what alkyl halides are needed to prepare the following carboxylic acid by the malonic ester synthesis?

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Answer 1

To prepare a specific carboxylic acid using the malonic ester synthesis, Identify the desired carboxylic acid structure, Remove the COOH, Add a halogen atom (X), and alkyl halide for the malonic ester synthesis.

you will need an alkyl halide as a reactant. Here is a step-by-step explanation to determine the required alkyl halide:
1. Identify the desired carboxylic acid structure. For this, you should know the target carboxylic acid's molecular structure or its name.
2. Remove the carboxylic acid group (COOH) from the target molecule.
3. Add a halogen atom (X) to the remaining carbon atom where the COOH group was attached. The halogen atom could be chlorine (Cl), bromine (Br), or iodine (I).
4. The resulting molecule is the required alkyl halide for the malonic ester synthesis.
For a more specific answer, please provide the structure or name of the carboxylic acid you wish to prepare.

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Calculate the decrease in temperature when 8.5 L at 25.0 °C is compressed to 4.00 L.

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The decrease in temperature when 8.5 L at 25.0 °C is compressed to 4.00 L is 86.7 °C.

This is a problem involving the ideal gas law, which relates pressure (P), volume (V), number of moles (n), and temperature (T) of a gas:

PV = nRT

where R is the gas constant. Assuming the number of moles is constant, we can write:

P₁V₁/T₁ = P₂V₂/T₂

where the subscripts 1 and 2 refer to the initial and final states of the gas, respectively.

We can use this equation to solve for the final temperature (T₂), given the initial conditions (P₁ = 1 atm, V₁ = 8.5 L, and T₁ = 25.0 °C) and the final volume (V₂ = 4.00 L):

P₁V₁/T₁ = P₂V₂/T₂

T₂ = (P₂V₂/T₁) * [tex](P₁V₁)^-1[/tex]

The pressure (P) is not given, but we can assume that it remains constant during the compression process, which is a reasonable assumption if the compression is slow and controlled. Let's assume a pressure of 1 atm.

T₂ = (1 atm * 4.00 L / (25.0 °C + 273.15)) *[tex](1 atm * 8.5 L)^-1[/tex]

T₂ = 211.5 K

The final temperature of the compressed gas is 211.5 K. To calculate the decrease in temperature, we need to find the change in temperature from the initial temperature of 25.0 °C:

ΔT = T₂ - T₁

ΔT = 211.5 K - (25.0 °C + 273.15)

ΔT = -86.7 °C.

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according to the arrhenius concept, if hno3 were dissolved in water, it would act as . group of answer choices a source of h- ions a proton acceptor an acid a source of hydroxide ions a base

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According to the Arrhenius concept, if HNO3 were dissolved in water, it would act as an acid. This is the correct answer.

This is because HNO3 would donate a proton (H+) to the water, increasing the concentration of H+ ions in the solution. The Arrhenius concept is a definition of acids and bases proposed by Svante Arrhenius in 1884.

According to this concept, an acid is a substance that produces hydrogen ions (H+) when dissolved in water, while a base is a substance that produces hydroxide ions (OH-) when dissolved in water.HNO3 is an example of an acid because it produces H+ ions when dissolved in water.

This can be seen from the following equation:

HNO3 + H2O → H3O+ NO3

In this equation, HNO3 donates an H+ ion to the water molecule, forming H3O+.

Therefore, HNO3 acts as an acid when dissolved in water.

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the experiment is repeated with an eggshell sample, and the experimental data are recorded in the table below. mass of eggshell sample 0.200g pressure prior to reaction 0.800atm pressure at completion of reaction 0.870atm question the mass percent of caco3(s) in the eggshell sample is closest to

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The mass percent of CaCO₃(s) in the eggshell sample is closest to 136%.

The number of moles of carbon dioxide produced in the reaction can be calculated from the change in pressure of the gas:

ΔP = P₂ - P₁ = 0.870 atm - 0.800 atm = 0.070 atm

n = (ΔP * V) / (R * T)

Assuming the volume of the gas is the same as the volume of the acid, we can use the initial pressure and volume of the acid to calculate the number of moles of carbon dioxide:

n = (0.070 atm * 0.100 L) / (0.0821 L atm/mol K * 298 K) = 0.00272 mol CO₂

From the balanced equation, we know that one mole of calcium carbonate produces one mole of carbon dioxide:

CaCO₃(s) + 2HCl(aq) → CaCl₂(aq) + CO₂(g) + H₂O(l)

Therefore, the number of moles of calcium carbonate in the eggshell sample is also 0.00272 mol.

The mass percent of calcium carbonate in the eggshell sample can be calculated as follows:

mass percent = (mass of CaCO₃ / mass of sample) x 100%

mass of CaCO₃ = n x molar mass of CaCO₃

The molar mass of CaCO₃ is 100.09 g/mol.

mass of CaCO₃ = 0.00272 mol x 100.09 g/mol = 0.272 g

mass percent = (0.272 g / 0.200 g) x 100% = 136%

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Make a prediction you think is happening to the coral reefs if the concentration of salt increases or decreases.

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Coral islands might be negatively impacted if the ocean's salinity level were to rise. Since corals have evolved to exist in a very narrow range of salinity, a rise in salt concentration might make them stressed or even kill them.

However, since corals need a certain amount of salinity to keep their internal water balance, a drop in salt concentration could also be harmful.

