The rate law for the reaction 2NO2 + O3 → N2O5 + O2 is rate = K[NO2][O3].
Which one of the following mechanisms Is consistent with this rate law?
A. NO2 + NO2 → N2O2 (fast)
N2O4 + O3 → N2O5 + O2 (slow)
B. NO2 + O3 → NO5 (fast)
NO5 + NO5 → N2O5 + (5/2)O2 (slow)
C. NO2 + O3 → NO3 + O2 (slow)
NO3 + NO2 → N2O5 (fast)
D. NO2 + NO2 → N2O2 + O2 (slow)
N2O2 + O3 → N2O5 (fast)

Answers

Answer 1

Answer:

C. NO2 + O3 → NO3 + O2 (slow)

NO3 + NO2 → N2O5 (fast)

Explanation:

A reaction mechanism represents an amount of elementary steps that explain how a reaction proceeds. The mechanism must explain the experimental rate law. Also, the slow step is the rate determining step.

This rate law is obtained from the multiplication of the reactants in the slow step, thus:

A. NO2 + NO2 → N2O2 (fast)

N2O4 + O3 → N2O5 + O2 (slow)

Rate law:

rate = k [N2O4] [O3]

This mechanism is not consistent with rate law.

B. NO2 + O3 → NO5 (fast)

NO5 + NO5 → N2O5 + (5/2)O2 (slow)

Rate law:

rate = k [NO5]²

This mechanism is not consistent with rate law.

C. NO2 + O3 → NO3 + O2 (slow)

NO3 + NO2 → N2O5 (fast)

Rate law:

rate = k [NO2] [O3]

This mechanism is consistent with rate law.

D. NO2 + NO2 → N2O2 + O2 (slow)

N2O2 + O3 → N2O5 (fast)

Rate law:

rate = k [NO2]²

This mechanism is not consistent with rate law.

Thus, right solution is:

C. NO2 + O3 → NO3 + O2 (slow)

NO3 + NO2 → N2O5 (fast)


Related Questions

How to do this
Q1 and Q2
Only want to know how to find molecular formula

Answers

Answer:

Question 1

A. Empirical formula is C8H8O3

B. Molecular formula is C8H8O3

Question 2.

A. Empirical formula is CH2

B. Molecular formula is C4H8

Explanation:

Question 1:

A. Determination of the empirical formula:

Carbon (C) = 63.2%

Hydrogen (H) = 5.26%

Oxygen (O) = 31.6%

Divide by their molar mass

C = 63.2/12 = 5.27

H = 5.26/1 = 5.26

O = 31.6/16 = 1.975

Divide by the smallest

C = 5.27/1.975 = 2.7

H = 5.26/1.975 = 2.7

O = 1.975/1.975 = 1

Multiply through by 3 to express in whole number

C = 2.7 x 3 = 8

H = 2.7 x 3 = 8

O = 1 x 3 = 3

Therefore, the empirical formula for the compound is C8H8O3

B. Determination of the molecular formula of the compound.

From Avogadro's hypothesis, 1 mole of any substance contains 6.02×10²³ molecules.

Now from the question given, we were told that 1 molecule of the compound has a mass of 2.53×10¯²² g.

Therefore, 6.02×10²³ molecules will have a mass of = 6.02×10²³ x 2.53×10¯²² = 152.306 g

Therefore, 1 mole of the compound = 152.306 g

The molecular formula of the compound can be obtained as follow:

[C8H8O3]n = 152.306

[(12x8) + (1x8) + (16x3)]n = 152.306

[(96 + 8 + 48 ]n = 152.306

152n = 152.306

Divide both side by 152

n = 152.306/152

n = 1

The molecular formula => [C8H8O3]n

=> [C8H8O3]1

=> C8H8O3

Question 2:

A. Determination of the empirical formula of the compound.

Mass sample of compound = 0.648 g

Carbon (C) = 0.556 g

Mass of Hydrogen (H) = mass sample of compound – mass of carbon

Mass of Hydrogen (H) = 0.648 – 0.556

Mass of Hydrogen (H) = 0.092 g

Thus, the empirical formula can be obtained as follow:

C = 0.556 g

H = 0.092 g

Divide by their molar mass

C = 0.556/12 = 0.046

H = 0.092/1 = 0.092

Divide by the smallest

C = 0.046/0.046 = 1

H = 0.092/0.046 = 2

Therefore, the empirical formula of the compound is CH2.

