determine the molar solubility of agbr in a 0.50 m nh3 solution. the ksp for agbr is 5.0 x 10-13 and the kf for ag(nh3)2 is 1.7 x 107

Answers

Answer 1

Therefore, the molar solubility of AgBr in a 0.50 M [tex]NH_3[/tex] solution is 3.3 x [tex]10^{-6[/tex] M.

We need to use the concept of complex ion formation. AgBr(s) dissociates in water to form Ag+ and Br-, which then react with NH3 to form the complex ion Ag([tex]NH_3[/tex]) + and [tex]NH_3[/tex].Br The balanced equation for this reaction is:

AgBr(s) + 2 [tex]NH_3[/tex](aq) → 2Ag([tex]NH_3[/tex])+(aq) + [tex]NH_3[/tex]Br(s)

The equilibrium constant for the formation of 2Ag([tex]NH_3[/tex])+ is given by the formation constant, Kf, which is [tex]NH_3[/tex]. The equilibrium constant for the dissolution of AgBr(s) is given by the solubility product, Ksp, which is 5.0 x [tex]10^{-13.[/tex]

Let x be the molar solubility of AgBr in [tex]NH_3[/tex] solution. Then, the concentration of Ag+ and Br- ions is also x. Using the equilibrium constant expression for the formation of Ag(NH3)2+, we have:

Kf = [Ag([tex]NH_3[/tex])2+]/([Ag+][[tex]NH_3[/tex]])

Substituting the values in terms of x, we get:

1.7 x [tex]10^7[/tex] = [Ag([tex]NH_3[/tex])2+]/(x[ [tex]NH_3[/tex]])

[Ag([tex]NH_3[/tex])2+] = 1.7 x[ [tex]NH_3[/tex]]

Using the equilibrium constant expression for the dissolution of AgBr, we have:

Ksp = [Ag+][Br-] = [tex]x^2[/tex]

Now, using the equilibrium constant expression for the reaction between AgBr and [tex]NH_3[/tex], we have:

Solving for x, we get:

[tex]x = \sqrt{(Ksp/Kf) x [ NH_3]}[/tex]

x = [tex]\sqrt{(5.0 * 10^-13/1.7 * 10^7) x 0.50}[/tex]

x = 3.3 x  [tex]10^{-6[/tex] M

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Related Questions

Complete the following table with the the C-C-C bonds angles for each compound. Report Table MM. 1: Bond Angles Compound C-C-C Angle (straight chain or cyclic) Propane Butane Pentane Cyclopropane Cyclobutane Cyclopentane

Answers

Table MM. 1 shows the C-C-C bond angles for various organic compounds. The C-C-C bond angles vary depending on the geometry of the molecule, which can be either straight chain or cyclic.

For straight chain compounds such as propane, butane, and pentane, the bond angles are close to the ideal tetrahedral angle of 109.5 degrees. However, for cyclic compounds such as cyclopropane, cyclobutane, and cyclopentane, the bond angles deviate from the ideal tetrahedral angle due to the ring strain caused by the cyclic structure. Cyclopropane has a planar triangular structure with bond angles of 60 degrees, while cyclobutane and cyclopentane have bond angles of approximately 90 and 108 degrees, respectively.

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Give balanced equations for the following reactions. a) Combustion of cyclopentene b) Addition of bromine to 1-butene c) Reaction of nitric acid with benzene d) Addition of sulfuric acid to ethylbenzene.

Answers

In chemistry, balanced equations are essential to describe chemical reactions accurately. Here are the balanced equations for the following reactions:

a) The combustion of cyclopentene can be represented as C₅H₈ + 7.5 O₂ → 5 CO₂ + 4 H₂O

b) The addition of bromine to 1-butene can be represented as C₄H₈ + Br₂ → C₄H₈Br₂

c) The reaction of nitric acid with benzene can be represented as C₆H₆ + HNO₃ → C₆H₅NO₂ + H₂O

d) The addition of sulfuric acid to ethylbenzene can be represented as C₈H₁₀ + H₂SO₄ → C₈H₉SO₃H + H₂O

It's important to note that balanced equations ensure that the same number of atoms of each element exists on both sides of the equation, following the Law of Conservation of Mass.

Let us discuss this in detail.

a) Combustion of cyclopentene:
C₅H₈ + 7.5 O₂ → 5 CO₂ + 4 H₂O
Cyclopentene reacts with oxygen to produce carbon dioxide and water.

b) Addition of bromine to 1-butene:
C₄H₈ + Br₂ → C₄H₈Br₂
1-butene reacts with bromine to form 1,2-dibromo butane.

c) Reaction of nitric acid with benzene (in the presence of a catalyst, typically sulfuric acid):
C₆H₆ + HNO₃ → C₆H₅NO₂ + H₂O
Benzene reacts with nitric acid to produce nitrobenzene and water.

d) Addition of sulfuric acid to ethylbenzene (sulfonation):
C₈H₁₀ + H₂SO₄ → C₈H₉SO₃H + H₂O
Ethylbenzene reacts with sulfuric acid to form ethylbenzene sulfonic acid and water.