While salinity variations do not pose the greatest danger to coral reefs, they can undoubtedly affect their health and should be watched closely along with other environmental factors.

Coral reef survival and health depend heavily on salinity or the amount of salt in the ocean. Corals have developed to exist in a particular range of salinities, and changes outside of that range may have a detrimental effect on their capacity to endure and flourish.

The surrounding water may become too salty for the corals to endure if the concentration of salt increases, as might be the case due to human activities like salt mining or seawater desalination.

This could make them stressed out and more prone to illness, bleaching, or even mortality. Contrarily, a decrease in salt concentration, such as that caused by freshwater runoff, can make the water too diluted for the corals to keep their internal water balance, which can also lead to stress and other negative effects.

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What are likely formulas for the following molecules?
(a) NH2OH
(b) AlCl2
(c) CF2Cl2
(d) CH2O

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(a) NH2OH- Nitrogen is a group 5 element and has 5 valence electrons. Oxygen is a group 6 element and has 6 valence electrons. Hydrogen is a group 1 element and has 1 valence electron. Therefore, NH2OH has the formula: NH2OH

(b) AlCl2- Aluminum is a group 3 element and has 3 valence electrons. Chlorine is a group 7 element and has 7 valence electrons. Therefore, AlCl2 has the formula: AlCl2

(c) CF2Cl2- Carbon is a group 4 element and has 4 valence electrons. Fluorine is a group 7 element and has 7 valence electrons. Chlorine is a group 7 element and has 7 valence electrons. Therefore, CF2Cl2 has the formula: CF2Cl2

(d) CH2O- Carbon is a group 4 element and has 4 valence electrons. Oxygen is a group 6 element and has 6 valence electrons. Hydrogen is a group 1 element and has 1 valence electron. Therefore, CH2O has the formula: CH2O

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the proportion of parent to daughter isotopes in a mineral is 40% parent and 60% daughter. how many half-lives have elapsed since the mineral contained 100% parent atoms?

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The ratio between 1 and 2 half lives that have elapsed since the mineral contained 100% parent atoms.

Let us consider that the parent isotope decays into the daughter isotope through a process of radioactive decay with a constant half-life.

we can use the fact of the half life which is the proportion of parent to daughter isotopes which changes over the time. We have to determine that how many half-lives have elapsed since the mineral contained 100% parent atoms.

We have the proportion of parents to daughter isotopes in the mineral is 40% parent and 60% daughter. So the ratio becomes 2:3 parent to daughter isotopes.

Calculating the current ratio of 2:3 is closest to the ratio of 1:3 which occurs after two half-lives of the mineral. So we get the ratio between 1 and 2 half-lives which have elapsed since the mineral contained 100% parent atoms.

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what is the ph of the buffer that results when 12.5 g of nah2po4 and 22.0 g na2hoi4 are mixed and diluted with water to 0.5 l?

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The pH of the buffer that results when 12.5 g of [tex]NaH_{2}PO_{4}[/tex] and 22.0 g [tex]Na_{2}HPO_{4}[/tex] are mixed and diluted with water to 0.5 L is 9.36. A buffer is a solution that resists changes in pH as acids or bases are added to it. It is created from a weak acid or base and one of its salts.

To calculate the pH of a buffer, we can use the Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA]) where: pH is the pH of the buffer pKa is the acid dissociation constant of the weak acid[A-] is the concentration of the conjugate base of the weak acid[HA] is the concentration of the weak acid.

According to the problem, 12.5 g of [tex]NaH_{2}PO_{4}[/tex] and 22.0 g [tex]Na_{2}HPO_{4}[/tex] are mixed and diluted with water to 0.5 L. The molecular weight of  [tex]NaH_{2}PO_{4}[/tex] is 120 g/mol. Therefore, the number of moles of  [tex]NaH_{2}PO_{4}[/tex] is:12.5 g × 1 mol/120 g = 0.104 mol The molecular weight of  [tex]Na_{2}HPO_{4}[/tex] is 142 g/mol.

Therefore, the number of moles of  [tex]Na_{2}HPO_{4}[/tex] is:22.0 g × 1 mol/142 g = 0.155 mol The total concentration of the buffer is the sum of the concentrations of the weak acid and its conjugate base. Therefore, the concentration of  [tex]NaH_{2}PO_{4}[/tex] is:0.104 mol/0.5 L = 0.208 M The concentration of   [tex]Na_{2}HPO_{4}[/tex] is:0.155 mol/0.5 L = 0.31 M The pKa of  [tex]NaH_{2}PO_{4}[/tex] is 7.21.The concentration of the weak acid [HA] is 0.208 M.

The concentration of the conjugate base [A-] is 0.31 M.pH = pKa + log([A-]/[HA])= 7.21 + log(0.31/0.208)= 9.36The pH of the buffer that results when 12.5 g of  [tex]NaH_{2}PO_{4}[/tex] and 22.0 g  [tex]Na_{2}HPO_{4}[/tex] are mixed and diluted with water to 0.5 L is 9.36.

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what is the ph of a 0.050 m hbr solution? group of answer choices 1.30 none of these choices are correct. 1.12 0.89 3.00

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Answer:

The answer is 1.30

Explanation:

The equation to calculate the pH of a strong acid solution is pH = -log[H+], where [H+] is the concentration of hydrogen ions in the solution.