B. Determination of the molecular formula of the compound.

Mole of compound = 0.5 mole

Mass of compound = 28.5 g

Molar mass of compound =.?

Mole = mass /Molar mass

0.5 = 28.5/ Molar mass

Cross multiply

0.5 x molar mass = 28.5

Divide both side by 0.5

Molar mass = 28.5/0.5 = 57 g/mol

Thus, the molecular formula of compound can be obtained as follow:

[CH2]n = 57

[12 + (1x2)]n = 57

14n = 57

Divide both side by 14

n = 57/14

n = 4

Molecular formula => [CH2]n

=> [CH2]4

=> C4H8.

Identify some other substances (besides KCl) that might give a positive test for chloride upon addition of AgNO3. Based on the reactant used in your experiment, do you think it is reasonable to exclude these types of substances as contaminants that would give a false positive when you tested your reaction residue to verify that it is KCl?

Answers

Answer:

Other substances that give a positive test with AgNO3 are other chlorides present, iodides and bromide. However iodides and bromides have different colours hence they will not give a false positive test for KCl. Other chlorides present may lead to a false positive test for KCl.

Explanation:

In the qualitative determination of halogen ions, silver nitrate solution is used. Various halide ions give various colours of precipitate with silver nitrate. Chlorides yield a white precipitate, bromides yield a cream precipitate while iodides yield a yellow precipitate. All these ions or some of them may be present in the system.

However, if other chlorides are present, they will also yield a white precipitate just as KCl leading to a false positive test for KCl. Since other halogen ions yield precipitates of different colours, they don't lead to a false test for KCl. We can exclude other halides from the tendency to lead us to a false positive test for KCl but not other chlorides.

In the qualitative analysis test of chloride upon addition of AgNO₃, presence of diffrerent chloride salts other than KCl will gives false test.

How do we get on addition of KCl in AgNO₃?

On adding halogens on the silver nitrate solution we will get the precipitate of diffrent colors of diffrent halides.

Chlorides will gives white color precipiate in the silver nitrate solution, so KCl and other chlorides will also give white color precipitate.Bromides will gives cream color precipitate.Iodides will gives yellow color precipitate.

So, presence of diffrent chloride salt in the silver nitrate solution in addition with KCl will gives a false positive result for the test.

To know more about qualitative analysis, visit the below link:

https://brainly.com/question/1779681

Which of the following statements is not true for an exothermic reaction? Question options: The products have a higher heat content than the reactants. The temperature of the reaction system increases. The temperature of the surroundings increases. Heat passes from the reaction system to the surroundings. The enthalpy change for the reaction is negativ

Answers

Answer:

The products have a higher heat content than the reactants.

Explanation:

The statement above is not true for an exothermic reaction because in an exothermic reaction heat is released to the surroundings. This simply means that the total energy of the products is less than that of the reactants.

A plot of 1/[BrO-] vs. time is linear and the slope is equal to 0.056 M-1s-1. If the initial concentration of BrO- is 0.65 M, how long will it take one-half of the BrO- ion to react

Answers

Answer:

time taken for one-half of the BrO⁻ ion to react is t= 27.45 secs

Explanation:

equation of reaction

3BrO⁻(aq) → BrO₃⁻(aq) + 2Br⁻(aq) (second order reaction)

given

the slope of the graph is 0.056M⁻¹s⁻¹ = k(constant)

initial concentration [A]₀ = 0.65M

for second order reaction,we can calculate the time taken for one-half of the BrO- ion to react using:

[tex]\frac{1}{[A]}[/tex] =[tex]\frac{1}{[A]}[/tex]₀ ⁺ k × t

where initial concentration [A]₀ = 0.65M

[A] = [A]₀÷2 = 0.325M

[tex]\frac{1}{0.325M}[/tex] = [tex]\frac{1}{0.65M}[/tex] + 0.056M⁻¹s⁻¹ × t

3.077= 1.54 + 0.056t

3.077-1.54=0.056t

1.537=0.056t

t= 27.45 secs

oxygen get stable configuration by ____________two electrons



please give the answer as fast as you can


please ​

Answers

Answer:

gaining two electrons

Explanation:

electron configuration

2:6

so add two to 6 to get stable 2:8

Gaining electrons easy

Calculate how much acetylene (C2H2) will be produced from 358 g of H2O and an excess of CaC2 if the percent yield for this reaction is 94.5%. CaC2 2 H2O --> C2H2 Ca(OH)2

Answers

Answer:

244.7 g of acetylene

Explanation:

The balanced reaction equation is shown below;

2H20 (l) + CaC2 (s) → Ca(OH)2 (s) + C2H2 (g)

Number of moles of were reacted = reacting mass/molar mass = 358g/18gmol-1 = 19.89 moles of water

From the balanced reaction equation;

2 moles water yields 1 mole of acetylene

19.89 moles of water will yield 19.89 × 1/2 = 9.945 moles of acetylene

Theoretical yield of acetylene = 9.945 moles of acetylene × molar mass of acetylene

Molar mass of acetylene = 26.04 g/mol

Theoretical yield of acetylene = 9.945 moles of acetylene × 26.04 g/mol

Theoretical yield of acetylene = 258.9678 g of acetylene

% yield = actual yield/ theoretical yield × 100

94.5 = actual yield/258.9678 g × 100

Actual yield= 94.5 × 258.9678 g/100

Actual yield = 244.7 g of acetylene

Differentiate between
expansion of solid and liquid​

Answers

In a liquid, the expansion is a little more than in

solids. The bonds in a liquid are weaker than in a

solid, so as you heat up a liquid, the particles can

move around each other faster and in so doing,

move further apart. Solids and liquids occupy a

'set' volume at a certain temperature.

2
Select the correct answer
in a redex reaction, what folle does the reducing agent play?

OA. it gives up electrons
OB. it keeps electrons
OC. it takes electrons
OD. it takes onygen atoms

Answers

Answer:

A. it gives up electrons

Explanation:

In a redox reaction, the reducing agent is the element or compound that undergoes oxidation and gives up electrons. The oxidizing agent is the element or compound that undergoes reduction and gains electrons.

Hope that helps.

Potassium iodide reacts with lead(II) nitrate in the following precipitation reaction: 2 KI(aq) + Pb(NO3)2(aq) → 2 KNO3(aq) + PbI2(s) What minimum volume of 0.400 M potassium iodide solution is required to completely precipitate all of the lead in 310.0 mL of a 0.112 M lead(II) nitrate solution?

Answers

Answer:

0.1736 L or 173.6 ml

Explanation:

Number of moles of lead II nitrate is obtained by;

Number of moles = concentration × volume of solution

Concentration= 0.112 M

Volume of solution= 310 ml

n= 0.112 × 310/1000

n= 0.03472 moles

From the reaction equation;

2 moles of potassium iodide reacted with 1 mole of lead II nitrate

x moles of potassium iodide will react with 0.03472 moles of lead II nitrate

x= 2 × 0.03472 moles= 0.06944 moles of potassium iodide

Volume of potassium iodide solution = number of moles/ concentration = 0.06944/ 0.4

Volume of potassium iodide solution= 0.1736 L or 173.6 ml

Need help finding major products

Answers

Answer:

Explanation:

RX + AgNO₃ = R⁺ ( carbocation ) + AgX + NO₃⁻

C₂H₅OH ( a nucleophile ) + R⁺ = ROC₂H₅

C₅H₁₁X + AgNO₃ = C₅H₁₁⁺ + AgX + NO₃⁻

In the first case carbocation produced is CH₃CH₂CH₂CH₂CH₂⁺

CH₃CH₂CH₂CH₂CH₂⁺ ⇒  CH₃CH₂CH₂C⁺HCH₃ ( secondary carbocation more stable )

CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃

Hence option D is correct .

b )

In the second case carbocation produced is

CH₃CH₂CH₂CH⁺CH₃

CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃

The product formed is same as in case of first

Option B is correct

Q1. Calculate the amount of copper produced in 1.0 hour when aqueous CuBr2 solution was electrolyzed by using a current of 4.50 A. Q2. In another electroplating experiment, if electric current was passed for 3 hours and 2.00 g of silver was deposited from a AgNO3 solution, what was the current used in amperes

Answers

Answer:

[tex]\boxed{\text{Q1. 3.6 g; Q2. 0.2 A}}[/tex]

Explanation:

Q1. Mass of Cu

(a) Write the equation for the half-reaction.

Cu²⁺ + 2e⁻ ⟶ Cu

The number of electrons transferred (z) is 2 mol per mole of Cu.

(b) Calculate the number of coulombs

q  = It  

[tex]\text{t} = \text{1.0 h} \times \dfrac{\text{3600 s}}{\text{1 h}} = \text{3600 s}\\\\q = \text{3 C/s} \times \text{ 3600 s} = \textbf{10 800 C}[/tex]

(c) Mass of Cu

We can summarize Faraday's laws of electrolysis as

[tex]\begin{array}{rcl}m &=& \dfrac{qM}{zF}\\\\& = &\dfrac{10 800 \times 63.55}{2 \times 96 485}\\\\& = & \textbf{3.6 g}\\\end{array}\\\text{The mass of Cu produced is $\boxed{\textbf{3.6 g}}$}[/tex]

Note: The answer can have only two significant figures because that is all you gave for the time.

Q2. Current used

(a) Write the equation for the half-reaction.

Ag⁺ + e⁻ ⟶ Ag

The number of electrons transferred (z) is 1 mol per mole of Ag.  

(a) Calculate q

[tex]\begin{array}{rcl}m &=& \dfrac{qM}{zF}\\\\2.00& = &\dfrac{q \times 107.87}{1 \times 96 485}\\\\q &=& \dfrac{2.00 \times 96485}{107.87}\\\\& = & \textbf{1789 C}\\\end{array}[/tex]

(b) Calculate the current

t = 3 h = 3 × 3600 s = 10 800 s

[tex]\begin{array}{rcl}q&=& It\\1789 & = & I \times 10800\\I & = & \dfrac{1789}{10800}\\\\& = & \textbf{0.2 A}\\\end{array}\\\text{The current used was $\large \boxed{\textbf{0.2 A}}$}[/tex]

Note: The answer can have only one significant figure because that is all you gave for the time.

Question 14 of 25
What type of reaction is BaCl2 + Na,504 → 2NaCl + Baso,?
A. Single-replacement
B. Synthesis
C. Double-replacement
D. Decomposition

Answers

double displacement

bcoz each of the reactants combines with other reactants to obtain the product

g If attempting to dissolve both silver bromide and silver chloride in aqueous solution through complex ion formation, which data will be the most relevant?

Answers

Answer:

Kf

Explanation:

The stability constant Kf of a given complex specie is an equilibrium constant that represents the formation of that particular complex specie in solution. It measures the strength of the interaction between the ligands and metal that form the particular complex specie. The magnitude of Kf shows how easily a complex specie is formed in solution.

Hence if I want to dissolve the bromides or chlorides of silver which are ordinarily insoluble in water by means of complex formation, the magnitude of the stability constant for each particular complex specie is important as it gives information regarding the thermodynamic feasibility of the process.

8.670 mL + 9.87 mL=​

Answers

Answer:18.4 ML

Explanation:

easy add

how are mass and weight affected in chemical reactions?

Answers

Answer:

How the chemical reacts

Explanation:

Which best describes the total mass of a sample of water when it condenses
from a liquid to a gas?
A. The mass is less because the water molecules get closer together
and take up more space.
B. The mass is the same because the decrease in energy equals the
increase in the number of molecules.
C. The mass is the same because water molecules are not created or
destroyed during a phase change.
D. The mass is greater after water condenses because the mass of
the molecules increases.

Answers

Answer:

Its C I hopefully help you

Yes he have reason the answer is C

Provide the structures of the fragments that result when the molecular ion of 2-heptanone undergoes fragmentation via McLafferty rearrangement. Include charges and single electrons.

Answers

Answer:

See explanation

Explanation:

We have to start, remembering the mechanism behind the McLafferty rearrangement. The hydrogen in the gamma carbon (in this case, carbon 5) would be removed by a heterolytic rupture due to the cation-radical placed in the oxygen of the carbonyl group. Then we will have several heterolytic ruptures. Between carbons alpha and beta (in this case, 4 and 3) and a rupture in the carbonyl group. Due to these ruptures, two double bonds would be formed. One double bond in the alcohol cation-radical and the other one in the alkene.

See figure 1

I hope it helps!

Benzene boils at 80.10 °C and has a molal boiling constant, k b, of 2.53 C/m. When 2.15 g of a compound is dissolved in 20.0 g of benzene, the resulting solution has a boiling point of 81.10 °C. What is the molality of the solute?

Answers

Answer:

[tex]m=0.395mol/kg[/tex]

Explanation:

Hello,

This is a problem about boiling point elevation which is modeled via:

[tex]\Delta T=i*m*Kb[/tex]

Whereas for this solvent (nonpolar, nonionizing), the van't Hoff factor is one. In such a way, the molality of the solute is simply computed as shown below:

[tex]m=\frac{\Delta T}{Kb}=\frac{(81.10-80.10)\°C}{2.53\°C/m} \\\\m=0.395mol/kg[/tex]

In this manner, we can also compute the molar mass of the solute by noticing 20.0 g (0.020 kg) of benzene were used:

[tex]n=0.395mol/kg*0.020kg=7.9x10^{-3} mol[/tex]

And considering the 2.15 g of the solute:

[tex]Molar\ mass=\frac{2.15g}{7.9x10^{-3}mol}\\ \\Molar\ mass=271.975g/mol[/tex]

Best regards.

Calculate the pH of a buffer solution obtained by dissolving 18.0 g of KH2PO4(s) and 35.0 g of Na2HPO4(s) in water and then diluting to 1.00 L.

Answers

Answer:

pH of the buffer is 7.48

Explanation:

The H₂PO₄⁻/HPO₄²⁻ buffer has a pKa of 7.21. You can find pH of this buffer following H-H equation:

pH = pKa + log [A⁻] / [HA]

pH = 7.21 + log [HPO₄²⁻] / [ H₂PO₄⁻]

Where [] represents molarity of each specie of the buffer and, as volume is 1.00L, also represents its moles.

Thus, to find pH of the buffer we need to calculate moles of each specie, thus

Moles of 18.0g of KH₂PO₄(Molar mass: 136.086g/mol) = moles of H₂PO₄⁻ are:

18.0g KH₂PO₄ ₓ (1mol / 136.086g) = 0.132 moles of KH₂PO₄= H₂PO₄⁻

Moles of 35.0g of Na₂HPO₄(Molar mass: 141.96g/mol) = moles of HPO₄²⁻ are:

35.0g Na₂HPO₄ ₓ (1mol / 141.96g) = 0.2465 moles of Na₂HPO₄= HPO₄²⁻

Replacing in H-H equation:

pH = 7.21 + log [HPO₄²⁻] / [ H₂PO₄⁻]

pH = 7.21 + log [0.2465] / [0.132]

pH = 7.48

pH of the buffer is 7.48

Iron(II) is available to bond with chloride ion. How many of each type of ion will bond to form an ionic compound?

A) 3 iron(II), 1 chloride

B) 2 iron(II), 3 chloride

C) 2 iron(II), 1 chloride

D) 1 iron(II), 2 chloride

Answers

Answer:

D) 1 iron(II), 2 chloride

Explanation:

Iron II chloride is the compound; FeCl2. It is formed as follows, ionically;

Fe^2+(aq) + 2Cl^-(aq) -----> FeCl2

The formation of one mole of FeCl2 involves the reaction one mole of iron and two moles of chloride ions. This means that in FeCl2, the ratio of iron to chlorine is 1:2 as seen above.

Therefore there is one iron II ion and two chloride ions in each mole of iron II chloride, hence the answer.

what is the meaning of the word tetraquark?​

Answers

Answer:

A tetraquark in physics is an exotic meson composed of four valence quarks.

Explanation:

It has been suspected to be allowed by quantum chromodynamics, the modern story of strong interactions.

Hope it helps.

Consider the reaction between two solutions, X and Y, to produce substance Z: aX + bY → cZ When 500. mL of a 1.8 M solution of X is combined with 500. mL of a 1.8 M solution of Y, the resulting solution has a concentration of 0.60 M Y and 0.60 M Z. No more of substance X remains in the flask. 1. How many moles each of X and Y are present before the reaction occurs? 2. How many moles each of Y and Z are present after the reaction occurs? 3. How many moles each of X and Y have reacted? 4. What is the balanced equation for this reaction?

Answers

Answer:

1. 0.90 are the initial moles of X and Y

2. 0.60 moles are the moles of Y and Z after the reaction

3. 0.90 moles of X and 0.30 moles of Y

4. 3X + 1Y → 2Z

Explanation:

1. For the reaction, initial moles of X and Y are:

500mL = 0.500L × (1.8 moles / L) = 0.90 are the initial moles of X and Y

2. After the reaction. The total volume is 500mL + 500mL = 1L

Moles Y and Z = 1L × (0.60 moles / 1L) = 0.60 moles are the moles of Y and Z after the reaction

3. As there is no moles of X after the reaction, all X reacts, that is 0.90 moles of X. And moles of Y that reacts are 0.90 mol - 0.60mol = 0.30 moles of Y

4. That means 3 moles of X reacts per mole of Y 0.90/0.30 = 3. Also, 2 moles of Z are produced per mole of Y 0.60/0.30 = 2.

That means balanced equation is:

aX + bY → cZ

3X + 1Y → 2Z

1. If a question states "The patching material costs NASA $306/in2 …", the conversion factor in this statement is: Recognizing — Equation statement: $306 = _____ ___________

Answers

Answer:

$306 = Cost of 1 square inch of the patching material in question.

$306 = 1 in²

Explanation:

The conversion factor is am expression that is used to prove the equivalence of some quantities with different units.

The conversion factor basically converts from one quantity to another.

For this question, the conversion factor given for the patching material is $306/in².

This means that the patching material costs $306 for every square inch, the equation for the conversion is thus

$306 = 1 in² of the patching material.

Hope this Helps!!!

A. Identify the structure drawn below.

Answers

Answer:

Hexane

Explanation:

You have a carbon structure with only single bonds.  This means that the name will end in -ane.

There are 6 carbon atoms.  This means that the name will begin with hex-.

The structure is hexane.

Calculate the amount of HCl in grams required to react with 3.75 g of CaCO3 according to the following reaction: CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g)

Answers

Answer:

The correct answer is 2.75 grams of HCl.

Explanation:

The given balanced equation is:  

CaCO₃ (s) + 2HCl (aq) ⇒ CaCl₂ (aq) + H₂O (l) + CO₂ (g)

Based on the given information, one mole of calcium carbonate is reacting with two moles of HCl. The molecular mass of HCl is 36.5 grams, thus, the mass of 2 moles of HCl will be, 36.5 × 2 = 73 grams

The molecular mass of CaCO₃ is 100 gram per mole, that is, the mass of 1 mole of CaCO₃ is 100 grams, therefore, the mass of HCl required for reacting with 3.75 grams of CaCO₃ will be,  

= 3.75 × 2 × 36.5 / 100 = 2.74 grams of HCl.  

Example: One liter of saturated calcium fluoride
solution contains 0.0167 gram of CaFat 25°C.
Calculate the molar solubility of, and Ksp for, CaF2.​

Answers

Answer:

[tex]Molar\ solubility=2.14x10^{-4}M[/tex]

[tex]Ksp=3.91x10^{-11}[/tex]

Explanation:

Hello,

In this case, given that 0.0167 grams of calcium fluoride in 1 L of solution form a saturated one, we can notice it is the solubility, therefore, the molar solubility is computed by using the molar mass of calcium fluoride (78.1 g/mol):

[tex]Molar\ solubility=\frac{0.0167gCaF_2}{1L}*\frac{1molCaF_2}{78.1gCaF_2} \\\\Molar\ solubility=2.14x10^{-4}M[/tex]

Next, since dissociation equation for calcium fluoride is:

[tex]CaF_2(s)\rightarrow Ca^{2+}(aq)+2F^-(aq)[/tex]

The equilibrium expression is:

[tex]Ksp=[Ca^{2+}][F^-]^2[/tex]

We can compute the solubility product by remembering that the concentration of both calcium and fluoride ions equals the molar solubility, thereby:

[tex]Ksp=(2.14x10^{-4})(2*2.14x10^{-4})^2\\\\Ksp=3.91x10^{-11}[/tex]

Regards.

Calculate the equilibrium concentrations of N2O4 and NO2 at 25 ∘C in a vessel that contains an initial N2O4 concentration of 0.0655 M . The equilibrium constant Kc for the reaction N2O4(g)⇌2NO2(g) is 4.64×10−3 at 25 ∘C. Express your answers using four decimal places separated by a comma.

Answers

Answer:

[N2O4] = 0.0573M

[NO2] = 0.0163M

Explanation:

The equilibrium of N2O4 is:

N2O4(g)⇌2NO2(g)

Where Kc is defined as:

Kc = 4.64x10⁻³ = [NO2]² / [N2O4]

When you add just N2O4, the reaction will occurs until  [NO2]² / [N2O4] = 4.64x10⁻³. Here, the system reaches equilibrium.

That means if 0.0655M N2O4 begin reaction, in equilibrium we will have:

[N2O4] = 0.0655M - X

[NO2] = 2X

Where X is defined as reaction coordinate

Replacing in Kc:

4.64x10⁻³ = [NO2]² / [N2O4]

4.64x10⁻³ = [2X]² / [0.0655-X]

3.0392x10⁻⁴ - 4.64x10⁻³X = 4X²

3.0392x10⁻⁴ - 4.64x10⁻³X - 4X² = 0

Solving for X:

X = -0.0093 → False solution. there is no negative concentrations

X = 0.008156M → Right solution.

Replacing X, equilibrium concentrations are:

[N2O4] = 0.0655M - X

[NO2] = 2X

[N2O4] = 0.0573M[NO2] = 0.0163M

Reduction occurs at which electrode?

Answers

Answer:

negative charge electrode

Explanation:

In cathode positive ions are picked up to perform reduction.At the same time negative ions are picked up at anode to get oxidized from electrolyte.

Answer:

The electrode that removes ions from the solution :) a p e x

Please help me out ASAP!


What is meant by concentration?​

Answers

Answer:

concentration is the abundance of a constituent divided by the total volume of a mixture.

14. Which group of diamagnetic transition metals exhibits trends in density and melting points that don't match the same trends seen in
other groups?
A. Group 3
B. Group 12
C. Group 7
D. Group 11​

Answers

Answer:

Group 12

Explanation:

Group 12 transition metals are diamagnetic. They behave properties that distinguish them. They naturally have twelve electrons hence their outermost shell is fully filled.

Transition metals have high densities which increases down the group. However, the increase in density of transition elements of group 12 varies with temperature at a rate that is quite different from other transition elements. Hence the differences in the value of melting points and density changes by only a very small amount as you come down group 12 compared to other groups of transition elements.

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