Answer:
rate of recrystallization = 4.99 × 10⁻³ min⁻¹
Explanation:
For Avrami equation:
[tex]y = 1-e ^{(-kt^n)} \\ \\ e^{(-kt^n)} = 1-y\\ \\ -kt^n = In(1-y) \\ \\ k = \dfrac{-In(1-y)}{t^n}[/tex]
To calculate the value of k which is a dependent variable for the above equation ; we have:
[tex]k = \dfrac{-In(1-0.40)}{200^{2.5}}[/tex]
[tex]k = 9.030 \times 10 ^{-7}[/tex]
The time needed for 50% transformation can be determined as follows:
[tex]y = 1-e ^{(-kt^n)} \\ \\ e^{(-kt^n)} = 1-y\\ \\ -kt^n = In(1-y) \\ \\ t =[ \dfrac{-In(1-y)}{k}]^{^{1/n}}[/tex]
[tex]t_{0.5} =[ \dfrac{-In(1-0.4)}{9.030 \times 10^{-7}}]^{^{1/2.5}}[/tex]
= 200.00183 min
The rate of reaction for Avrami equation is:
[tex]rate = \dfrac{1}{t_{0.5}}[/tex]
[tex]rate = \dfrac{1}{200.00183}[/tex]
rate = 0.00499 / min
rate of recrystallization = 4.99 × 10⁻³ min⁻¹
A student accidentally let some of the vapor escape the beaker. As a result of this error, will the mass of naphthalene you record be too high, too low, or unaffected? Why?
Answer:
too low
Explanation:
If our aim is to recover the naphthalene and measure its mass after separation, then we must not allow any vapour to escape.
Naphthalene is a sublime substance, it can be separated by sublimation. It changes directly from solid to gas. This vapour must be kept securely so that none of it escapes. If part of the naphthalene vapour happens to escape accidentally, then the measured mass of naphthalene will be too low compared to the mass of naphthalene originally present in the mixture.
Solid MgO has the same crystal structure as NaCl. How many oxide ions surround each Mg * ion as nearest neighbors in MgO? 4 none of these
Answer:
The number of oxide ions as the nearest neighbors of [tex]{\rm{M}}{{\rm{g}}^{{\rm{2 + }}}}[/tex] ions are known to be as six
Explanation:
The regularity of a crystal structure leads to the idea of space lattice.In order to explain this concept, let us consider a crystal of NaCl, It consists of a perfectly regular arrangement of sodium ions and chlorine ions.
If we represent the position of each Na+ in the crystal by a point marked x the result will be a regular three dimensional network of points. This will be the space lattice of Na+ in the crystal NaCl. The symmetry of the combined lattice determined the symmetry of the crystal as a whole.
The space lattice of a crystal may be considered as built up of a three dimensional basic pattern called unit cell. The unit cell is a repeat unit which generates the whole pattern in three dimensions of the unit cell.
In Solid MgO , the crystal structure which is used to predict the properties of the material, have the same structure as that of NaCl.
The obtain the structure of a face centered cubic FCC unit cell where the ions occupy the corner of the cube and the center of each face of the cube.
The number of oxide ions as the nearest neighbors of [tex]{\rm{M}}{{\rm{g}}^{{\rm{2 + }}}}[/tex] ions are known to be as six. As a result of that , the coordination number of [tex]{\rm{M}}{{\rm{g}}^{{\rm{2 + }}}}[/tex] ions is six.
Through what basic mechanism is 2-methylcyclohexanol converted to 1-bromo-1-methylcyclohexane when treated with HBr
Answer:
Sn1 mechanism reaction
Explanation:
In this case, we have to start with the protonation of the "OH" group by the attack of the lone pairs in the alcohol group to the "H" in the HBr producing a positive charge in the oxygen. Then, water is produced and a carbocation is generated. This carbocation can be stabilized by a hydride shift. We can move a hydrogen atom to the positive charge and we will obtain a tertiary carbocation. Finally, the [tex]Br^- [/tex] will attack to produce the final halide.
See figure 1.
I hope it helps!