For a 0.050 M HBr solution, the concentration of H+ ions is also 0.050 M since HBr is a strong acid and dissociates completely in water. Therefore, the pH can be calculated as follows:

pH = -log[H+] =

ph=-log(0.050) = 1.30

So the pH of a 0.050 M HBr solution is 1.30.

The pH of a 0.050 M HBr solution is 1.30. The correct option is (a) 1.30.

What is pH?

The negative of the logarithm to base 10 of the hydrogen ion concentration (expressed in mol/L) is referred to as pH. pH can be defined using the following equation:

pH = - log [H+]

Where [H+] is the concentration of hydrogen ions in moles per liter. It ranges from 0 to 14. A pH of 7.0 is neutral. If the pH is below 7, the solution is acidic, and if it is above 7, the solution is alkaline (basic).

HBr is the chemical formula for hydrogen bromide, a diatomic molecule consisting of hydrogen and bromine. It is a colorless gas with a strong odor that fumes in moist air. It is a potent acid that reacts vigorously with water to form hydrobromic acid.

In an aqueous solution, hydrobromic acid is the resulting acid. For a 0.050 M HBr solution, we can use the equation:

pH = - log [H+]

pH = - log [0.050]

pH = 1.30

Therefore, the pH of a 0.050 M HBr solution is 1.30.

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three students are asked to discuss the percent error obtained in this lab. which student employs correct scientific reasoning? group of answer choices the percent error could be caused by the salt not completely dissolving, therefore the change in heat per mole would be accidentally low. the percent error could be caused by mixing the reaction too quickly, the friction caused by mixing would increase the change in heat measured. the percent error could be caused by the change in ph of the solution, this would decrease the change in heat accidentally.

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The correct student with scientific reasoning is the first student who states that the percent error could be caused by the salt not completely dissolving, which would result in a lower measured change in heat per mole. This is a valid scientific reasoning as the dissolving of the salt is an important factor that affects the change in heat during the reaction.

The percent error could be caused by the salt not completely dissolving, therefore the change in heat per mole would be accidentally low. The percent error could be caused by mixing the reaction too quickly, the friction caused by mixing would increase the change in heat measured. The percent error could be caused by the change in pH of the solution, this would decrease the change in heat accidentally.

The second student's statement that the percent error could be caused by mixing the reaction too quickly is not a valid scientific reasoning, as mixing does not affect the change in heat produced by the reaction.

The third student's statement that the percent error could be caused by the change in pH of the solution decreasing the change in heat is also not a valid scientific reasoning, as a change in pH would not affect the change in heat produced by the reaction.

Therefore, the first student provides the correct scientific reasoning for the possible cause of the percent error in the lab.

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Determine the heat absorbed by 1.5 moles of glycerol when its temperature increases from 25°C to 70°C. The molar mass of glycerol (C3H803) is 92.09 g/mol.

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As a result, 1.5 moles of glycerol absorb about 1.99 Joules of heat when their temperature rises from 25 to 70 degrees Celsius.

What is C3H8O3 also known as?

Glycerin is a straightforward polymer. The molecular formula of this solvent is C3H8O3. It is sometimes referred to as glycerine or glycerol.

We can use the following formula to determine how much heat 1.5 moles of glycerol absorbed: q = n × C × ΔT

Glycerol has a specific heat capacity of 2.43 J/g°C. This needs to be divided by the molar mass of glycerol in order to be converted to Joules per mole per degree Celsius:

C = (2.43 J/g°C) / (92.09 g/mol)

C = 0.0264 J/mol°C

The change in temperature can then be calculated as follows:

ΔT = (70°C - 25°C) = 45°C

We can now enter the values into the formula as follows:

q = (1.5 mol) × (0.0264 J/mol°C) × (45°C)

q = 1.99 J

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if the concentration of 1-iodopropane quadruples and the concentration of sodium hydroxide triples in this sn2 reaction, how much faster is the reaction rate?

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The rate of an SN2 reaction depends on some the concentration of both the nucleophile and the substrate. Here the nucleophile is the hydroxide ion. Substrate is 1-iodopropane.

The rate equation for an SN2,

Rate = k [substrate] [nucleophile]

k ⇒ rate constant.

Suppose the concentration of 1-iodopropane becomes four time. Also the concentration of sodium hydroxide becomes three times. Now the new rate of the reaction is,

New Rate = k [4[substrate]] [3[nucleophile]]

New Rate = k [12[substrate]] [nucleophile]

New Rate = 12k [substrate] [nucleophile]

The new rate of the reaction is 12 times the original rate. So the reaction is 12 times faster when the concentration of 1-iodopropane becomes four times and the concentration of sodium hydroxide becomes three times.

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g enter your experimental data into columns d-g. 2. use your temperature data and equation 7.1 to determine the calories of heat released (column h) for each sample combustion. enter the calculation of q using equation 7.1 into the cells of column h with the appropriate mass of water for m. the specific heat of water for c and at= column g entry - column f entry. report your results to the proper number of significant figures. 3. use the initial sample mass to determine the cal/g (column 1) you measured for each sample. if you used different sizes of sample and got very different results for a particular food, which value is likely to be more reliable? explain why. 4. use the mass lost in the burning (column e entry - column d entry) to determine the salg lost (column j) for each sample.

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It is important to be concise and not provide extraneous amounts of detail.

When answering questions on the Brainly platform, you should always aim to be factually accurate, professional, and friendly. Additionally,You should also use the following terms in your answer if they are relevant to the question being asked

g enter your experimental data into columns d-g.