These balanced equations represent the given reactions concisely and accurately.

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Calculate ΔS∘rxn for this balanced chemical equation.

2NO(g)+O2(g)→2NO2(g)

Express your answer to one decimal place and include the appropriate units.

Answers

[tex]ΔS∘rxn[/tex] for this balanced chemical equation [tex]2NO(g) + O2(g) → 2NO2(g)[/tex] is 47.8 J/mol K.

To calculate ΔS∘rxn, we need to determine the change in entropy for the reaction. We can use the standard molar entropies of the reactants and products to calculate this.

The standard molar entropy of NO(g) is 210.8 J/mol K, the standard molar entropy of O2(g) is 205.0 J/mol K, and the standard molar entropy of NO2(g) is 239.9 J/mol K.

[tex]= [2S∘(NO2)] - [2S∘(NO) + S∘(O2)]= [2(239.9 J/mol K)] - [2(210.8 J/mol K) + 205.0 J/mol K] = 47.8 J/mol K[/tex]

Therefore, ΔS∘rxn for the reaction [tex]2NO(g) + O2(g) → 2NO2(g)[/tex]is 47.8 J/mol K.

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a technician is asked to prepare a dilution of a common laboratory disinfectant. the label indicates that a 1:39 dilution in water is required prior to use. calculate the volume in ml of disinfectant required to make 2.0 l. record the correct amount, rounded to one decimal place

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The technician would need 51.3 ml of disinfectant to make a 2.0 L solution with a 1:39 dilution.


To calculate the volume of disinfectant needed, we first need to determine the ratio of disinfectant to water in the dilution. A 1:39 dilution means that for every 1 part disinfectant, 39 parts water are added.

We can use this ratio to calculate the amount of disinfectant needed for a 2.0 L solution. To do this, we first need to determine the total volume of the diluted solution, which is 2.0 L.

Next, we can set up a proportion:

1 part disinfectant / 39 parts water = x ml disinfectant / 2.0 L solution

To solve for x, we can cross-multiply and simplify:

1 * 2.0 L * x = 39 * 1000 ml

x = 39,000 ml / 2.0 L

x = 19.5 ml

So, we need 19.5 ml of disinfectant for a 2.0 L solution with a 1:39 dilution. However, this is only the amount needed for a 1:39 dilution. To calculate the total amount of disinfectant needed, we need to divide 19.5 ml by the dilution factor (39):

19.5 ml / 39 = 0.5 ml

Finally, we can multiply 0.5 ml by the total volume of the solution (2.0 L) to get the final answer:

0.5 ml * 2.0 L = 51.3 ml

Therefore, the technician would need 51.3 ml of disinfectant to make a 2.0 L solution with a 1:39 dilution, rounded to one decimal place.

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Farm A and Farm B are both adding new animals each month. The graph below compares the numbers of animals on Farm A and Farm B over time, in months.
Farm Animals
Number of Animals

Answers

Farm A and Farm B have the same number of animals for ten months.

What is a graph?

A graph is a depiction of data or information that demonstrates the relationships between various variables using a system of lines, bars, or points. Graphs are frequently used to present complicated data in a way that is simple to comprehend and analyze.

If we want to know when the two farms would have the same number of animals then we have to look at for where the two lines intersect as shown in the graph.

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a heated low rate digester is used to digest 4000 lb dry solids/day, and 72% of the sludge solids are mlvss. during the digestion, 65% of the mlvss is digested (removed). the digested sludge has 7% dry solids and the wet specific gravity is 1.03. what is the digested sludge volume produced per day.

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The digested sludge volume produced per day is approximately 1996 gallons/day.

To calculate the digested sludge volume produced per day, we first need to determine the mass of the sludge produced per day.

From the information given, we know that the digester is processing 4000 lb of dry solids per day. However, not all of this dry solids will end up as sludge. We know that 72% of the sludge solids are MLVSS, so we can calculate the mass of MLVSS produced per day as follows:

MLVSS produced per day = 4000 lb/day x 0.72 = 2880 lb/day

Since 65% of the MLVSS is digested (removed), we can calculate the mass of digested sludge produced per day as follows:

Digested sludge produced per day = 2880 lb/day x 0.65 = 1872 lb/day

Now, we need to determine the volume of digested sludge produced per day. We know that the digested sludge has a dry solids content of 7%, which means that the remaining 93% of the sludge is water. We also know that the wet specific gravity of the sludge is 1.03, which means that it is slightly more dense than water.

To calculate the volume of the digested sludge, we can use the following formula:

Volume = Mass / (Density x % solids)

Plugging in the values we have, we get:

Volume = 1872 lb/day / (1.03 x 0.93) = 1996 gallons/day

Therefore, the digested sludge volume produced per day is approximately 1996 gallons/day.

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. in the first of this reaction, the concentration of dropped from to . what is the average rate of the reaction during this time interval?(remember to normalize the rate of the reaction for all reactants and products.)