A saturated solution was formed when 5.16×10−2 L of argon, at a pressure of 1.0 atm and temperature of 25 ∘C, was dissolved in 1.0 L of water.
Calculate the Henry's law constant for argon. it must be im M/atm
Answer:
The Henry's law constant for argon is [tex]k=2.11*10^{-3}\frac{ M}{atm}[/tex]
Explanation:
Henry's Law indicates that the solubility of a gas in a liquid at a certain temperature is proportional to the partial pressure of the gas on the liquid.
C = k*P
where C is the solubility, P the partial pressure and k is the Henry constant.
So, being the concentration [tex]C=\frac{ngas}{V}[/tex]
where ngas is the number of moles of gas and V is the volume of the solution, you must calculate the number of moles ngas. This is determined by the Ideal Gas Law: P*V=n*R*T where P is the gas pressure, V is the volume that occupies, T is its temperature, R is the ideal gas constant, and n is the number of moles of the gas. So [tex]n=\frac{P*V}{R*T}[/tex]
In this case:
P=PAr= 1 atmV=VAr= 5.16*10⁻² LR=0.082 [tex]\frac{atm*L}{mol*K}[/tex]T=25 °C=298 °KThen:
[tex]n=\frac{1 atm*5.16*10^{-2} L}{0.082 \frac{atm*L}{mol*K} *298K}[/tex]
Solving:
n= 2.11 *10⁻³ moles
So: [tex]C=\frac{ngas}{V}=\frac{2.11*10^{-3} moles}{1 L} =2.11*10^{-3} \frac{moles}{L}= 2.11*10^{-3} M[/tex]
Using Henry's Law and being C=CAr and P =PAr:
2.11*10⁻³ M= k* 1 atm
Solving:
[tex]k=\frac{2.11*10^{-3} M}{1 atm}[/tex]
You get:
[tex]k=2.11*10^{-3}\frac{ M}{atm}[/tex]
The Henry's law constant for argon is [tex]k=2.11*10^{-3}\frac{ M}{atm}[/tex]
The Henry's law constant for argon gas in 1 litre of water is 2.1 × 10⁻³M/atm.
What is Henry's law?Henry's law of gas states that solubility of a gas in any liquid at particular temperature is directly proportional to the partial pressure of the gas.
C∝P
C = kP, where
k = Henry's constant
P = partial pressure of gas
C is the solubility and it is present in the form of concentration and will be calculated as:
C = n/V
n = no. of moles
V = volume
And moles of the gas will be calculated by using the ideal gas equation as:
PV = nRT
n = (1)(5.16×10⁻²) / (0.082)(298) = 2.1 × 10⁻³ moles
And Concentration in liquid will be:
C = 2.1 × 10⁻³mol / 1L = 2.1 × 10⁻³ M
Now we put all these values in the first equation to calculate the value of k as:
k = (2.1 × 10⁻³M) / (1atm) = 2.1 × 10⁻³M/atm
Hence required value of k is 2.1 × 10⁻³M/atm.
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What's the electron configuration of a Ca+2 ion?
A. [Kr]
B. [Ar]
C. [Ne]
D. [He]
Answer:
B
Explanation:
The Ca+2 ion means that 2 electrons have been given away. So when you try and find the answer, you have to count backwards from Calcium. When you do, you get K+ first and then Argon which is either column 8 orc column 18 depending on your periodic table.
The element you hit is Argon.
The answer is B
Answer:
B ar
Explanation:
pen foster answer
An aqueous solution containing 5.06 g of lead(II) nitrate is added to an aqueous solution containing 6.03 g of potassium chloride.Enter the balanced chemical equation for this reaction. Be sure to include all physical states.balanced chemical equation:What is the limiting reactant?lead(II) nitratepotassium chlorideThe percent yield for the reaction is 82.9% . How many grams of the precipitate are formed?precipitate formed:gHow many grams of the excess reactant remain?excess reactant remaining:
Answer:
Pb(NO3)2(aq) + 2KCl(aq) ------> 2KNO3(aq) + PbCl2(s)
3.52 g of PbCl2
3.76 g of KCl
Explanation:
The equation of the reaction is;
Pb(NO3)2(aq) + 2KCl(aq) ------> 2KNO3(aq) + PbCl2(s)
Number of moles of Pb(NO3)2 =mass/molar mass 5.06g/331.2 g/mol = 0.0153 moles
Number of moles of KCl= mass/ molar mass= 6.03g/74.5513 g/mol= 0.081 moles
Next we obtain the limiting reactant; the limiting reactant yields the least number of moles of products.