2. use your temperature data and equation 7.1 to determine the calories of heat released (column h) for each sample combustion. enter the calculation of q using equation 7.1 into the cells of column h with the appropriate mass of water for m. the specific heat of water for c and at

= column g entry - column f entry. report your results to the proper number of significant figures.

3. use the initial sample mass to determine the cal/g (column 1) you measured for each sample. if you used different sizes of sample and got very different results for a particular food, which value is likely to be more reliable? explain why.

4. use the mass lost in the burning (column e entry - column d entry) to determine the salg lost (column j) for each sample.

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Which physical property requires no tools, scales, or other equipment to determine?

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Color is a physical property that requires no tools, scales, or other equipment to determine. It is an observable characteristic of an object and can be described using terms such as red, blue, green, etc. Other physical properties such as odor, taste, and texture may also be determined without the use of tools or equipment.

some toxic substances degrade once released into the environment. what controls the rate of degradation? group of answer choices all of the above moisture chemistry of the substance temperature sun exposure

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The rate of degradation of toxic substances in the environment is controlled by several factors. These include the chemistry of the substance, moisture, temperature, and sun exposure. The correct answer is "all of the above".

When toxic substances are released into the environment, the rate of degradation is controlled by all of the above factors. Toxic substances are substances that cause harm to living organisms when they come into contact with them.

The moisture content of the environment where the toxic substance is released affects the rate of degradation. When the environment is moist, the toxic substance degrades more quickly than when the environment is dry.

The substance's chemistry influences the rate of degradation, as some substances break down more quickly than others when exposed to the environment's natural processes.

Temperature also influences the rate of degradation of toxic substances. When temperatures are high, the substance degrades more quickly than when temperatures are low.

Sun exposure also impacts the rate of degradation, with more sun exposure leading to faster degradation than less sun exposure.

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if you consistently titrated until your indicator turned yellow, how would that affect the calculated concentration of the hcl?

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When a base is titrated until the solution turns yellow, this indicates that the pH has been lowered below the pH at equivalence. This change is from acidic to basic, then neutral.

As the yellow colour develops at pH 6, two equivalence points are crossed here, causing the pH to be dropped to 6. In this titration, more acid volume is added than is necessary to reach the equivalent point.

We utilise moles and volume of base (known) to calculate the concentration of acid and obtain the moles of acid at the equivalence point.

Acid molarity equals moles of acid divided by volume in litres. If the volume is greater, the molarity value is less accurate. As a result, the acid's molarity is reduced.

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Furoic acid 1HC5H3O32 has a Ka value of 6.76 * 10-4 at 25 °C. Calculate the pH at 25 °C of (a) a solution formed by adding 25.0 g of furoic acid and 30.0 g of sodium furoate 1NaC5H3O32 to enough water to form 0.250 L of solution, (b) a solution formed by mixing 30.0 mL of 0.250 M HC5H3O3 and 20.0 mL of 0.22 M NaC5H3O3 and diluting the total volume to 125 mL, (c) a solution prepared by adding 50.0 mL of 1.65 M NaOH solution to 0.500 L of 0.0850 M HC5H3O3.

Answers

(a) The pH at 25°C in first solution is 1.97

(b) The pH at 25°C in  second solution is 2.19

(c) The pH at 25°C in third solution is 2.26

(a) For the solution formed by adding 25.0 g of furoic acid and 30.0 g of sodium furoate to 0.250 L of water, we can calculate the molarity of furoic acid as follows:

25.0 g of furoic acid = 1.000 mol of furoic acid

1.000 mol of furoic acid = 4.000 L of solution

Molarity of furoic acid = [tex]\frac{4.000 L}{0.250 L} = 16.00 M[/tex]

The pH of the solution can then be calculated using the Ka value:

[tex]Ka =\frac{ [H^+][C_5H_3O_3 ^-]}{[HC_5H_3O_3]}[/tex]

[tex][H^+] = Ka *\frac{ [HC_5H_3O_3] }{ [C_5H_3O_3^-]} \\\\= 6.76 * 10^{-4} * \frac{16.00}{1} = 0.1081 M[/tex]

[tex]pH = -log[H^+] = -log(0.1081) = 1.97[/tex]

(b) For the solution formed by mixing 30.0 mL of 0.250 M [tex]HC_5H_3O_3[/tex]and 20.0 mL of 0.22 M[tex]NaC_5H_3O_3[/tex] and diluting the total volume to 125 mL, we can calculate the molarity of furoic acid as follows:

30.0 mL of 0.250 M [tex]HC_5H_3O_3[/tex] = 0.0750 mol of furoic acid

20.0 mL of 0.220 M [tex]NaC_5H_3O_3[/tex] = 0.044 mol of sodium furoate

Total moles of furoic acid = 0.0750 + 0.044 = 0.119 mol

Molarity of furoic acid =[tex]\frac{0.119 mol}{1.25 L} = 0.0952 M[/tex]

The pH of the solution can then be calculated using the Ka value:

[tex]Ka =\frac{ [H^+][C_5H_3O_3^-]}{[HC_5H_3O_3]}[/tex]

[tex][H+] = Ka *\frac{ [HC_5H_3O_3] }{ [C_5H_3O_3^-] }\\= 6.76 * 10^{-4} * \frac{0.0952 }{ 1} \\= 0.0065 M[/tex]

[tex]pH = -log[H^+] = -log(0.0065) = 2.19[/tex]

