration of the resulting solutes?

Answers

Answer:

0.5 M

Explanation:

First, let us look at the balanced equation of the reaction.

[tex]H_2SO_4 + 2KOH --> K_2SO_4 + 2H_2O[/tex]

The solute formed is [tex]K_2SO_4[/tex].

Recall that: mole = molarity x volume

Hence,

50 ml, 1.00 M H2SO4 = 0.05 x 1 = 0.05 mole

50 ml, 2.0 M KOH = 0.05 x 2 = 0.1 mole

From the equation

1 mole of H2SO4 reacts with 2 moles of KOH to give 1 mole of K2SO4.

Hence,

0.05 mole H2SO4 reacting with 0.1 mole KOH will give 0.05 mole [tex]K_2SO_4[/tex].

Also recall that: concentration = mole/volume

Total volume of resulting solution = 50 ml + 50 ml = 100 ml or 0.1 liter

Concentration of [tex]K_2SO_4[/tex] = mole of [tex]K_2SO_4[/tex]/volume of resulting solution

                              = 0.05/0.1 = 0.5 M

The concentration of the resulting solute = 0.5 M

A 1.2 L weather balloon on the ground has a temperature of 25°C and is at atmospheric pressure (1.0 atm). When it rises to an elevation where the pressure is 0.71 atm, then the new volume is 1.8 L. What is the temperature (in °C) of the air at this elevation?

Answers

Answer: 44.37 degrees C

Explanation:

Use combined gas law: (P1)(V1)/T1=(P2)(V2)/T2

For most gas laws, you  must convert to Kelvin:

K=deg C+273

K=25+273=298 K

Plug and chug:

(1.0 atm)(1.2 L)/(298 K)=(0.71 atm)(1.8 L)/(x)

Solve for x and get 317.37 K

Subtract 273 from this to convert to degrees Celsius. You will get 44.37 degrees Celsius.

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Not all bonds are "created equal". From the following molecules, which one contains the most easily broken carbon to carbon bond? Group of answer choices H3C—CH3 F2C=CF2 H2C=CH2 HCCH

Answers

Answer:

H3C—CH3

Explanation:

The strength of a bond is indicated by the value of its bond dissociation energy. Simply put, the bond dissociation energy is the energy required to break the bond.

Carbon forms single, double and triple bonds with itself. As a matter of fact, carbon atoms can link to each other indefinitely. This is known as catenation and has been attributed to the low bond energy of the carbon-carbon single bond.

The bond energy of the carbon-carbon single bond is about 90KJmol-1 while that of carbon-carbon double bond is about 174KJmok-1. The carbon-carbon triple bond has the highest bond dissociation energy of about 230KJmol-1.

Hence, it is easier to break carbon-carbon single bonds than double and triple bonds respectively, hence the answer.

According to the forces of attraction, the molecule which can be easily broken is CH₃-CH₃ as it has a single bond with low dissociation energy as compared to double or triple bonds.

Forces of attraction is a force by which atoms in a molecule  combine. it is basically an attractive force in nature.  It can act between an ion  and an atom as well.It varies for different  states  of matter that is solids, liquids and gases.

The forces of attraction are maximum in solids as  the molecules present in solid are tightly held while it is minimum in gases  as the molecules are far apart . The forces of attraction in liquids is intermediate of solids and gases.

The physical properties such as melting point, boiling point, density  are all dependent on forces of attraction which exists in the substances.Single bonds have least dissociation energy while triple bonds have the maximum  dissociation energy.

Thus,the molecule which can be easily broken is CH₃-CH₃.

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what mass of calcium nitrate can be prepared by the reaction of 18.9 grams of nitric acid with 7.4 grams of calcium hydroxide

Answers

Answer:

16.4 grams of calcium nitrate can be prepared by the reaction of 18.9 grams of nitric acid with 7.4 grams of calcium hydroxide

Explanation:

The balanced reaction is:

Ca(OH)₂ + 2 HNO₃ → Ca(NO₃)₂ + 2 H₂O

First, you must determine the limiting reagent. The limiting reagent is one that is consumed first in its entirety, determining the amount of product in the reaction. When the limiting reagent is finished, the chemical reaction will stop.