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To determine the average rate of the reaction during this time interval, we need to use the formula: average rate = change in concentration of reactant or product / time interval. In this case, we are given that the concentration of one reactant, which is not specified, dropped from a certain value to another value.

Since we do not have information about the other reactants or products involved in the reaction, we cannot normalize the rate of the reaction. Therefore, we can only calculate the average rate of the specified reactant using the given values.

The average rate can be calculated by dividing the change in concentration by the time interval in which the change occurred, which will give us the rate of the reaction in units of concentration per time.

The steps to calculate the average rate using the provided terms:

1. Identify the reactant whose concentration has dropped during the reaction. In this case, the reactant's concentration dropped from an initial concentration to a final concentration.
2. Calculate the change in concentration by subtracting the final concentration from the initial concentration.
3. Identify the time interval over which the reaction occurred.
4. Normalize the rate of reaction for all reactants and products, if necessary, by dividing the change in concentration by the stoichiometric coefficients of the respective reactants and products.
5. Calculate the average rate by dividing the normalized change in concentration by the time interval.

With the provided information, apply these steps to find the average rate of the reaction during the specified time interval.

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what ion will be formed by the phosphorus atom shown below when it has a stable set of valence electrons?

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The phosphorus atom shown below has 5 valence electrons. In order to have a stable set of valence electrons, it needs to gain 3 more electrons. This will result in the formation of a phosphide ion (P³⁻).

When a phosphorus atom gains a stable set of valence electrons, it forms an ion called a phosphide ion. The phosphorus atom achieves stability by gaining three electrons to complete its valence shell, resulting in a -3 charge. Therefore, the ion formed is P³⁻ (phosphide ion).

Phosphorus is a chemical element with the atomic number 15 and the letter P in its name. Phosphorus is an element that appears in two major forms: red and white. However, because to its strong reactivity, phosphorus is never found on Earth as a free element.

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the transition state of a reaction can easily be isolated: select the correct answer below: at high temperatures at low temperatures at low pressures under no circumstance

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Under no circumstance. The transition state of a reaction is a highly unstable and short-lived intermediate state that cannot be isolated under any conditions. It can only be inferred through theoretical calculations and experimental observations.

The transition state of a reaction cannot be isolated under any circumstances. The transition state is an unstable, high-energy state that exists for a very short time during a chemical reaction.

Under no circumstances. A reaction's transition state is an extremely unstable, transient intermediate stage that is impossible to isolate under any circumstances. Only theoretical calculations and experimental observations can be used to deduce it.

Under no circumstances can the reaction's transition stage be isolated. During a chemical process, the transition state is an unstable, high-energy condition that only lasts for a relatively brief period of time.

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draw the conjugate base for the acid ch2=ch2 . draw all hydrogens. remember to include charges and non-bonding electrons where necessary.

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the conjugate base for ch2=ch2 is:

CH2=CH−

To draw the conjugate base for the acid CH2=CH2, follow these steps:

1. Identify the acid: CH2=CH2 is ethylene, which is a weak acid.

2. Remove a hydrogen: To form the conjugate base, we need to remove a hydrogen atom from ethylene. This leaves us with CH2=CH-.

3. Add a lone pair: Since we removed a hydrogen, the conjugate base now has an additional lone pair of electrons. The carbon atom that lost the hydrogen now has a lone pair.

4. Add charges: The removal of a hydrogen results in a negative charge on the conjugate base. So, the carbon atom with the lone pair will have a negative charge.

Therefore, The conjugate base for the acid CH2=CH2 is CH2=CH- with a lone pair on the negatively charged carbon atom.

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g compare the melting point data of the two samples and comment on the data. post-lab: is the recrystallized sample pure? explain

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Based on the melting point data, it can be seen that there is a difference between the two samples. The melting point of the recrystallized sample is likely to be higher compared to the other sample.

This is because recrystallization helps in purifying the sample and removing impurities, which can lead to a higher melting point.
In terms of the recrystallized sample's purity, it can be inferred that the sample is likely to be pure. This is because recrystallization involves dissolving the sample in a solvent, and then slowly cooling it down to form crystals. During this process, impurities are left behind in the solvent, while the pure sample forms crystals. Therefore, the higher melting point of the recrystallized sample indicates that it is likely to be pure. However, further tests may be needed to confirm its purity.

To compare the melting point data of the two samples and comment on the data, you need to follow these steps:
1. Obtain the melting point data for both samples.
2. Compare the values of the melting points.
3. Analyze the results and provide a comment based on your observations.
A pure substance has a sharp, well-defined melting point, while an impure substance will have a broader melting point range. If the recrystallized sample has a sharp melting point that matches the known value for the pure substance, it is likely pure. If the melting point is broad or lower than the known value, the sample is likely still impure. Compare the melting point data of the recrystallized sample with the known value to determine its purity.

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the most useful way to classify amino acids is by: molecular weight. polarity. alphabetical order. pka. propensity in proteins.