For Pb(NO3)2;
1 mole of Pb(NO3)2 yields 1 mole of PbCl2
Therefore 0.0153 moles of Pb(NO3)2 yields 0.0153 moles of PbCl2
For KCl;
2 moles of KCl yields 1 mole of PbCl2
0.081 moles of KCl yields 0.081 moles ×1/2 = 0.041 moles of PbCl2
Therefore Pb(NO3)2 is the limiting reactant.
Theoretical Mass of precipitate obtained = 0.0153 moles of PbCl2 × 278.1 g/mol = 4.25 g of PbCl2
% yield = actual yield/theoretical yield ×100
Actual yield = % yield × theoretical yield /100
Actual yield= 82.9 ×4.25/100
Actual yield = 3.52 g of PbCl2
If 1 mole of Pb(NO3) reacts with 2 moles of KCl
0.0153 moles of Pb(NO3)2 reacts with 0.0153 moles × 2 = 0.0306 moles of KCl
Amount of excess KCl= 0.081 moles - 0.0306 moles = 0.0504 moles of KCl
Mass of excess KCl = 0.0504 moles of KCl × 74.5513 g/mol = 3.76 g of KCl
Which is a nonpolar molecule?
Answer:
Explanation:
A nonpolar molecule has no separation of charge, so no positive or negative poles are formed. In other words, the electrical charges of nonpolar molecules are evenly distributed across the molecule. Nonpolar molecules tend to dissolve well in nonpolar solvents, which are frequently organic solvents. The answer is hydrogen cyanide.
10. What effect does temperature have on molecular motion? Using this explanation, explain why both pressure and volume can decrease with decreasing temperature.
Answer:
If the temperature increases the molecular movement as well, and if it increases the same it will happen with the molecular movement.
Pressure, volume and temperature are three factors that are closely related since they increase the temperature, the pressure usually decreases due to the dispersion of the molecules that can be generated, so the volume also increases.
If the temperature drops, the material becomes denser, its molecules do not collide with each other, their volume and pressure increases.
Explanation:
The pressure is related to the molecular density and the movement that these molecules have.
The movement is regulated by temperature, since if it increases, the friction and collision of the molecules also.
On the other hand, the higher the volume, the less pressure there will be on the molecules, since they are more dispersed among themselves.
(in the opposite case that the volume decreases, the pressure increases)
If the average rate of the reaction A --->2B C is 1M/s, what is the average rate of formation (in M/s) of B over that same period of time
Answer:
[tex]r_B=2M/s[/tex]
Explanation:
Hello,
In this case, since the average rate of reaction is related with the consumption of A which has an stoichiometric coefficient of 1, the rate of formation of B will be:
[tex]r_B=2*1M/s\\\\r_B=2M/s[/tex]
By cause of the stoichiometric coefficient of B which doubles the average rate.
Best regards.
Compute the equilibrium constant at 25 ∘C for the reaction between Sn2+(aq) and Cd(s), which form Sn(s) and Cd2+(aq). Express your answer using two significant figures
Answer:
6.1×10^8
Explanation:
The reaction is;
Sn^2+(aq) + Cd(s) -----> Sn(s) + Cd^2+(aq)
E°cell = E°cathode - E°anode
E°cathode= -0.14 V
E°anode= -0.40 V
E°cell = -0.14-(-0.40)
E°cell= -0.14+0.40
E°cell= 0.26 V
But
E°cell= 0.0592/n log K
E°cell= 0.0592/2 log K
0.26= 0.0296log K
log K = 0.26/0.0296
log K= 8.7838
K= Antilog (8.7838)
K= 6.1×10^8
Given that Ag-107 (51.839% abundance) and the mass ratio: Ag-109/Ag-107=1.0187.