(c) For the solution prepared by adding 50.0 mL of 1.65 M[tex]NaOH[/tex]solution to 0.500 L of 0.0850 M [tex]HC_5H_3O_3[/tex], we can calculate the molarity of furoic acid as follows:

50.0 mL of 1.65 M NaOH = 0.0825 mol of NaOH

0.500 L of 0.0850 M [tex]HC_5H_3O_3[/tex] = 0.0425 mol of furoic acid

Total moles of furoic acid = 0.0825 + 0.0425 = 0.125 mol

Molarity of furoic acid =[tex]\frac{ 0.125 mol}{1.50 L} = 0.083 M[/tex]

The pH of the solution can then be calculated using the Ka value:

[tex]Ka =\frac{ [H^+][C_5H_3O_3^{-}}{[HC_5H_3O_3]}[/tex]

[tex][H+] = Ka *\frac{ [HC5H3O3] }{[C5H3O3-] }\\= 6.76 * 10^{-4}*\frac{ 0.083 }{1 }\\= 0.0055 M[/tex]

[tex]pH = -log[H^+] = -log(0.0055) = 2.26[/tex]

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what is the conjugate acid of the brønsted-lowry base, h₂po₄⁻

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The conjugate acid of the Brønsted-Lowry base, H₂PO₄⁻, is: H₃PO₄.

Brønsted-Lowry base is any substance that can accept or accept an H+ ion. Bronsted-Lowry acid is a substance that donates or loses an H+ ion. A conjugate acid is an acid that is formed when a base accepts a hydrogen ion. Similarly, a conjugate base is formed when an acid donates a hydrogen ion.

How does conjugate acid and conjugate base work?

If a base accepts a hydrogen ion (H+), it will become an acid. And, if an acid donates an H+ ion, it will become a base. A pair of species related through the loss or gain of H+ ion are called conjugate acid-base pairs.

According to the given question, H₂PO₄⁻ is the Brønsted-Lowry base. Now, to determine the conjugate acid, an H+ ion is added to it.

H₂PO₄⁻ + H⁺ → H₃PO₄

Therefore, the conjugate acid of H₂PO₄⁻ is H₃PO₄.

Note:

In Brønsted-Lowry theory, a molecule or an ion is considered an acid or base based on its ability to donate or accept H+ ions. Acid can lose H+ ions, and base can gain H+ ions.

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A gas absorbs 8.2 kJ of heat and does 7.9 kJ of work. Calculate ΔE.

Answers

A gas absorbs 8.2 kJ of heat and does 7.9 kJ of work the change in internal energy of the gas is 0.3 kJ.

According to the first law of thermodynamics:

ΔE = Q - W

ΔE is the change in internal energy of the gas

Q is the heat absorbed by the gas

W is the work done by the gas

Substituting the given values:

ΔE = 8.2 kJ - 7.9 kJ

ΔE = 0.3 kJ

Thermodynamics is the branch of physics that deals with the relationships between heat, energy, and work. It is a fundamental concept in understanding how energy is transferred and transformed in physical systems, from the behavior of atoms and molecules to the macroscopic properties of matter.

Thermodynamics is based on a few fundamental laws, including the first law of thermodynamics (also known as the law of conservation of energy), which states that energy cannot be created or destroyed, only transferred or converted from one form to another. The second law of thermodynamics states that the total entropy of a closed system can only increase over time, and that heat will flow spontaneously from hotter objects to colder ones.

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which of the following are at equilibrium? check all that apply. which of the following are at equilibrium?check all that apply. the concentrations of the reactants and the products do not change. the rate of the reverse reaction does not change. the rate of the forward reaction is twice as fast as the rate of the reverse reaction.

Answers

An equilibrium is reached when the concentrations of the reactants and products do not change, and the rate of the forward reaction is equal to the rate of the reverse reaction.

Based on this definition, the following statements apply to an equilibrium:

1. The concentrations of the reactants and the products do not change.


2. The rate of the reverse reaction does not change.

The third statement, "the rate of the forward reaction is twice as fast as the rate of the reverse reaction," does not apply to an equilibrium. This is because, in equilibrium, the rate of the forward reaction must be equal to the rate of the reverse reaction for the concentrations to remain constant. If the forward reaction was faster, it would cause the concentrations to change, and the system would not be in equilibrium.

In summary, a system is at equilibrium when the concentrations of reactants and products do not change, and the rates of the forward and reverse reactions are equal. The first two statements apply to an equilibrium, while the third statement does not.

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The state of an ideal gas is changed in a closed path 1→2→3→4→1 as shown. If the value at at point 1 is V = 1 m3 and P = 105 Pa, calculate the net work in this cycle in units of kJ. Make sure you use negative sign for work done by the system and positive for work done on the system.

Answers

The net work done in this cycle is -6.517 x 10^4 J, which is equivalent to -65.17 kJ. Note that the negative sign indicates that the system is doing work on its surroundings.

To calculate the net work done in this closed path, we need to calculate the work done in each segment of the path and then add them up.

The work done by or on a gas during a process is given by the area enclosed by the process on a P-V diagram.

Since this is a closed path, the net work done is equal to the area enclosed by the path.

First, let's determine the type of processes happening in each segment of the path:

1 → 2: Isothermal compression (temperature is constant)

2 → 3: Isobaric expansion (pressure is constant)

3 → 4: Adiabatic expansion (no heat exchange with surroundings)

4 → 1: Isobaric compression (pressure is constant)

Using the ideal gas law, we can relate the pressure, volume, and temperature of the gas at each point in the path:

P1V1/T1 = P2V2/T2 (for segment 1 → 2, since it is an isothermal process)

P2 = P3 = 2P1 (for segment 2 → 3, since pressure is constant)

P3V3^γ = P4V4^γ (for segment 3 → 4, since it is an adiabatic process, where γ is the ratio of specific heats of the gas)

P4 = P1 (for segment 4 → 1, since pressure is constant)

Now, we can solve for the volumes at each point in the path:

V2 = V1 (P1/P2) (from 1 → 2)

V3 = V2 (P2/P3) = V1(P1/P2)(P2/P3) (from 2 → 3)

V4 = V3(P3/P4)^1/γ = V1(P1/P2)(P2/P3)(P3/P4)^1/γ (from 3 → 4)

Substituting the given values:

V2 = 1 (105/2 x 105) = 0.5 m^3

V3 = 0.5 (2 x 105/105) = 1 m^3

V4 = 1 (105/2 x 105) x (2 x 105/105) x (105/105)^1/7 = 0.25 m^3

Now we can calculate the work done in each segment of the path using the area enclosed by each process on a P-V diagram:

1 → 2: W12 = -nRT ln(V2/V1) = -nRT ln(0.5/1) = nRT ln(2)

2 → 3: W23 = P2ΔV = 2 x 105 (1 - 0.5) = 1 x 10^4 J

3 → 4: W34 = -nCv(T4 - T3) = -nCv(T4/T3 - 1) = -nCv[(P4/P3)^(γ-1) - 1] = -nCv[(105/2 x 105)^(1/7) - 1]

4 → 1: W41 = P1ΔV = 105 (0.25 - 1) = -7.875 x 10^4 J

Since this is a closed path, the net work done is the sum of the work done in each segment of the path:

[tex]W_{net}[/tex]= W12 + W23 + W34 + W41

[tex]W_{net}[/tex] = nRT ln(2) + 1 x 10^4 J - nCv[(105/2 x 105)^(1/7) - 1] - 7.875 x 10^4 J

We can simplify this expression by using the ideal gas law and the specific heat capacity at constant volume:

[tex]W_{net}[/tex]= (P1V1/RT)RT ln(2) + P2ΔV - (3/2)nR[(105/2 x 105)^(1/7) - 1] - P1ΔV

[tex]W_{net}[/tex]= V1 ln(2) + P2ΔV - (3/2)(n/2)(105/2 x 105)^(1/7) + P1ΔV

[tex]W_{net}[/tex]= V1 ln(2) + P2ΔV - (3/4)n(105/2 x 105)^(1/7) + P1ΔV

We can substitute the values for ΔV and simplify further:

[tex]W_{net}[/tex]= 1 ln(2) + 1 x 10^4 J - (3/4)n(105/2 x 105)^(1/7) - 7.875 x 10^4 J

[tex]W_{net}[/tex]= -6.517 x 10^4 J

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question 4 metals are both good heat conductors and good electrical conductors because of the looseness of outer electrons in metal atoms. similarity between thermal and electrical conductive properties. high elasticity of metals. relatively high densities of metals. ability of metals to transfer energy easily.

Answers

Metals are good conductor of heat and electricity because of the presence of loose outer electrons in metal atoms. So option A is the correct answer.

Heat conduction occurs due to the collision of the molecules and transfer of the heat energy from one to another. Electricity is conducted when particles are charged and they move in an  organized manner.

In metals there are free held electrons also called as sea of electrons, which are not specific to an individual atoms, but are loosely bound so they can move along the whole metallic frame work. Also all the metals show low resistance.

As the electrons are free to move along the total metallic framework this increases collision between particles and become conductor of heat. As the mobile electrons can move from atom to atom, they are excellent conductors of electricity.

So option A is correct.

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The complete question is

Question 4: Metals are both good heat conductors and good electrical conductors because of

A. The looseness of outer electrons in metal atoms.

B. Similarity between thermal and electrical conductive properties.

C. High elasticity of metals. relatively high densities of metals.

D. Ability of metals to transfer energy easily.

at a given temperature, which gas has the lowest average molecular speed? 1. nitrogen 2. fluorine 3. carbon monoxide 4. carbon dioxide 5. chlorine

Answers

The gas with the slowest average molecular speed at a particular temperature is chlorine, or Cl2. The right answer is 5.

The formula for the typical molecular speed is:

The atomic speed is 1/M.

Where,

The molecular mass is M.

N2 has a molecular weight of 28.01 g/mol.

F2 has a molecular weight of 37.99 g/mol.

Carbon monoxide has a molecular weight of 28.01 g/mol.

Cl2 has a molecular weight of 70.90 g/mol.

The average molecular speed decreases with increasing molecule mass. The average molecular speed increases with decreasing molecular weight.

The chlorine has the slowest average molecular speed as a result.

The substance with the slowest average molecular speed is chlorine, or Cl2. Hence option 5 is correct.

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8.97998 in significant figure

Answers

Answer: 8.98 (rounded to two significant figures)

Explanation:  

Answer:

9

Explanation:

8.97998 to the nearest significant figure.

49.8 grams of KI is dissolved in 1.00 kg solventCalculate the molarity, molality, mole fraction,
and mass % of KI in this solution. (Remember that 1 L water = 1 kg water)

Answers

The solution has a molality of 0.299 mol/kg, a molarity of 0.299 M, a mole fraction of 0.0054, and a mass percentage of 4.74%.

How is molarity determined?

The amount of moles of KI must be determined before we can compute the molarity:

n = m/M

where M is the molar mass of KI (166.00 g/mol), m is the mass of KI (49.8 g), and n is the number of moles.

n=49.8 g/166.00 g/mol = 0.299 moles

The solution's molarity is as follows:

Molarity = n/V

where V is the solution's volume in liters (since 1 kg of solvent is approximately equal to 1 L of solution).

Molarity = 0.299 moles/one litre = 0.299 M

How is molality determined?

We use the following equation to get the molality:

molality equals n / m solvent

where m solvent is the solvent's mass in kilograms (since 1 kg of solvent is given in the problem statement).

Molality is defined as 0.299 moles per kilogram (mol/kg).

How is the mole fraction determined?

The formula for KI's mole fraction is:

Mole fraction of KI is equal to n KI/n total.

where n total is the total number of moles in the solution and n KI is the number of moles of KI. The mass of the solvent can be used to determine n total:

m solvent = n total / M solvent

where M solvent is the solvent's molar mass. Given that water has a molar mass of 18.015 g/mol, we obtain:

Total number of moles = 1.00 kg / 18.015 g/mol = 55.49 moles.

The mole fraction of KI is as follows:

The mole fraction of KI is calculated as follows: 0.0054

How is mass percent calculated?

We must first determine the total mass of the solution in order to compute the mass percent:

KI mass plus solvent mass equals the mass of the solution.

The mass of the solution is 49.8 g plus 1000 g, or 1049.8 g.

Thus, the mass percent of KI is:

mass% KI = 100% x (mass of KI / mass of solution)

(49.8 g / 1049.8 g) x 100% = 4.74% is the mass% KI formula.

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4. which factors can affect reaction rate? i. the state of the reactants ii. the frequency of the collisions between particles iii. the average kinetic energy of the particles

Answers

The reaction rate can be affected by the state of the reactants, the frequency of collisions between particles, and the average kinetic energy of the particles in the reactant mixture. Option B is correct.

The state of the reactants can affect the reaction rate. For example, a solid reactant will typically react more slowly than a liquid or gaseous reactant because the molecules in a solid are typically held together more tightly and have less opportunity to come into contact with one another.

The more often the reactant molecules collide with each other, the higher the chance of a successful reaction. Therefore, increasing the frequency of collisions between particles can increase the reaction rate. This can be achieved by increasing the concentration or pressure of the reactants or by increasing the temperature of the system.

The average kinetic energy of the particles in the reactant mixture is directly proportional to the temperature of the system. As the temperature increases, the kinetic energy of the particles increases, and the particles move faster, leading to a higher chance of successful collisions and an increased reaction rate. Option B is correct.

The complete question is

Which factors can affect reaction rate?

I. The state of the reactants

II. The frequency of the collisions between particles

III. The average kinetic energy of the particles

Options:

A. I and II only

B. I, II and III

C. II and III only

D. I and III only

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g determine the oxidation state for each of the elements below. the oxidation state of ... phosphorus ... in ... phosphorous tribromide pbr3 ... is ... . the oxidation state of nitrogen in nitrosyl fluoride nof is . the oxidation state of phosphorus in phosphoryl trichloride pocl3 is .

Answers

1) The oxidation state of phosphorus in phosphorous tribromide is equals to 3.

2) The oxidation state of nitrogen in nitrosyl fluoride is equals to 3.

3) The oxidation state of phosphorus in phosphoryl trichloride is equals to 5.

In chemistry, the oxidation state, or oxidation number of an atom is equal to the total number of electrons removed from an element (that is represents positive oxidation state) or added to an element (represents negative oxidation state) to reach its present state. It describes the degree of oxidation that is loss of electrons of an atom in a chemical compound. We have two compounds and we have to determine the oxidation state of particular atom in compound.

1) Compound is phosphorous tribromide, [tex]PBr_3[/tex]. Let us consider x be the oxidation number of P in PBr₃. Since, the total charge of the complex is zero, the addition of oxidation states of all elements in it must be equal to 0. Therefore, x + 3(-1) = 0, where charge on Br is -1.

=> x = 3

2) Compound is nitrosyl fluoride, NOF

Consider x be the oxidation number of N in NOF. Since, the total charge on the complex is zero, the addition of oxidation states of all elements in it should be equal to 0. Therefore, x + (-1) + (-2) = 0, where charge on F is -1 and Oxygen is (-2).

=> x -1 -2 = 0

=> x = 3

3) Compound is phosphoryl trichloride, POCl₃. Consider x be the oxidation number of P in POCl₃. Since, the total charge on the complex is zero, the sum of oxidation states of all elements in it must be equal to zero. Therefore, x + 3(-1) + (-2) = 0, where charge on Cl is -1 and Oxygen is (-2).

=> x -3 -2 = 0

=> x = 5

Hence, required oxidation state of phosphorus is +5.

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Which of the following environments would not contain fossils?

Answers

Answer: Igneous (chilled from a molten state) and metamorphic (recrystallized by intense heat &/or pressure) do not contain fossils.

When 2.004 g of calcium is heated in pure nitrogen gas, the
sample gains 0.4670 g of nitrogen. Calculate the empirical
formula of the calcium nitride formed.

Answers

The empirical formula of calcium nitride is Ca₇N₆.

The mass of nitrogen that reacted with calcium can be calculated by subtracting the initial mass of nitrogen from the final mass:

mass of nitrogen reacted = final mass of nitrogen - an initial mass of nitrogen

mass of nitrogen reacted = 0.4670 g - 0 g

mass of nitrogen reacted = 0.4670 g

The mass percent of calcium and nitrogen in the compound can be calculated as follows:

mass percent of calcium = (mass of calcium / total mass of compound) x 100%

mass percent of calcium = (2.004 g / (2.004 g + 0.4670 g)) x 100%

mass percent of calcium = 81.11%

mass percent of nitrogen = (mass of nitrogen / total mass of compound) x 100%

mass percent of nitrogen = (0.4670 g / (2.004 g + 0.4670 g)) x 100%

mass percent of nitrogen = 18.89%

We can convert the mass percent of each element to its corresponding mass in grams:

mass of calcium = 81.11 g/100 g x total mass of compound

mass of calcium = 81.11 g/100 g x (2.004 g + 0.4670 g)

mass of calcium = 1.923 g

mass of nitrogen = 18.89 g/100 g x total mass of compound

mass of nitrogen = 18.89 g/100 g x (2.004 g + 0.4670 g)

mass of nitrogen = 0.5485 g

We can then find the ratio of calcium to nitrogen by dividing the mass of each element by its atomic mass and then dividing by the smaller result:

Ca: (1.923 g / 40.08 g/mol) = 0.0478 mol

N: (0.5485 g / 14.01 g/mol) = 0.0392 mol

Dividing both values by 0.0392 mol gives:

Ca:N = 1.218:1

This ratio can be simplified by multiplying both sides by 6 (to get whole number values):

Ca:N = 7:6

The empirical formula of calcium nitride is Ca₇N₆.

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1. For the reaction C + 2H2 → CH4, how many moles of carbon are needed to make 174.6 grams of methane, CH4 ?

Round your answer to the nearest tenth. If you answer is a whole number like 4, report the answer as 4.0

Use the following molar masses. If you do not use these masses, the computer will mark your answer incorrect.:

Element

Molar Mass

Hydrogen

1

Carbon

12

2. 3 Cu + 8HNO3 --> 3 Cu(NO3)2 + 2 NO + 4 H2O

In the above equation how many moles of water can be made when 110.2 grams of HNO3 are consumed?

Round your answer to the nearest tenth. If you answer is a whole number like 4, report the answer as 4.0

Use the following molar masses. If you do not use these masses, the computer will mark your answer incorrect.:

Element

Molar Mass

Hydrogen

1

Nitrogen

14

Copper

63.5

Oxygen

16

Answers

10.91 moles of carbon are needed to make 174.6 grams of methane.

0.9 moles of water can be made when 110.2 grams of HNO3 are consumed.

First, we need to calculate the number of moles of methane produced from the given mass.

Molar mass of CH4 = 12 + 4(1) = 16 g/mol

Number of moles of CH4 = 174.6 g / 16 g/mol = 10.91 mol (rounded to two decimal places)

According to the balanced chemical equation, 1 mole of carbon is required to produce 1 mole of CH4. Therefore, the number of moles of carbon required can be calculated as follows:

Number of moles of C = 10.91 mol × 1 mol C / 1 mol CH4 = 10.91 mol (rounded to two decimal places)

We need to use the given balanced chemical equation to determine the stoichiometry of the reaction between Cu and HNO3, and then use the molar mass of HNO3 to calculate the number of moles consumed and the number of moles of water produced.

According to the balanced chemical equation, 8 moles of HNO3 react to produce 4 moles of H2O. Therefore, the ratio of moles of HNO3 to moles of H2O is 8:4, or 2:1.

Number of moles of HNO3 = 110.2 g / 63.5 g/mol = 1.737 mol (rounded to three decimal places)

Number of moles of H2O = 1.737 mol / 2 = 0.869 mol (rounded to three decimal places).

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How do I solve this?

Answers

The maximum mass of H2O that can be produced from 51.7 g of NH3 and O2 is approximately 34.9 g.

The balanced equation for the reaction between ammonia and oxygen gas to produce nitric oxide and water is:

4NH3(g) + 5O2(g) -> 4NO(g) + 6H2O(g)

According to the balanced equation, 4 moles of NH3 reacts with 5 moles of O2 to produce 6 moles of H2O. Therefore, the mole ratio of NH3 to H2O is 4:6, or 2:3.

If the ratio of NH3 to O2 is smaller than the actual ratio, then NH3 is limiting and vice versa.

Let's first calculate the number of moles of NH3 and O2 present in the reaction mixture:

moles of NH3 = 51.7 g / 17.03 g/mol = 3.03 mol

moles of O2 = 51.7 g / 32.00 g/mol = 1.62 mol

Now let's calculate the ratio of NH3 to O2:

NH3/O2 = 3.03 mol / 1.62 mol = 1.87

The actual ratio of NH3 to O2 is larger than the mole ratio of 2:1, which means that O2 is limiting.

The mole ratio of O2 to H2O is 5:6, which means that 5 moles of O2 react with 6 moles of H2O. Therefore, the maximum number of moles of H2O that can be produced from 1.62 mol of O2 is:

moles of H2O = (6/5) x 1.62 mol = 1.94 mol

Finally, we can calculate the maximum mass of H2O produced using its molar mass:

mass of H2O = 1.94 mol x 18.02 g/mol = 34.9 g

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