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The most useful way to classify amino acids is by their propensity in proteins, reflecting their functional and structural roles in proteins. Option (5)

Hydrophobic amino acids tend to be found in the interior of proteins, where they can interact with other hydrophobic residues to form stable structures, while hydrophilic amino acids tend to be found on the surface of proteins, where they can interact with water molecules and other polar residues.

Additionally, amino acids can be classified based on their charge and acidity, which are determined by their pKa values. Amino acids with acidic side chains are negatively charged at physiological pH, while amino acids with basic side chains are positively charged. The balance of charged and uncharged residues within a protein can affect its stability, function, and interactions with other molecules.

Therefore, classifying amino acids by their propensity in proteins and their charge and acidity provides a useful framework for understanding their functional and structural roles in proteins.

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Full Question: the most useful way to classify amino acids is by:

molecular weight. polarity. alphabetical order. pka. propensity in proteins.

1. If magnesium is added to hydrochloric acid, the reaction takes 35 seconds to go to
completion. It was found to change the hydrochloric acid from 0.5 M to 0.35 M.

Answers

The rate of the reaction can be obtained as  0.004 Ms-1.

What is the rate of reaction?

We know that the rate of reaction is the rate of the change of the concentration with time of the system.

The rate of a chemical reaction is the speed at which the reactants are converted into products. It is usually expressed as the change in concentration of a reactant or product per unit time.

Rate of reaction = Change in concentration/ Time

= 0.5 - 0.35/35

= 0.004 Ms-1

Thus the reaction is is calculated as 0.004 Ms-1.

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#SPJ1If magnesium is added to hydrochloric acid, the reaction takes 35 seconds to go to completion. It was found to change the hydrochloric acid from 0.5 M to 0.35 M. What is the rate of reaction?

What is the heat energy needed to raise the temperature of 6 63moles of ethanol CH CHO from a temperature of 231 [CH,CH,OH-46.07g/mol) (CCHICHION-2.46J/gºC]) 241.6°C. The mass of 3.)

Answers

The heat energy needed to raise the temperature of 6.63 moles of ethanol from 231°C to 241.6°C is approximately 7492.286 J.

To calculate the heat energy required to raise the temperature of ethanol, we will use the following formula:

[tex]q = m * c * ΔT[/tex]

where q is the heat energy, m is the mass of the substance, c is the specific heat capacity, and ΔT is the change in temperature.

First, we need to calculate the mass of ethanol:

mass = moles * molar mass

mass = 6.63 moles * 46.07 g/mol

mass = 305.1 g

Now we can use the formula to calculate the heat energy:

[tex]q = m * c * ΔT\\q = 305.1 g * 2.46 J/gºC * (241.6°C - 231°C)\\\\[/tex]

q = 7492.286 J

Therefore, the heat energy needed to raise the temperature of 6.63 moles of ethanol from 231°C to 241.6°C is approximately 7492.286 J.

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Calculate the pH and [S2-] in a 0.10 M H2S solution. Assume Ka1 = 1.0 x 10-7 and Ka2 = 1.0 x 10-19.

Answers

The concentration of S2- in the solution is [tex]1.0 x 10^-14 M[/tex].

The dissociation of hydrogen sulfide (H2S) in water can be represented by the following chemical equations:

H2S ⇌ H+ + HS-         (Ka1)

HS- ⇌ H+ + S2-           (Ka2)

where Ka1 and Ka2 are the acid dissociation constants for the two acidic groups in H2S.

Given that the initial concentration of H2S is 0.10 M, we can assume that the initial concentration of HS- and S2- is negligible (since the Ka2 value is much smaller than Ka1). We can use an ICE table to determine the equilibrium concentrations of the species:

Reaction       | H2S           ⇌ H+     + HS-

Initial (M)    | 0.10          0       0

Change (M)     | -x            +x      +x

Equilibrium (M)| 0.10 - x      x       x

Substituting these values into the expression for Ka1 gives:

Ka1 = [H+][HS-] / [H2S]

1.0 x 10^-7 = x^2 / (0.10 - x)

Since the value of x is small compared to the initial concentration of H2S, we can make the approximation that 0.10 - x ≈ 0.10, which simplifies the expression to:

1.0 x 10^-7 = x^2 / 0.10

Solving for x gives:

x = 1.0 x 10^-4 M

Therefore, the concentration of H+ is 1.0 x 10^-4 M, and the pH of the solution is:

pH = -log[H+]

pH = -log(1.0 x 10^-4)

pH = 4

To calculate the concentration of S2-, we need to use the equilibrium expression for Ka2:

Ka2 = [H+][S2-] / [HS-]

1.0 x 10^-19 = x^2 / (1.0 x 10^-4)

Solving for x gives:

x = 1.0 x 10^-14 M

Therefore, the concentration of S2- in the solution is 1.0 x 10^-14 M.

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using the information provided in table 1, provide a detailed explanation why cyclohexane will provide better data than benzene in the determination of the molecular mass for an unknown compound

Answers

Contrary to benzene, cyclohexane is a nonpolar solvent that does not go through the aromaticity process. As a result, it does not interact in any way that could influence how its molecular mass is determined with the unknown molecule.

On the other hand, benzene and the unidentified molecule may interact in a way that prevents the measurement of the unidentified compound's molecular mass. Because of this interference, estimates of the molecular mass of the unknown substance may be larger than the actual value. Therefore, when determining the molecular mass of an unknown chemical, utilizing cyclohexane as a solvent can yield more precise results than benzene.

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--The complete Question is, provide a detailed explanation why cyclohexane will provide better data than benzene in the determination of the molecular mass for an unknown compound .--

what is the coordination number around the central metal atom in hexaaquachromium(iii) ([cr(h₂o)₆]³⁺)?

Answers

The coordination number around the central metal atom in hexaaquachromium(iii) ([cr(h₂o)₆]³⁺) is 6.

The coordination number of a complex ion refers to the number of ligands that are attached to the central metal ion. In the case of hexaaquachromium(III) ([Cr(H2O)6]3+), the formula tells us that there are six water ligands coordinated to the central chromium ion.

Each water molecule can donate two electron pairs to the chromium ion, one from the oxygen atom and another from the lone pair on the water molecule. Therefore, the coordination number around the chromium ion in [Cr(H2O)6]3+ is 6.

Therefore, the coordination number of the central metal atom in hexaaquachromium(III) ([Cr(H2O)6]3+) is 6.

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a.) Determine the [H3O+] of a 0.170 M solution of formic acid (Ka=1.8×10−4).

Express your answer using two significant figures.

b.) Determine pH of this solution of formic acid.

Express your answer to two decimal places.

c.) Amphetamine (C9H13N) is a weak base with a pKb of 4.2.

Calculate the pH of a solution containing an amphetamine concentration of 230 mg/L .

Express your answer to one decimal place.

Answers

a) The [H₃O⁺] of a 0.170 M solution of formic acid (Ka=1.8×10⁻⁴) is 0.012 M.

b) The pH of the solution of formic acid is 1.92.

c) The pH of a solution containing an amphetamine concentration of 230 mg/L and pKb of 4.2 is 9.5.

a) The equilibrium reaction for formic acid is:

HCOOH + H₂O ⇌ H₃O⁺ + HCOO⁻

The Ka expression for formic acid is:

Ka = [H₃O⁺][HCOO⁻]/[HCOOH]

Let x be the concentration of [H₃O⁺] that forms when the solution reaches equilibrium. The concentration of [HCOO⁻] will also be x. The initial concentration of formic acid [HCOOH] is 0.170 M. Using the Ka expression, we can set up an equation to solve for x:

Ka = x²/0.170 - x

Solving for x, we get x = 0.012 M. Thus, the [H₃O⁺] of the solution is 0.012 M.

b) The pH of the solution can be calculated using the equation:

pH = -log[H₃O⁺]

Substituting the value of [H₃O⁺] from part a), we get:

pH = -log(0.012) = 1.92

Thus, the pH of the solution is 1.92.

c) The equilibrium reaction for amphetamine is:

C₉H₁₃N + H₂O ⇌ C₉H₁₂NH⁺ + OH⁻

The pKb expression for amphetamine is:

pKb = -log(Kb) = -log([C₉H₁₂NH⁺][OH⁻]/[C₉H₁₃N])

Let x be the concentration of [OH⁻] that forms when the solution reaches equilibrium. The concentration of [C₉H₁₂NH⁺] will also be x. The initial concentration of amphetamine [C₉H₁₃N] is 230 mg/L or 0.230 g/L. The molar mass of amphetamine is 135.21 g/mol. Using the pKb expression, we can set up an equation to solve for x:

pKb = -log(x²/(0.230-x))

Solving for x, we get x = 5.01×10⁻⁶ M. Thus, the [OH⁻] of the solution is 5.01×10⁻⁶ M.

The pH of the solution can be calculated using the equation:

pH = 14 - pOH = 14 - (-log[OH⁻])

Substituting the value of [OH⁻], we get:

pH = 14 - (-log(5.01×10⁻⁶)) = 9.5

Thus, the pH of the solution is 9.5.

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You must solve the mystery. For each scenario, figure out what the pollutant could be.

Fill in the table with the pollutant, the sources, and the human health effects

You will choose from the following pollutants:

Lead Photochemical smog Coal

Rn-222 Ozone Carbon monoxide

Sick Building Syndrome Nitrogen oxides Sulfurous smog

Asbestos Particulate matter Formaldehyde (VOC)

Particles NOX and VOCs

Make up a mystery of your own for others to solve. For this section you may use any resources you want, but if you look online, make sure you use credible sources.


Sally is visiting Lake Tahoe at ~6,000 feet and loves being among the conifer trees. They smell so good! It’s a bright sunny day and many people are driving around the scenic lake loop. Sally notices a beautiful blue haze filling the valleys. The more Sally runs up and down the trail, the worse Sally’s lungs feel. Sally gets an asthma attack. Luckily a friendly rabbit offers to share its inhaler with Sally

Answers

The pollutant in this scenario is likely to be photochemical smog.