Calculate the mass of Ag-107. (Atomic mass of Ag = 107.87 amu)
Answer:
Atomic mass of Ag-107 = 106.94 amu
Explanation:
Let the mass of Ag-107 be y
Since the mass ratio of Ag-109/Ag-107 is 1.0187, the mass of Ag-109 is 1.0187 times heavier than the mass of Ag-107
Mass of Ag-109 = 1.0187y
Relative atomic mass of Ag = sum of (mass of each isotope * abundance)
Relative atomic mass of Ag = 107.87
Abundance of Ag-107 = 51.839% = 0.51839
Abundance of Ag-109 = 41.161% = 0.48161
107.87 = (y * 0.51839) + (1.018y * 0.48161)
107.87 = 0.51838y + 0.49027898y
107.87 = 1.00865898y
y = 107.87/1.00865898
y = 106.94 amu
Therefore, atomic mass of Ag-107 = 106.94 amu
Sodium oxide has the chemical formula Na2O. What is the oxidation number of oxygen in this compound? Provide your answer below: ___
Answer: The oxidation number of oxygen in this compound is -2.
Explanation:
For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.
In [tex]Na_2O[/tex], sodium is having an oxidation state of +1 called as [tex]Na^+[/tex] cation and oxygen is an anion with oxidation state of -2. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]Na_2O[/tex]
The cations and anions being oppositely charged attract each other through strong coloumbic forces and form an ionic bond.
Answer:
Sodium Oxide: Na2O, Barium Phosphide: Ba3P2
Explanation:
Just did the question
Suppose you titrate 25.00 mL of 0.200 M KOBr with 0.200M H2SO4. The pH at half-equivalence point is 7.75 a). What is the initial pH of the 25.00mL of 0.200M KOBr mentioned above
Answer:
Approximately [tex]10.88[/tex].
Explanation:
Equilibrium constant[tex]\rm OBr^{-}[/tex] can act as a weak Bronsted-Lowry base:
[tex]\rm OBr^{-}\; (aq) + H_2O\; (l) \rightleftharpoons HOBr\; (l) + OH^{-}\; (aq)[/tex].
(Side note: the state symbol of [tex]\rm HOBr[/tex] in this equation is [tex]\rm (l)[/tex] (meaning liquid) because [tex]\rm HOBr[/tex] is a weak acid.)
However, the equilibrium constant of this reaction, [tex]K_\text{eq}[/tex], isn't directly given. The idea is to find [tex]K_\text{eq}[/tex] using the [tex]\rm pH[/tex] value at the half-equivalence point. Keep in mind that this system is at equilibrium all the time during the titration. If temperature stays the same, then the same [tex]K_\text{eq}[/tex] value could also be used to find the [tex]\rm pH[/tex] of the solution before the acid was added.
At equilibrium:
[tex]\displaystyle K_\text{eq} = \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]}[/tex].
At the half-equivalence point of this titration, exactly half of the base, [tex]\rm OBr^{-}[/tex], has been converted to its conjugate acid, [tex]\rm HOBr[/tex]. Therefore, the half-equivalence concentration of [tex]\rm OBr^{-}[/tex] and [tex]\rm HOBr[/tex] should both be equal to one-half the initial concentration of [tex]\rm OBr^{-}[/tex].
As a result, the half-equivalence concentration of [tex]\rm OBr^{-}[/tex] and [tex]\rm HOBr[/tex] should be the same. The expression for [tex]K_\text{eq}[/tex] can thus be simplified:
[tex]\begin{aligned}& K_\text{eq} \\&= \frac{\left(\text{half-equivalence $[\rm HOBr\; (l)]$}\right)\cdot \left(\text{half-equivalence $[\rm OH^{-}\; (aq)]$}\right)}{\text{half-equivalence $[\rm OBr^{-}\; (l)]$}}\\ &=\text{half-equivalence $[\rm OH^{-}\; (aq)]$}\end{aligned}[/tex].