To determine the limiting reagent, it is possible to use the reaction stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction):

Ca(OH)₂: 1 moleHNO₃: 2 molesCa(NO₃)₂: 1 mole H₂O : 2 moles

Being:

Ca: 40 g/moleO: 16 g/moleH: 1 g/moleN: 14 g/mole

Then, the molar mass of the compounds participating in the reaction is:

Ca(OH)₂: 40 g/mole + 2*(16 g/mole + 1 g/mole)= 74 g/moleHNO₃: 1 g/mole + 14 g/mole + 3*16 g/mole= 63 g/moleCa(NO₃)₂: 40 g/mole + 2*(14 g/mole + 3*16 g/mole)= 164 g/moleH₂O : 2*1 g/mole + 16 g/mole= 18 g/mole

Then, by stoichiometry of the reaction the following amounts of reagents and products participate:

Ca(OH)₂: 1 mole* 74 g/mole= 74 gHNO₃: 2 moles* 63 g/mole= 126 gCa(NO₃)₂: 1 mole* 164 g/mole= 164 gH₂O : 2 moles* 18 g/mole= 36 g

Then apply the following rule of three: if 126 grams of nitric acid reacts with 74 grams of calcium hydroxide, 18.9 grams of nitric acid with how much mass of calcium hydroxide does it react?

[tex]mass of calcium hydroxide=\frac{18.9 grams of nitric acid*74 grams of calcium hydroxide}{126 grams of nitric acid}[/tex]

mass of calcium hydroxide= 11.1 grams

But 11.1 grams of calcium hydroxide are not available, 7.4 grams are available. Since you have less mass than you need to react with 18.9 grams of nitric acid, calcium hydroxide will be the limiting reagent.

Then, it is possible to determine the amount of mass of calcium nitrate produced by another rule of three:  if 164 grams of calcium nitrate are formed by stoichiometry from 74 grams of calcium hydroxide, how much mass of calcium nitrate will form from 7.4 grams of calcium hydroxide?

[tex]mass of calcium nitrate=\frac{7.4 grams of calcium hydroxide*164 grams of calcium nitrate}{74 grams of calcium hydroxide}[/tex]

mass of calcium nitrate= 16.4 grams

16.4 grams of calcium nitrate can be prepared by the reaction of 18.9 grams of nitric acid with 7.4 grams of calcium hydroxide

What was Ernest Rutherford experiment

Answers

Geiger marsdent expirement

most vegetables substantially diminish in quality in as little as days

Answers

Answer:

As little as 2 days

Hope this is correct

HAVE A GOOD DAY!

Balance the following redox reaction in acidic solution: H+(aq)+Zn(s)→H2(g)+Zn2+(aq) Express your answer as a chemical equation. Identify all of the phases in your answer. nothing

Answers

Answer:

The balanced equation is: Zn(s) + 2H⁺(aq) → Zn²⁺(aq) + H₂(g)

Explanation:

Zn(s) is a simple substance (its oxidation number is zero) and it is oxidized to Zn²⁺. It loses two electrons, so the half reaction is the following:

Zn(s) → Zn²⁺(aq) + 2 e-   (oxidation reaction)

Hydrogen ion (H⁺) is reduced to hydrogen gas (H₂). The oxidation number is decreased from +1 to 0 (because H₂ is a simple substance). H⁺ gains 1 electron per H atom, so the half reaction is the following:

2H⁺(aq) + 2 e- → H₂(g) (reduction reaction)

We obtain the overall reaction from the addition of the two half reactions. We write the reduction reaction first and then the oxidation reaction, as follows:

2H⁺(aq) + 2 e- → H₂(g)

+

Zn(s) → Zn²⁺(aq) + 2 e-

---------------------------------

Zn(s) + 2H⁺(aq) → Zn²⁺(aq) + H₂(g)

The two electrons at both sides of the equation (2 e-) are canceled. The overall reaction is in acidic solution due to the presence of H⁺ ions. The net charge at both sides is the same : +2, so the mass and the charge are balanced.