Sources of photochemical smog include emissions from vehicles, power plants, and other industrial sources. Sunlight and heat cause the nitrogen oxides (NOx) and volatile organic compounds (VOCs) emitted by these sources to react and form photochemical smog, which is characterized by a blue haze and can exacerbate respiratory issues like asthma.

The effects of photochemical smog on human health can include respiratory irritation, coughing, wheezing, and shortness of breath. It can also worsen existing conditions such as asthma, bronchitis, and emphysema. In extreme cases, it can lead to permanent lung damage. It is important to limit exposure to photochemical smog, especially for individuals with respiratory issues.

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Give the major organic product from the reaction of each of the following reagents or series of reagents with methylene cyclohexane, shown below. a) Cl2 b)Br2/CH3OH c) . BH3 2. H2O/NaOH 21

Answers

a) The major organic product is 1,2-dichlorocyclohexane. b) The major organic product is 1-bromo-1-cyclohexanol. c) The major organic product is cyclohexanol.

PART a) The Cl₂ molecule is a strong electrophile, which can undergo an addition reaction with the methylene group (CH₂) in cyclohexane. The addition of Cl₂ to the methylene group leads to the formation of a dihaloalkane. In this case, the Cl₂ adds across the double bond to form 1,2-dichlorocyclohexane as the major product.

PART b) In the presence of CH3OH, Br₂ undergoes a nucleophilic substitution reaction with the methylene group in cyclohexane. The nucleophilic substitution of Br₂ is regioselective and leads to the formation of 1-bromo-1-cyclohexanol as the major product.

PART c) BH3 undergoes an electrophilic addition reaction with the methylene group in cyclohexane, leading to the formation of an organoborane. The organoborane then undergoes a nucleophilic substitution reaction with H₂O/NaOH, which results in the oxidation of the boron atom and the replacement of the boron-containing group with a hydroxyl group. The final product is cyclohexanol.

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brainly how many grams of co2 are produced when 88g of o2 are reacted with an excess of butane

Answers

The balanced chemical equation for the combustion of butane with oxygen is: 2 C₄H₁₀ (g) + 13 O₂ (g) → 8 CO₂ (g) + 10 H₂O (g)

According to the above reaction, 2 moles of butane (C4H10) react with 13 moles of oxygen (O₂) to produce 8 moles of carbon dioxide (CO2).

The moles of oxygen can be calculated as shown below.

moles of O₂ = mass of O2 / molar mass of O₂

moles of O₂ = 88 g / 32 g/mol

moles of O₂ = 2.75 mol

Use the mole ratio from the balanced equation to determine the moles of CO₂ produced:

moles of CO₂ = (8/13) x moles of O₂

moles of CO₂ = (8/13) x 2.75 mol

moles of CO₂ = 1.69 mol

The mass of CO₂ can be calculated as shown below.

mass of CO₂ = moles of CO₂ x molar mass of CO₂

mass of CO₂ = 1.69 mol x 44.01 g/mol

mass of CO₂ = 74.3 g

Therefore, when 88 g of O₂ is reacted with an excess of butane, 74.3 g of CO₂ is produced.

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suppose you mix 100.0 g of water at 24.5 oc with 75.0 g of water at 73.7 oc. what will be the final temperature of the mixed water, in oc?

Answers

The final temperature of the mixed water will be approximately 311.3°C.

To solve this problem, we can use the principle of heat transfer, which states that heat will flow from the hotter object to the colder object until they reach thermal equilibrium at the same temperature.

The amount of heat lost by the hot water will be equal to the amount of heat gained by the cold water. This can be expressed mathematically as:

Qlost = Qgain

where Q is the amount of heat, and subscripts h and c denote the hot and cold water, respectively.

The amount of heat gained or lost can be calculated using the formula:

Q = m * c * ΔT

where m is the mass of the water, c is the specific heat capacity of water (4.184 J/g°C), and ΔT is the change in temperature.

Let's first calculate the amount of heat lost by the hot water:

Qlost = m_h * c * (T_h - T_f)

where T_f is the final temperature of the mixed water.

Substituting the values given in the problem, we get:

Qlost = 75.0 g * 4.184 J/g°C * (73.7°C - T_f)

Next, let's calculate the amount of heat gained by the cold water:

Qgain = m_c * c * (T_f - T_c)

Substituting the values given in the problem, we get:

Qgain = 100.0 g * 4.184 J/g°C * (T_f - 24.5°C)

Since Qlost = Qgain, we can set the two equations equal to each other and solve for T_f:

75.0 g * 4.184 J/g°C * (73.7°C - T_f) = 100.0 g * 4.184 J/g°C * (T_f - 24.5°C)

Simplifying the equation, we get:

31155 J - 311.55 T_f = 4184 T_f - 102584 J

Combining like terms, we get:

429.55 T_f = 133739 J

Solving for T_f, we get:

T_f = 311.3°C

Therefore, the final temperature of the mixed water will be approximately 311.3°C.

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How many grams of Cu can be produced from 3.0 g of NaCI

Answers

To calculate the amount of Cu that can be produced from 3.0 g of NaCl, we need to first write and balance the chemical equation for the reaction between NaCl and Cu:

2NaCl + Cu → CuCl2 + 2Na

From the balanced equation, we can see that 2 moles of NaCl react with 1 mole of Cu to produce 1 mole of CuCl2 and 2 moles of Na.

To determine the amount of Cu produced, we need to calculate the number of moles of NaCl in 3.0 g:

mass of NaCl = 3.0 g
molar mass of NaCl = 58.44 g/mol
moles of NaCl = mass/molar mass = 3.0 g / 58.44 g/mol = 0.051 mol

Now we can use the stoichiometry of the balanced chemical equation to determine the number of moles of Cu produced:

1 mole of Cu is produced from 2 moles of NaCl
moles of Cu = (0.051 mol NaCl) / (2 mol NaCl/1 mol Cu) = 0.026 mol Cu

Finally, we can use the molar mass of Cu to convert the number of moles to grams:

molar mass of Cu = 63.55 g/mol
mass of Cu = moles of Cu x molar mass of Cu = 0.026 mol x 63.55 g/mol = 1.68 g

Therefore, 1.68 grams of Cu can be produced from 3.0 g of NaCl.

What is the final temperature of the water went 100 mL of 30°C water is mixed with 500 mL of 60°C water

Answers

The final temperature of the water resulting from the mixing of 100 mL of 30°C water with 500 mL of 60°C water would be 55°C.

Temperature calculation

In order to calculate the final temperature of a mixture of two different temperatures of water, we can use the following formula:

[tex]T_{(final)} = (m_1T_1 + m_2T_2) / (m_1 + m_2)[/tex]

where:

T(final) is the final temperature of the mixturem1 and m2 are the masses of water in milliliters (mL) or grams (g)T1 and T2 are the initial temperatures of water in degrees Celsius (°C).

In this case, we have 100 mL of 30°C water and 500 mL of 60°C water. We can convert mL to grams using the density of water which is approximately 1 g/mL2. Therefore:

m1 = 100 g T1 = 30°C m2 = 500 g T2 = 60°C

Thus:

T(final) = (100x30) + (500x60) / (100 + 500) T(final) = (3000 + 30000) / 600 T(final) = 55°C

Therefore, the final temperature of the mixture is 55°C.

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If an acid has a Ka value of 4.31×10−10, what is the Kb of its conjugate base?

Answers

The Kb value of the conjugate base can be found using the relationship between Ka and Kb.



1. Write out the chemical equation for the acid and its conjugate base:

HA (acid) + H2O ⇌ A- (conjugate base) + H3O+

2. Write out the equilibrium constant expression for the acid:

Ka = [A-][H3O+]/[HA]

3. Use the relationship between Ka and Kb:

Ka x Kb = Kw

where Kw is the ion product constant for water (1.0 x 10^-14 at 25°C).

4. Rearrange the equation to solve for Kb:

Kb = Kw/Ka

5. Substitute in the values:

Kb = 1.0 x 10^-14 / 4.31 x 10^-10

Kb = 2.32 x 10^-5

Therefore, the Kb value of the conjugate base is 2.32 x 10^-5.

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Balance the following equation: H2O(aq) + Ca(NO3 )2(s) + (NH4)2HP04(s) + NH3(aq) → Calo(PO4)6 (OH)2(s) + NH4NO3(aq)

Answers

The balanced equation is [tex]H_2O(aq) + Ca(NO_3)_2(s) + (NH_4)2HPO_4(s) + NH_3(aq) - > Ca_{10}(PO_4)6(OH)_2(s) + 2NH_4NO_3(aq)[/tex]

To balance the chemical equation:

[tex]H_2O(aq) + 5Ca(NO_3)_2(s) + 10(NH_4)2HPO_4(s) + NH_3(aq) - > Ca_10(PO_4)6(OH)_2(s) + 2NH_4NO_3(aq)[/tex]

We need to ensure that the number of atoms of each element is equal on both sides of the equation.

First, let's balance the phosphorus atoms by multiplying (NH4)2HPO4 by 10:

[tex]H_2O(aq) + Ca(NO_3)2(s) + 10(NH_4)2HPO_4(s) + NH_3(aq) - > Ca_10(PO_4)6(OH)_2(s) + 20NH_4NO_3(aq)[/tex]

Now we have 20 nitrogen atoms on the left and 40 on the right, so we can balance them by multiplying [tex]NH_4NO_3[/tex](aq) by 2:

[tex]H_2O(aq) + Ca(NO_3)_2(s) + 10(NH_4)2HPO_4(s) + NH_3(aq) - > Ca_{10}(PO_4)_6(OH)_2(s) + 2NH_4NO_3(aq)[/tex]

Finally, we need to balance the calcium atoms by adding a coefficient of 5 to [tex]Ca_(NO_3)_2[/tex](s):

[tex]H_2O(aq) + Ca(NO_3)_2(s) + (NH_4)2HPO_4(s) + NH_3(aq) - > Ca_{10}(PO_4)6(OH)_2(s) + 2NH_4NO_3(aq)[/tex]

Now we have balanced the chemical equation - there are 10 calcium atoms, 6 phosphorus atoms, 20 nitrogen atoms, and 62 oxygen atoms on both sides.

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Based on the slogan "No Corporate Money,” which statement best explains de Blasio’s position on super PACs?

Super PACs are a good way for corporations to fund campaigns.
Super PACs should not receive contributions from corporations.
Super PACs should not make contributions to corporations.
Super PACs and corporations make too much money.

Answers

Answer: B. Super PACs should not receive contributions from corporations.

Explanation: Mayor de Blasio's position on super PACs is that they should not receive contributions from corporations. This is in line with his slogan, "No Corporate Money," which suggests that corporations should not be allowed to use their finances to influence campaigns.

Based on the slogan "No Corporate Money,”  the statement that best explains de Blasio’s position on super PACs is - "Super PACs should not receive contributions from corporations."

Super PACs receiving funding from corporations is against De Blasio's position which is reflected in the campaign slogan "No Corporate Money." He probably thinks corporate influence in politics should be kept to a minimum in order to promote a more fair and open electoral system. This viewpoint is in line with the notion that corporate funding may influence judgment and thwart sincere public interest representation.

De Blasio seeks to lessen the possibility of excessive corporate influence over candidates and policies by opposing corporate contributions to super PACs encouraging a more democratic and people  centered approach to political campaigning and governance.

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the radioactive isotope 14 c has a half-life of approximately 5715 years. a piece of ancient charcoal contains only 88 % as much of the radioactive carbon as a piece of modern charcoal. how long ago was the tree burned to make the ancient charcoal? (round your answer to the nearest integer.)

Answers

The tree was burned to make the ancient charcoal approximately 17,130 years ago.

We can use the formula for radioactive decay to solve this problem. The formula is:

N = N0 * (1/2)^(t/T)

Where:
N = the amount of radioactive material at a given time
N0 = the initial amount of radioactive material
t = the time that has elapsed since the material was created
T = the half-life of the material

Let's use this formula for both the modern and ancient charcoal:

For modern charcoal:
N = N0
t = 0
T = 5715 years

For ancient charcoal:
N = 0.88*N0
t = ?
T = 5715 years

Now we can set up an equation using the two formulas:

0.88*N0 = N0 * (1/2)^(t/5715)

Simplifying this equation:

0.88 = (1/2)^(t/5715)

Taking the natural logarithm of both sides:

ln(0.88) = (t/5715)*ln(1/2)

Solving for t:

t = (ln(0.88)/ln(1/2))*5715

t ≈ 17,130 years

Therefore, the tree was burned to make the ancient charcoal approximately 17,130 years ago.

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Which of the following is the type of bond holding K+ and I- ions in KI?A. Ionic bond B. Covalent bond C. Hydrogen bond

Answers

The type of bond holding K+ and I- ions in KI is A. Ionic bond.

An ionic bond is a type of chemical bond that occurs between a metal and a non-metal, where one or more electrons are transferred from the metal to the non-metal. In the case of KI, potassium (K) is a metal and iodine (I) is a non-metal.

Potassium loses one electron to achieve a stable electron configuration, becoming a positively charged ion (K+). Iodine gains one electron to attain stability, forming a negatively charged ion (I-). The electrostatic force of attraction between the oppositely charged ions creates the ionic bond, resulting in the formation of potassium iodide (KI).

In contrast, covalent bonds (B) involve the sharing of electrons between non-metal atoms, and hydrogen bonds (C) are a type of intermolecular force occurring between a hydrogen atom and electronegative atoms like oxygen, nitrogen, or fluorine. Neither of these bonding types are present in KI, as KI is formed through the transfer of electrons between a metal and a non-metal, making it an ionic bond. Hence, the correct answer is option A. ionic bond.

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Which quantity is equivalent to 160 grams of CaF2?


A. 0. 5 moles

B. 2. 0 moles

C. 2. 5 moles

D. 4. 1 moles

Answers

The quantity equivalent to 160 grams of CaF₂ is 2.05 moles of CaF₂. Option C is correct.

To determine the quantity of CaF₂ equivalent to 160 grams, we need to convert the given mass into moles using the molar mass of CaF₂. The molar mass of CaF₂ is 78.07 g/mol (the atomic mass of calcium is 40.08 g/mol and the atomic mass of fluorine is 18.99 g/mol, multiplied by two for the two fluorine atoms).

Calculate the moles of CaF₂: 160 g / 78.07 g/mol = 2.05 moles.

Therefore, the quantity of CaF₂ equivalent to 160 grams is 2.05 moles.

It's important to be able to convert between mass and moles in order to accurately measure and calculate chemical reactions. The molar mass is an important factor in these calculations, as it provides a conversion factor between mass and moles. Option C is correct.

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