In other words, the [tex]K_\text{eq}[/tex] of this system is equal to the [tex]\rm OH^{-}[/tex] concentration at the half-equivalence point. Assume that [tex]\rm p\mathnormal{K}_\text{w}[/tex] the self-ionization constant of water, is [tex]14[/tex]. The concentration of [tex]\rm OH^{-}[/tex] can be found from the [tex]\rm pH[/tex] value:
[tex]\begin{aligned}& \text{half-equivalence $[\rm OH^{-}\; (aq)]$} \\ &= 10^{\rm pH - p\mathnormal{K}_\text{w}}\;\rm mol \cdot L^{-1} \\ &= 10^{7.75 - 14}\; \rm mol \cdot L^{-1}\\ &= 10^{-6.25}\; \rm mol \cdot L^{-1}\end{aligned}[/tex].
Therefore, [tex]\begin{aligned} K_\text{eq} &= 10^{-6.25}\end{aligned}[/tex].
Initial pH of the solutionAgain, since [tex]\rm KOBr[/tex] is a soluble salt, all that [tex]0.200\; \rm M[/tex] of [tex]\rm KOBr[/tex] in this solution will be in the form of [tex]\rm K^{+}[/tex] and [tex]\rm OBr^{-}[/tex] ions. Before any hydrolysis takes place, the concentration of [tex]\rm OBr^{-}[/tex] should be equal to that of [tex]\rm KOBr[/tex]. Therefore:
[tex]\text{$[\rm OBr^{-}\; (aq)]$ before hydrolysis} = 0.200\; \rm M[/tex].
Let the equilibrium concentration of [tex][\rm OH^{-}\; (aq)][/tex] be [tex]x\; \rm M[/tex]. Create a RICE table for this reversible reaction:
[tex]\begin{array}{c|ccccccc} & \rm OBr^{-}\; (aq) &+&\rm H_2O\; (l)& \rightleftharpoons & \rm HOBr\; (l)& + & \rm OH^{-}\; (aq) \\ \textbf{I}& 0.200\; \rm M & & & & 0 \; \rm M & & 0\; \rm M \\ \textbf{C} & -x\; \rm M & & & & +x \; \rm M & & +x\; \rm M \\ \textbf{E}& (0.200 + x)\; \rm M & & & & x \; \rm M & & x\; \rm M \end{array}[/tex].
Assume that external factors (such as temperature) stays the same. The [tex]K_\text{eq}[/tex] found at the half-equivalence point should apply here, as well.
[tex]\displaystyle K_\text{eq} = \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]}[/tex].
At equilibrium:
[tex]\displaystyle \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]} = \frac{x^2}{0.200 + x}[/tex].
Assume that [tex]x[/tex] is much smaller than [tex]0.200[/tex], such that the denominator is approximately the same as [tex]0.200[/tex]:
[tex]\displaystyle \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]} = \frac{x^2}{0.200 + x} \approx \frac{x^2}{0.200}[/tex].
That should be equal to the equilibrium constant, [tex]K_\text{eq}[/tex]. In other words:
[tex]\displaystyle \frac{x^2}{0.200} \approx K_\text{eq} = 10^{-6.25}[/tex].
Solve for [tex]x[/tex]:
[tex]x \approx 3.35\times 10^{-4}[/tex].
In other words, the [tex]\rm OH^{-}[/tex] before acid was added was approximately [tex]3.35\times 10^{-4}\; \rm M[/tex], which is the same as [tex]3.35\times 10^{-4}\; \rm mol \cdot L^{-1}[/tex]. Again, assume that [tex]\rm p\mathnormal{K}_\text{w} = 14[/tex]. Calculate the [tex]\rm pH[/tex] of that solution:
[tex]\begin{aligned}\rm pH &= \rm p\mathnormal{K}_\text{w} + \log [\mathrm{OH^{-}}] \approx 10.88\end{aligned}[/tex].
(Rounded to two decimal places.)
Which correctly lists the three land uses that the Bureau of Land Management was originally created to manage? mining, recreation, wildlife refuges recreation, developing oil and gas, battlefields grazing, mining, developing oil and gas developing oil and gas, battlefields, wildlife refuges
Answer: C
Explanation:
Right on edge 2020
The Bureau of Land Management was originally created to manage land for grazing, mining, developing oil and gas.
What is land management?Land management refers to the activities which are done in order to protect and preserve the land as well the resources found on land.