The reaction A + 2B → products was found to follow the rate law: rate = k[A] 2[B]. Predict by what factor the rate of reaction will increase when the concentration of A is doubled, the concentration of B is tripled, and the temperature remains constant

Answers

Answer:

By a factor of 12

Explanation:

For the reaction;

A + 2B → products

The rate law is;

rate = k[A]²[B]

As you can see, the rate is proportional to the square of the concentration of  A  and the of the concentration of  B .

Let's say initially, [A] = x, [B] = y

The rate law in this case is equal to;

rate1 = k. x².y

Now you double the concentration of A and triple the concentration of B.

[A] = 2x, [B] = 3y

The new rate law is given as;

rate2 = k . (2x)². (3y)

rate2 = k . 4x² . 3y

rate2 = 12 k . x² . y

Comparing rate 2 and rate 1, the ratio is given as; rate 2/ rate 1 = 12

Therefore the rate has increased by a factor of 12.

When a 2.75g sample of liquid octane (C8H18) is burned in a bomb calorimeter, the temperature of the calorimeter rises from 22.0 °C to 41.5 °C. The heat capacity of the calorimeter, measured in a separate experiment, is 6.18 kJ/°C. Determine the ΔE for octane combustion in units of kJ/mol octane.

Answers

Answer:

THE HEAT OF COMBUSTION IS 4995.69 kJ/mol OF OCTANE.

Explanation:

Heat capacity = 6.18 kJ/C

Temperature change = 41.5 C - 22.0 C = 19.5 C

Heat required to raise the temperature by 19.5 °C is:

Heat = heat capacity * temperature change

Heat = 6.18 kJ/ C * 19.5 C

heat = 120.51 kJ of heat

120.51 kJ of heat is required to raise the temperature of 2.75 g sample of  a liquid octane.

Molar mass of octane = ( 12* 8 + 1 * 18) = 114 g/mol

So therefore, the heat of the reaction per mole of octane will be:

120.51 kJ of heat is required for 2.75 g of octane

x J of heat will be required for 114 g of octane

x J = 120.51kJ * 114 / 2.75

x = 4995.69 kJ of heat per mole.

In conclusion, the heat of the combustion reaction in kJ / mole of octane is 4995.69 kJ/mol

When (R)-3-bromo-2,3-dimethylpentane is treated with sodium hydroxide, four different alkenes are formed. Draw all four products, and rank them in terms of stability.

Answers

Answer:

Most stable: 2,3-dimethylpent-2-ene > (E)-3,4-dimethylpent-2-ene > (Z)-3,4-dimethylpent-2-ene > 2-methyl-3-methylenepentane : Least stable

Explanation:

Treatment of NaOH with (R)-3-bromo-2,3-dimethylpentane results in the elimination of HBr. Each H atoms present on each [tex]\beta[/tex]-carbon atoms can be eliminated result in the formation of four possible products: (1) 2,3-dimethylpent-2-ene, (2) (E)-3,4-dimethylpent-2-ene, (3) (Z)-3,4-dimethylpent-2-ene and (4) 2-methyl-3-methylenepentane.

The stability of these alkenes depends on the number of hyperconjugative H atoms present with respect to the double bond. In accordance with this, 2,3-dimethylpent-2-ene is the most stable alkene (11-hyperconjugative H atoms). Then, 3,4-dimethylpent-2-ene is the second most stable alkene (7-hyperconjugative H atoms). Among (E)-3,4-dimethylpent-2-ene and (Z)-3,4-dimethylpent-2-ene, (E)-3,4-dimethylpent-2-ene is more stable due to it's less sterically hindered structure. 2-methyl-3-methylenepentane is the least stable alkene (3-hyperconjugative H atoms).

So, decreasing order of stability of alkenes from most stable to least stable:

2,3-dimethylpent-2-ene > (E)-3,4-dimethylpent-2-ene > (Z)-3,4-dimethylpent-2-ene > 2-methyl-3-methylenepentane

Three bromo As just a result of the nucleophilic substitution mechanism, 2,4 dimethylpentane generates a racemic mix containing both the r and s forms of the molecule.

In the first, sluggish phase, a two-degree cation with a positive charge is produced at carbon 3, and then it undergoes rearrangement to a 3-degree carbocation at carbon 2 either from the side. So because carbocation only has 6 electrons in its outermost shell, it is sp2 hybridized and thus planar in structure. In step two then occurs, as well as the attack of the -OH group, as the -OH (hydroxyl) group can strike from either side (top or bottom), leading to the formation of a racemic mixture of 2,4 dimethyl pentane-2-ol.This quantity of alpha-hydrogens in an alkyl group can be used to determine its stability. The greater the number of alpha-hydrogens inside an alkene, the overall larger the number of hyperconjugated structures, and thus the greater the stability. Due to the obvious symmetrical structure of a trans-isomer, whenever the amount of alpha-hydrogens is the same, the trans-alkene isomer is much more stable than that of the cis-alkene isomer.

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The following balanced equation describes the reduction of iron(III) oxide to molten iron within a blast furnace: Fe2O3(s) + 3CO(g) ---> 2Fe(l) + 3CO2(g) Steve inserts 450. g of iron(III) oxide and 260. g of carbon monoxide into the blast furnace. After cooling the pure liquid iron, Steve determines that he has produced 288g of iron ingots. How much of the excess reactant (in grams) is left over after the theoretical yield of liquid iron is produced?

Answers

Answer:

Amount of excess Carbon (ii) oxide left over = 23.75 g

Explanation:

Equation of the reaction: Fe₂O₃ + 3CO ----> 2Fe + 3CO₂

Molar mass of Fe₂O₃ = 160 g/mol;

Molar mass of Carbon (ii) oxide = 28 g/mol

From the equation of reaction, 1 mole of Fe₂O₃ reacts with 3 moles of carbon (ii) oxide; i.e. 160 g of iron (iii) oxide reacts with 84 g (3 * 28 g)  of carbon (ii) oxide

450 g of Fe₂O₃ will react with 450 * 84/180) g of carbon (ii) oxide = 236..25 g of carbon (ii) oxide

Therefore the excess reactant is carbon (ii) oxide.

Amount of excess Carbon (ii) oxide left over = 260 - 236.25

Amount of excess Carbon (ii) oxide left over = 23.75 g

A compound is found to contain 18.28 % phosphorus , 18.93 % sulfur , and 62.78 % chlorine by mass. To answer the question, enter the elements in the order presented above. QUESTION 1: The empirical formula for this compound is . QUESTION 2: The molar mass for this compound is 169.4 g/mol. The molecular formula for this compound is

Answers

Answer:

1. EF = PSCl₃; 2. MF = PSCl₃  

Explanation:

1. Empirical formula

The empirical formula is the simplest whole-number ratio of atoms in a compound.

The ratio of atoms is the same as the ratio of moles.

So, our first job is to calculate the molar ratio of P:S:Cl.

Assume 100 g of the compound.

(a) Calculate the mass of each element.

Then we have 18.28 g P, 18.93 g S, and 67.28 g Cl.

(b) Calculate the moles of each element

[tex]\text{Moles of P} = \text{18.28 g C} \times \dfrac{\text{1 mol P}}{\text{30.97 g P}} = \text{0.5902 mol P}\\\\\text{Moles of S} = \text{18.93 g S} \times \dfrac{\text{1 mol S}}{\text{32.06 g S }} = \text{0.5905 mol S}\\\\\text{Moles of Cl} = \text{62.78 g Cl} \times \dfrac{\text{1 mol Cl}}{\text{35.45 g Cl }} = \text{1.771 mol Cl}[/tex]

(c) Calculate the molar ratio of the elements

Divide each number by the smallest number of moles

P:S:Cl = 0.5902:0.5905:1.898 = 1:1.000:3.000 ≈ 1:1:3

(d) Write the empirical formula

EF = PSCl₃

The empirical formula for this compound is PSCl₃.

2. Molecular formula

(a) Calculate the ratio of the molecular and empirical formula masses

n = (169.4 u)/(169.40 u) = 1.000 ≈ 1

(b) Calculate the molecular formula

MF = (EF)ₙ = (EF)₁ = PSCl₃

The molecular formula for this compound is PSCl₃.

How many milliliters of 0.0850 M NaOH are required to titrate 25.0 mL of 0.0720 M hydrobromic acid, HBr, to the equivalence point?

Answers

Answer:

21.2 mL

Explanation:

Step 1: Write the balanced equation.

NaOH + HBr ⇒ NaBr + H₂O

Step 2: Calculate the reacting moles of HBr

25.0 mL of 0.0720 M hydrobromic acid react.

[tex]0.0250 L \times \frac{0.0720mol}{L} = 1.80 \times 10^{-3} mol[/tex]

Step 3: Calculate the reacting moles of NaOH

The molar ratio of NaOH to HBr is 1:1. The reacting moles of NaOH are 1/1 × 1.80 × 10⁻³ mol = 1.80 × 10⁻³ mol.

Step 4: Calculate the required volume of NaOH

[tex]1.80 \times 10^{-3} mol \times\frac{1,000mL}{0.0850mol} = 21.2 mL[/tex]

In this experiment, you will analyze your sample by TLC by spotting pure benzophenone and your product and eluting with 5:1 hexanes/ethyl acetate. Choose the statement that BEST describes what you should observe for a successful experiment.
A) The benzophenone in the standard and reaction samples should travel the farthest and will have the same Rf value. No unreacted benzhydrol should be observed at a lower Rf value.
B) The benzophenone in the standard and reaction samples should travel the least and will have the same Rf value. No unreacted benzhydrol should be observed at a higher Rf value.
C) The benzophenone in the standard and reaction samples should travel the farthest and will have the same Rf value. Unreacted benzhydrol should be observed at a lower Rf value.
D) The benzophenone in the standard and reaction samples should travel the farthest and will have the different Rf values. No unreacted benzhydrol should be observed at a lower Rf value.

Answers

Answer:

The correct answer is statement A.

Explanation:

In a media comprising 20 percent ethyl acetate/hexane, as the benzophenone is non-polar, so it will travel farther with high Rf value. On the other hand, as benzohydrol is a polar molecule, therefore, it should be at lower Rf value and will not rise in the given media.  

For an experiment to be successful, there should not be any unreacted benzohydrol to be left in the experimental system. The benzophenone in the reaction as well as the standard samples should exhibit similar Rf value.  

The benzophenone in the standard and reaction samples should travel the farthest and will have the same Rf value. No unreacted benzhydrol should be observed at a lower Rf value to analyze by TLC.

What is TLC ?

In synthetic chemistry, thin-layer chromatography (TLC) is a method that is frequently used to identify compounds, assess their purity, and monitor the progress of a reaction. Additionally, it enables the solvent system for a specific separation problem to be optimized.

The foundation of TCL is the adsorption-based separation theory. The separation depends on how sensitive different chemicals are to the stationary and mobile phases.

TLC, or thin layer chromatography, is a technique for isolating the components of mixtures before analysis. TLC can be used to identify compounds, ascertain their identities, and ascertain the purity of a compound.

Thus, option A is correct.

To learn more about TLC, follow the link;

https://brainly.com/question/14393140

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