The Bureau of Land Management was created to manage land in the US.
The Bureau of Land Management was originally created to manage land for grazing, mining, developing oil and gas.
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For the following equilibrium, if the concentration of phosphate ion is X, what will be the molar solubility of copper phosphate? Cu3(PO4)2(s)↽−−⇀3Cu2+(aq)+2PO3−4(aq)
Answer: The molar solubility of copper phosphate is [tex]\frac{X}{2}[/tex]
Explanation:
Solubility product is defined as the equilibrium constant in which a solid ionic compound is dissolved to produce its ions in solution. It is represented as [tex]K_{sp}[/tex]
The equation is given as:
[tex]Cu_3(PO_4)_2(s)\rightarrow 3Cu^{2+}(aq)+2PO_4^{3-}[/tex]
By stoichiometry of the reaction:
1 mole of [tex]Cu_3(PO_4)_2[/tex] gives 3 moles of [tex]Cu^{2+}[/tex] and 2 moles of [tex]PO_4^{3-}[/tex]
When the solubility of [tex]Cu_3(PO_4)_2[/tex] is S moles/liter, then the solubility of [tex]Cu^{2+}[/tex] will be 3S moles\liter and solubility of [tex]PO_4^{3-}[/tex] will be 2S moles/liter.
Molar concentration of [tex]PO_4^{3-}[/tex] = X
Given : 2S = X
Thus S =[tex]\frac{X}{2}[/tex]
Thus the molar solubility of copper phosphate is [tex]\frac{X}{2}[/tex]
Which of the following best describes hydrocarbons? a. Alkanes in which a hydrogen atom is replaced by a hydroxyl group b. Binary compounds of carbon and hydrogen c. Organic compounds containing water and carbon d. Covalently bonded carbon compounds which have intermolecular force attractions to hydrogen compounds e. Compounds which are formed by the reaction of a naturally occurring carbon-containing substance and water
Answer:
b. Binary compounds of carbon and hydrogen
Explanation:
Before proceeding, Hydrocarbons refers to organic chemical compounds composed exclusively of hydrogen and carbon atoms. This means the only elements present in an hydrocarbon are;
- Carbon
- Hydrogen
Looking through the options;
- Option A: This is wrong because the hydroxyl group contains oxygen and hydrocarbons contain only hydrogen and carbon.
- option B: This is correct. Binary compounds refers to compounds with just two elements.
- option C: This is wrong because water contains oxygen and hydrocarbons contain only hydrogen and carbon.
- option D: Carbon atoms can contain other elements so this option is wrong.
- option E: This also wrong because we had already gotten the correct option.
Ag+(aq)+2NH3(aq)⇌Ag(NH3)2+(aq) : A g + ( a q ) + 2 N H 3 ( a q ) ⇌ A g ( N H 3 ) 2 + ( a q ) : blank is the Lewis acid and blank is the Lewis base. is the Lewis acid and A g + ( a q ) + 2 N H 3 ( a q ) ⇌ A g ( N H 3 ) 2 + ( a q ) : blank is the Lewis acid and blank is the Lewis base. is the Lewis base.
Answer:
Silver ion - Lewis acid, Ammonia - Lewis base
Explanation:
The reaction is given as;
Ag+(aq) + 2NH3(aq) ⇌ [Ag(NH3)]2+(aq)
A lewis acid is an electron pair acceptor. While a lewis base is any substance that that can donate a pair of nonbonding electrons.
This reaction however is a complexation reaction, where ammonia is reacting with the silver ion.
Silver ion accepts electrons in this reaction, hence it is the lewis acid. The ammonia on the other hand donates the electrons used in bonding so it is the lewis base.
To infer means to do what?
A. reach a conclusion about data
B. make a hypothesis about data
C. decide to collect some more data
D. state something found indirectly from data
Answer:
A
Explanation:
infer means use data to reach conclusion.
which material is a conductor of electric current?
Answer:Conduction materials include metals, electrolytes, superconductors, semiconductors, plasmas and some nonmetallic conductors such as graphite and Conductive polymers. Copper has a high conductivity.
Explanation: