Determine [OH−] of a solution that is 0.300 M in HCO3−. (Ka1 for H2CO3 is 4.3×10^−7.) Express your answer in molarity to two significant figures.

Answers

Answer 1

Answer: The concentration of OH− in the solution is 2.07×10^−4 M, to two significant figures.

Explanation:

The HCO3− ion is a weak acid that can undergo the following equilibrium reaction with water:

HCO3− + H2O ⇌ H2CO3 + OH−

where H2CO3 is the conjugate acid of HCO3−. The Ka1 for H2CO3 is given as 4.3×10^−7, which means that the equilibrium constant for the above reaction is:

Ka1 = [H2CO3][OH−] / [HCO3−]

At equilibrium, the concentrations of H2CO3 and HCO3− are related by the equilibrium constant expression:

Ka1 = [H2CO3][OH−] / [HCO3−] = (x)(x) / (0.300 - x)

where x is the concentration of OH− in M at equilibrium. Since Ka1 is a small number, we can make the approximation that x is much smaller than 0.300, so that we can neglect the (0.300 - x) term in the denominator of the above expression. This gives:

Ka1 = x^2 / 0.300

Solving for x, we get:

x = √(Ka1 × 0.300) = √(4.3×10^−7 × 0.300) = 2.07×10^−4 M

Therefore, the concentration of OH− in the solution is 2.07×10^−4 M, to two significant figures.

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Related Questions

determine the molar solubility of copper(i) azide (cun3) in a solution with a ph of 2.690. ignore activities. the sp for cun3 is 4.9×10−9. the a for hn3 is 2.2×10−5.

Answers

The molar solubility of the copper azide (CuN₃) in the solution with the pH of the 2.690 is the  4.1 × 10⁻⁹ M.

The pH = 2.690

[H⁺ ] = 0.0020 M

The equation is as :

HN₃ ⇄ H⁺ + N₃⁻

Ka = [H⁺][N₃⁻]/ [HN₃] = 2.2 × 10⁻⁵

The Ksp value is :

Ksp = [Cu⁺][N₃⁻] = 4.9 × 10⁻⁹

CuN₃(s) + H⁺ --> Cu⁺ + HN₃

Keq = [Cu⁺][HN₃] / [H⁺ ]

Ka = [H⁺][N₃⁻]/ [HN₃]

[H⁺][N₃⁻]/ [HN₃]  = 1/Ka  

Keq = Ksp x 1/Ka

Keq = [Cu⁺][N₃⁻] x [HN₃] /[H+][N₃⁻]

Keq = [Cu⁺][HN₃] / [H⁺]

Keq = 4.9 × 10⁻⁹  / 2.2 × 10⁻⁵

Keq  = 2.23 × 10⁻⁴

Y = molar solubility of CuN₃

Y = [Cu⁺] = [HN₃]

Keq = 2.23 × 10⁻⁴

Keq = Y(Y) / [H⁺]

2.23 × 10⁻⁴ = (Y)(Y) / 7.6 × 10⁻¹⁴

Molar solubility of CuN₃ = 4.1 × 10⁻⁹ M.

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For the Complex III in the electron transport chain:

Complex III step 1: UQH2 is oxidized in a 2 electron process. Cytochrome c is reduced and UQ is reduced to UQH in two 1 electron processes.
Complex III step 2: UQH2 is oxidized in a 2 electron process. Cytochrome c is reduced and UQH is reduced to UQH2 in two 1 electron processes.

The necessary standard reduction potentials are:

UQ + 2H+ + 2e- UQH2 E° = 0.06 V
cyt c (Fe3+) + e- cyt c (Fe2+) E° = 0.254 V
UQ + H+ + e- UQH. E° = 0.03 V
UQH. + H+ + e- UQH2 E° = 0.19 V

Calculate the total redox potential of the complex.

Answers

The total redox potential of Complex III is 0.218 V.

The total redox potential of Complex III can be calculated by adding the reduction potentials of the individual steps involved in the process:

Step 1:

[tex]UQH2 → UQ + 2H+ + 2e- E° = -0.06 V (oxidation)\\cyt c (Fe3+) + e- → cyt c (Fe2+) E° = 0.254 V (reduction)\\UQ + H+ + e- → UQH. E° = 0.03 V (reduction)[/tex]

Net E° for Step 1 = 0.03 + 0.254 - (-0.06) = 0.344 V

Step 2:

[tex]UQH2 → UQH. + H+ + e- E° = -0.19 V (oxidation)\\cyt c (Fe3+) + e- → cyt c (Fe2+) E° = 0.254 V (reduction)\\UQH. + H+ + e- → UQH2 E° = -0.19 V (reduction)[/tex]

Net E° for Step 2 = -0.19 + 0.254 + (-0.19) = -0.126 V

The total redox potential of Complex III is the sum of the net E° values for the two steps:

0.344 V + (-0.126 V) = 0.218 V

Therefore, the total redox potential of Complex III is 0.218 V.

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draw the major monobromination product formed by heating the alkane with bromine. add carbon‑bromine bonds to the predrawn structure.

Answers

The most cases, one product will be formed in greater amounts than the others and will be considered the major product.

How we can carbon‑bromine bonds to the predrawn structure?  

However, I can explain the general reaction and the expected product.

When an alkane, such as methane or ethane, is heated with bromine, a substitution reaction can occur in which one of the hydrogen atoms in the alkane is replaced by a bromine atom. This is called monobromination.

For example, let's consider the reaction between methane and bromine:

[tex]CH4 + Br2 → CH3Br + HBr[/tex]

In this reaction, one of the hydrogen atoms in methane is replaced by a bromine atom, forming methyl bromide ([tex]CH3Br[/tex]) as the major monobromination product.

The same reaction can occur with other alkanes, such as ethane, propane, and butane, but the specific product formed will depend on the structure of the alkane and the reaction conditions.

It is worth noting that the reaction between alkanes and halogens (such as bromine) is typically not very selective, meaning that multiple substitution products can be formed.

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calculate the volume of 0.800 M H2O2 (aq) that the student should add to excess NaOCl(aq) to produce 40.0 mL of O2(g) at 0.988 atm and 298K.

Answers

The student should add 4.03 mL of 0.800 M H2O2 solution to excess NaOCl(aq) to produce 40.0 mL of O2(g) at 0.988 atm and 298K.

The balanced chemical equation for the reaction between hydrogen peroxide (H2O2) and sodium hypochlorite (NaOCl) is:

2 NaOCl + 2 H2O2 → O2 + 2 NaCl + 2 H2O

From the equation, we see that 2 moles of hydrogen peroxide produce 1 mole of oxygen gas. We can use the ideal gas law to calculate the volume of oxygen gas produced:

PV = nRT

where P is the pressure (0.988 atm), V is the volume (40.0 mL = 0.0400 L), n is the number of moles of gas produced, R is the gas constant (0.08206 L·atm/mol·K), and T is the temperature (298 K). Solving for n, we get:

n = PV/RT = (0.988 atm)(0.0400 L)/(0.08206 L·atm/mol·K)(298 K) = 0.00161 mol

Since 2 moles of hydrogen peroxide produce 1 mole of oxygen gas, we need 2 × 0.00161 = 0.00322 moles of hydrogen peroxide. The concentration of the hydrogen peroxide solution is 0.800 M, so we can calculate the volume of solution needed:

V = n/C = 0.00322 mol/0.800 mol/L = 0.00403 L or 4.03 mL

Therefore, the student should add 4.03 mL of 0.800 M H2O2 solution to excess NaOCl(aq) to produce 40.0 mL of O2(g) at 0.988 atm and 298K.

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in the first of this reaction, the concentration of dropped from to . what is the average rate of dissapearance of in that time?

Answers

The average rate of the reaction is 0.00352 M/s. To calculate the average rate of the reaction, we need to use the formula: Average rate = (change in concentration)/(time interval).

In this case, we are given the initial concentration of HBr as 0.600 M and the concentration after 25.0 seconds as 0.512 M. Therefore, the change in concentration is: 0.600 M - 0.512 M = 0.088 M The time interval is also given as 25.0 seconds.

Now we can plug these values into the formula to get: Average rate = (0.088 M)/(25.0 s) Average rate = 0.00352 M/s Therefore, the average rate of the reaction during the first 25.0 seconds is 0.00352 M/s.

The average rate of the reaction is calculated as 0.00352 M/s.

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Note: The question given is incomplete. Here is the complete question.

Question: Consider the reaction: 2 HBr( g) ¡ H2( g) + Br2( g) b. In the first 25.0 s of this reaction, the concentration of HBr dropped from 0.600 M to 0.512 M. Calculate the average rate of the reaction during this time interval.

if using a 3m stock solution of nacl, how much of it would be needed to make a 0.1m solution that totals 0.6 l (or 600 ml)

Answers

You will need 20 ml of the 3M NaCl solution to make a 0.1M solution that totals 0.6L (or 600 ml).

To make a 0.1M solution of NaCl that totals 0.6L (or 600ml), you will need to use the formula:
moles of solute = Molarity x volume of solution in liters
First, we need to calculate how many moles of NaCl we need for this solution:
moles of NaCl = 0.1M x 0.6L
moles of NaCl = 0.06 moles
Next, we need to calculate how much 3M NaCl solution we need to make this 0.1M solution:
moles of solute = Molarity x volume of solution in liters
0.06 moles = 3M x volume of solution in liters
volume of solution in liters = 0.02 L or 20 ml
So, you will need 20 ml of the 3M NaCl solution to make a 0.1M solution that totals 0.6L (or 600 ml).

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A compound is found to contain 64.80 % carbon, 13.62 % hydrogen, and 21.58 % oxygen by weight. To answer the questions, enter the elements in the order presented above 1. What is the empirical formula for this compound? 2. The molecular weight for this compound is 74.14 gmol. What is the molecular formula for this compound? Try Another Version Submit Answer 1 Item attempt remaining 1. How many ATOMS of boron are present in 4.40 moles of boron tribromide? atoms of boron. 2. How many MOLES of bromine are present in 6.12x1022 molecules of boron tribromide? moles of bromine. Submit Answer Iry Another Version 1 Item attempt remaining

Answers

The empirical formula for this compound is C4H10O and molecular weight is 74.14 g/mol

What is the empirical formula and molecular formula for this compound?

The empirical formula for this compound can be determined by converting the percentages to grams and then to moles.

Assuming a 100 g sample, we have:

64.80 g carbon = 5.4 moles

13.62 g hydrogen = 13.5 moles

21.58 g oxygen = 1.35 moles

To find the simplest whole-number ratio of these elements, we divide by the smallest number of moles (1.35):

Carbon: 5.4 / 1.35 = 4

Hydrogen: 13.5 / 1.35 = 10

Oxygen: 1.35 / 1.35 = 1

Therefore, the empirical formula for this compound is C4H10O.

The empirical formula has a molecular weight of (4x12.01 + 10x1.01 + 1x16.00) = 74.14 g/mol, which is the same as the given molecular weight. This means the empirical formula is also the molecular formula.

So the compound is C4H10O.

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How many grams of lactic acid (CH3CHOHCOOH), together with 1.57 g of NaOH, must be used to make 250.0 mL of a lactic acid-lactate ion buffer at pH 3.75?

Answers

Answer :Mass of lactic acid = x = 0.0120 * (total mass - 1.57 g)

Mass of NaOH = y = 0.00906 * (total mass - 1)

Explanation:

To solve this problem, we will use the Henderson-Hasselbalch equation:

pH = pKa + log([A-]/[HA])

where pH is the desired pH of the buffer, pKa is the dissociation constant of lactic acid (3.86), [A-] is the concentration of the lactate ion, and [HA] is the concentration of lactic acid.

We can rearrange this equation to solve for [A-]/[HA]:

[A-]/[HA] = 10^(pH - pKa)

Now, we can use the fact that the buffer is made up of lactic acid and its conjugate base, the lactate ion. Let x be the number of grams of lactic acid we need, and let y be the number of grams of NaOH we need to react with the lactic acid to form the lactate ion. We can write two equations based on the moles of lactic acid and lactate ion in the buffer:

moles of lactic acid = x / molar mass of lactic acid

moles of lactate ion = y / molar mass of lactate ion

We can use these equations to relate the concentrations of lactic acid and lactate ion to their masses:

[Lactic acid] = (x / molar mass of lactic acid) / (volume of buffer)

[Lactate ion] = (y / molar mass of lactate ion) / (volume of buffer)

We know the volume of the buffer is 250.0 mL, so we can substitute this into the above equations. We also know that the total mass of lactic acid and NaOH is x + y + 1.57 g, so we can set up a third equation:

x + y + 1.57 g = total mass

Now, we can solve for x and y using the three equations we have set up. First, we can solve for [A-]/[HA] using the Henderson-Hasselbalch equation:

[A-]/[HA] = 10^(3.75 - 3.86) = 0.754

We know that the ratio of [A-] to [HA] is equal to the ratio of y to x, so we can set up the following equation:

y/x = 0.754

Multiplying both sides by x, we get:

y = 0.754x

Substituting this into the third equation we set up earlier, we get:

x + 0.754x + 1.57 g = total mass

Simplifying, we get:

1.754x + 1.57 g = total mass

We can now solve for x:

x = (total mass - 1.57 g) / 1.754

Substituting the molar masses of lactic acid and lactate ion, we get:

x = (total mass - 1.57 g) / (1.754 * 90.08 g/mol)

x = 0.0120 * (total mass - 1.57 g)

Now that we have solved for x, we can find y using the equation we derived earlier:

y = 0.754x

y = 0.754 * 0.0120 * (total mass - 1.57 g)

y = 0.00906 * (total mass - 1.57 g)

Finally, we can find the masses of lactic acid and NaOH:

Mass of lactic acid = x = 0.0120 * (total mass - 1.57 g)

Mass of NaOH = y = 0.00906 * (total mass - 1)

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what happens when light hits something white? why does it happen?

Answers

Answer: White objects look white because they reflect back all the visible wavelengths of light that shine on them - so the light still looks white to us. Colored objects, on the other hand, reflect back only some of the wavelengths; the rest they absorb.

Explanation:

Calculate the solubility (in g/L) of a generic salt with a formula of A2B, a Ksp of 4.10x10^-11 and a molar mass of 231 g/mol.

Answers

The solubility of A₂B is 5.66x10⁻⁶ g/L.

The solubility (in g/L) of a generic salt with a formula of A₂B and a Ksp of 4.10x10⁻¹¹ can be calculated as follows:

First, we need to write the equation for the dissolution of A₂B:

A₂B(s) ⇌ 2A+(aq) + B2⁻(aq)

The Ksp expression for A2B can be written as follows:

Ksp = [A⁺]²[B2⁻]

where [A⁺] and [B²⁻] are the molar concentrations of the ions in solution.

Since we have 2 moles of A⁺ ions for each mole of A₂B that dissolves, we can express the solubility (in moles/L) of A₂B as follows:

s = [A⁺] = [B²⁻]/2

Substituting this expression into the Ksp equation, we get:

Ksp = (s)²([B²⁻]/2) = (s)²([B²⁻]/4)

Solving for [B²⁻], we get:

[B²⁻] = 4Ksp/s² = 4(4.10x10⁻¹¹)/(231/2)² = 2.45x10⁻⁸ M

Finally, we can convert the molar concentration of B²⁻ to grams per liter by multiplying by its molar mass:

2.45x10⁻⁸ M × 231 g/mol = 5.66x10⁻⁶ g/L

Therefore, the solubility of A2B is 5.66x10⁻⁶ g/L.

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and the table of values given on the right. do you expect this reaction to be spontaneous at room temperature? why?

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Without more information about the specific reaction in question, it is difficult to make a definitive statement about its spontaneity at room temperature.

Why will be expect this reaction to be spontaneous at room temperature?

However, I can explain the concept of spontaneity and how it relates to chemical reactions.

Spontaneity refers to whether a reaction will occur without any external intervention, such as the addition of energy or a catalyst. It is determined by the change in free energy ([tex]ΔG[/tex]) of the system, which is calculated using the equation:

[tex]ΔG = ΔH - TΔS[/tex]

where [tex]ΔH[/tex] is the change in enthalpy (heat content) of the system, T is the temperature in Kelvin, and [tex]ΔS[/tex]is the change in entropy (degree of disorder) of the system.

If [tex]ΔG[/tex] is negative, the reaction is spontaneous and will occur without any external intervention. If [tex]ΔG[/tex] is positive, the reaction is non-spontaneous and will not occur without the addition of energy or a catalyst. If [tex]ΔG[/tex] is zero, the reaction is at equilibrium and there is no net change in the concentrations of reactants and products.

In general, the spontaneity of a reaction depends on the balance between the enthalpy and entropy changes. If the enthalpy change is negative (i.e., the reaction releases heat), the reaction will tend to be spontaneous at low temperatures. If the entropy change is positive (i.e., the reaction increases disorder), the reaction will tend to be spontaneous at high temperatures.

Without knowing the specific values of [tex]ΔH[/tex], ΔS, and T for the reaction in question, it is difficult to say whether it will be spontaneous at room temperature. However, in general, reactions that involve the breaking of strong bonds (such as [tex]C-H[/tex] bonds in alkanes) and the formation of weaker bonds (such as [tex]C-B[/tex]r bonds in alkyl bromides) tend to have positive enthalpy changes, which makes them less likely to be spontaneous. Additionally, the formation of a gas or an aqueous solution (both of which have high entropy) can increase the entropy change and make a reaction more likely to be spontaneous.

In conclusion, the spontaneity of a chemical reaction depends on a complex interplay between enthalpy and entropy changes, as well as the temperature and other factors.

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Give the systematic (IUPAC) name for each moleculeO O|| ||CH3CCH3 CH3CH2CCH2CH3

Answers

The systematic (IUPAC) name for each molecule CH³C(O)CH³ is dimethylmethanal and CH³CH²C(O)CH²CH³ is 2-methylpentanal

For the first molecule, CH³C(O)CH³, the structure represents an aldehyde with two methyl groups bonded to the carbonyl carbon atom. In IUPAC nomenclature, the suffix for aldehydes is "-al." Since there are two methyl groups attached, we name this molecule as "dimethylmethanal" or more commonly known as "acetone."

For the second molecule, CH³CH²C(O)CH²CH³, the structure represents an aldehyde with an ethyl group on one side and a methyl group on the other side of the carbonyl carbon atom. In IUPAC nomenclature, the parent chain is five carbons long and should be named as "pentanal." However, since there is a methyl group attached to the second carbon, the name should indicate its position as well. Therefore, the IUPAC name for this molecule is "2-methylpentanal." The systematic (IUPAC) name for each molecule CH³C(O)CH³ is dimethylmethanal and CH³CH²C(O)CH²CH³ is 2-methylpentanal

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Help me please!


illustrate the example in the given scenario in the box where conduction and convection are applied. Then relate it to the processes occurring in the Earth's internal heat

Answers

Answer:

The explanation why the chocolate bar will soften in your grasp as warmth is getting out of your body. Your body has a more prominent active energy than the chocolate bar, accordingly making a temperature slope. Subsequently, heat energy is moved from your body by means of your hand to the chocolate candy which later melts.

Explanation:

I got it from an expert verified answer

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50 mL of 0.60 M sodium hydroxide neutralized 20 mL of sulfuric acid. Determine the concentration of the acid.

Answers

The balanced chemical equation for the reaction between sodium hydroxide and sulfuric acid is:

2NaOH + H2SO4 → Na2SO4 + 2H2O

From the balanced equation, we can see that 2 moles of NaOH react with 1 mole of H2SO4.

The number of moles of NaOH used is:

0.050 L x 0.60 mol/L = 0.030 mol

Since 2 moles of NaOH react with 1 mole of H2SO4, the number of moles of H2SO4 in 20 mL of solution is:

0.030 mol NaOH x (1 mol H2SO4 / 2 mol NaOH) = 0.015 mol H2SO4

The concentration of the sulfuric acid is:

0.015 mol / 0.020 L = 0.75 M

2. Enter the expression 147N+α, where α is the lowercase Greek letter alpha.

Express your answer as a chemical expression.

3. Enter the chemical equation 2H+(aq)+S2−(aq)→H2S(g).

Express your answer as a chemical equation.

Answers

2. The chemical expression 147N+α is:  147N + α --> 151D + 4He

3. The chemical equation 2H+(aq)+S2−(aq)→H2S(g) is :  2H+ + S2- --> H2S

2. The expression 147N+α represents a nuclear reaction where alpha particle (α) is being emitted from the nucleus of nitrogen-14 (147N). The resulting product after the emission of alpha particle is oxygen-18 (148O).

Nuclear reactions involve the changes in the composition of an atomic nucleus, and they are different from chemical reactions which involve the interactions of electrons between atoms. In a nuclear reaction, the nucleus of an atom is altered, and one or more subatomic particles may be released.

In this case, the emission of an alpha particle from nitrogen-14 nucleus transforms it into oxygen-18 nucleus. An alpha particle consists of two protons and two neutrons, and its emission causes the atomic number of the element to decrease by two and the atomic mass to decrease by four.

Therefore, the chemical expression for the nuclear reaction 147N+α is:

14/7N + 4/2α → 18/8O

3. The chemical equation 2H+(aq)+S2−(aq)→H2S(g) represents the reaction between hydrogen ions (H+) and sulfide ions (S2-) to form hydrogen sulfide gas (H2S).

In aqueous solution, hydrogen ions are hydrated to form hydronium ions (H3O+), which are often represented as H+. Therefore, the reaction can also be written as:

2H3O+(aq) + S2-(aq) → H2S(g) + 2H2O(l)

This is an acid-base reaction where the hydronium ion (H3O+) acts as an acid and the sulfide ion (S2-) acts as a base. The reaction produces a weak acid, hydrogen sulfide, which exists mainly in the gaseous phase and is often recognized by its rotten egg-like odor.

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Round to 4 significant figures
4,567,985

Answers

4,568,000 without scientific notation, as the absence of a decimal reads from right to left, and zeros don’t count before the first non-zero digit.

Example:

1,100 has two significant figures

OR

4.568 x 10^6 with scientific notation. The decimal indicates reading left to right, excluding zeroes before the first digit from the left.
i think the answer is 4,568,000

all chemical activities can be viewed as a series of ____________ between molecules.

Answers

All chemical activities can be viewed as a series of interactions or reactions between molecules.

What is Molecules?

A molecule is the smallest unit of a substance that retains all of the chemical and physical properties of that substance. It is a group of two or more atoms that are held together by chemical bonds. Molecules can be made up of atoms of the same element, such as two oxygen atoms bonded together to form O2, or they can be made up of different elements, such as a water molecule (H2O) made up of two hydrogen atoms and one oxygen atom.

These interactions involve the exchange or sharing of electrons between atoms to form new chemical bonds or break existing ones. Some common types of molecular interactions include acid-base reactions, redox reactions, precipitation reactions, and complexation reactions. These interactions ultimately determine the properties and behavior of chemical substances and are fundamental to our understanding of chemistry.

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The combustion of a piece of paper in the presence of enough oxygen produces: CO2 (g) + H20 (9) CO2 (g) + H2 (9) O2 (g) + H20 (g)

Answers

When a piece of paper undergoes combustion (burning) in the presence of sufficient oxygen, it produces carbon dioxide ([tex]CO_{2}[/tex]) gas and water vapor ([tex]H_{2}O[/tex]).

This is due to the chemical reactions that occur between the paper and the oxygen. The paper contains carbon and hydrogen atoms, which combine with oxygen from the air to form [tex]CO_{2}[/tex] and [tex]H_{2}O[/tex].

It is important to note that the exact amounts of each product formed depend on the amount of oxygen present during combustion.

If there is not enough oxygen, incomplete combustion can occur and produce carbon monoxide (CO) instead of [tex]CO_{2}[/tex].

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Every time you change structure by moving a lone pair into a dobule triple bond what steps must be rpeated?

Answers

When you change the structure of a molecule by moving a lone pair into a double or triple bond, the following steps must be repeated: determine formal charge, checking resonance structures, bond orders, determine geometry, and check for stability.

Determine the formal charge: When a lone pair moves into a double or triple bond, it changes the formal charges of the atoms involved in the bond. You must recalculate the formal charges of all the atoms in the molecule to ensure that they are still stable and satisfy the octet rule.

Check for resonance structures: Moving a lone pair into a double or triple bond can create resonance structures. You must check for these structures and determine which is the most stable. The most stable resonance structure has the lowest formal charge and the fewest formal charges.

Check for bond order: The movement of a lone pair into a double or triple bond changes the bond order of the bond involved. You must recalculate the bond order and determine if the new bond is a single, double or triple bond.

Determine the geometry: Changing the bond order can also change the geometry of the molecule. You must determine the new geometry of the molecule based on the bond angles and the hybridization of the atoms involved.

Check for stability: After changing the structure of the molecule, you must check if the molecule is still stable. The molecule should satisfy the octet rule and have the lowest possible formal charges.

By repeating these steps every time a lone pair is moved into a double or triple bond, you can ensure that the new structure of the molecule is stable and accurate.

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in yeast, alcohol dehydrogenase reduces acetaldehyde to ethanol. calculate the free energy change for this reaction under standard conditions

Answers

The free energy change for the reaction where alcohol dehydrogenase reduces acetaldehyde to ethanol in yeast under standard conditions is -18,686 J/mol.

To calculate the free energy change for the reaction where alcohol dehydrogenase reduces acetaldehyde to ethanol in yeast under standard conditions, we can use the formula:

ΔG° = -RT ln K

Where:
- ΔG° is the standard free energy change
- R is the gas constant (8.314 J/mol K)
- T is the temperature in Kelvin (298 K)
- K is the equilibrium constant for the reaction

The balanced chemical equation for the reaction is:

Acetaldehyde + NADH + H+ → Ethanol + NAD+

The equilibrium constant for this reaction is 2100 M^-1. Therefore, we can plug these values into the equation to obtain:

ΔG° = -8.314 J/mol K x 298 K x ln 2100 M^-1
ΔG° = -8.314 J/mol K x 298 K x 7.65
ΔG° = -18,686 J/mol

Therefore, the free energy change for this reaction under standard conditions is -18,686 J/mol.

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What does it mean to contain a full second energy level?
Why?
Example

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An atom that contains a full second energy level has a full outermost energy level.

Meaning of having a full-second energy level

In chemistry, energy levels (also called electron shells) are fixed distances from the nucleus of an atom where electrons may be found.

When an atom contains a full second energy level, it means that its outermost energy level is full. This makes the atom very stable.

For example, carbon is in the second period, so it has electrons in its second energy level, and it is in the fourth group in the second energy level, so it has 4 electrons.

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you are told that the slower the crystals form, the more pure they are likely to be. why is this?

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When crystals form slowly, they have more time to arrange themselves in an organized and uniform structure. As a result, impurities are more likely to be excluded from the crystal lattice, leading to a higher purity. In contrast, if crystals form quickly, there is not enough time for the impurities to be fully excluded, resulting in a less pure crystal. Therefore, the slower the crystals form, the more time they have to create a regular lattice structure and exclude impurities, leading to a higher level of purity.
Hi! When crystals form slowly, they are more likely to be pure because the slow crystallization process allows for more orderly and precise arrangement of atoms and molecules. This results in fewer impurities being trapped within the crystal structure, leading to higher purity.

When crystals form, they come together in a regular, repeating pattern, creating a solid structure. The speed at which this process occurs is dependent on various factors, including temperature, concentration, and the properties of the solute and solvent involved.

When crystals form slowly, they have more time to arrange themselves in the most stable and energetically favorable configuration possible. This means that the resulting crystal structure is more ordered and less likely to contain impurities or defects.

On the other hand, if crystals form quickly, they may not have enough time to fully establish this optimal configuration, leading to a less pure final product. Additionally, rapid crystallization can create stress within the crystal structure, causing defects such as dislocations or twinning, which can further compromise its purity.

Overall, the rate at which crystals form plays a crucial role in determining their purity. Slow crystallization allows for a more perfect alignment of atoms or molecules, resulting in a more perfect crystal lattice and a more pure final product.

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g thin layer chromatography(tlc) is a specific type of separation technique. inthis particular tlc experiment, what is the mobile phase that will be used? whatis the stationary phase?

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Thin layer chromatography (TLC) is a separation technique commonly used in chemistry to separate and identify different components of a mixture.

In this technique, a stationary phase, which is usually a thin layer of silica gel or alumina coated on a flat plate, is used to separate the mixture. The mobile phase, on the other hand, is the solvent that is allowed to move through the stationary phase carrying the components of the mixture along with it.

In the specific TLC experiment you mentioned, the mobile phase used will depend on the nature of the mixture being separated. Typically, the mobile phase is a solvent or a mixture of solvents that can dissolve the components of the mixture, but not the stationary phase. The mobile phase should be chosen carefully to ensure that the components of the mixture are separated effectively.

As for the stationary phase, it is usually made up of a thin layer of silica gel or alumina coated on a flat plate. This stationary phase provides a large surface area for the mixture to interact with, allowing the components to separate based on their physical and chemical properties.

In summary, thin layer chromatography is a specific type of separation technique that uses a stationary phase and a mobile phase to separate and identify components of a mixture. The mobile phase used in the experiment depends on the nature of the mixture being separated, while the stationary phase is typically a thin layer of silica gel or alumina coated on a flat plate.

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Construct a rough plot of pH versus volume of base for the titration of 25.0 mL of 0.050 M HCN with 0.075 M NaOH

a) What is the pH before any NaOH is added?

b) What is the pH at the halfway point of the titration?

c) What is the pH when 95% of the required NaOH has been added?

Answers

The pH value of the solution before the start of titration is 5,35.

Step 1: The volume of cyanide acid is 25, 0 ml = 0,025 L. the amount concentration of cyanide acid is 0,050 M. The amount concentration of sodium hydroxide is 0,075 M.

Step 2:  To calculate the concentration of hydronium ions in order to calculate the pH value of acid solution, use the chemical reaction of the ICE table

Chemical reaction is given as:

[tex]HCN_{aq}[/tex] ⇄[tex]H_{3} O^{+} _{aq} + CN^{-} _{aq}[/tex]

Step 3: The value of Ka of cyanide acid is 4, [tex]0.10^{-10}[/tex].

Now, the value of x is given by:

[tex]K_{a} = \frac{[H_{3}O^{+}][CN^{-}] }{[HCN]}[/tex]

4, [tex]0.10^{-10} = \frac{x^{2} }{0,050 M - x}[/tex]

[tex]x = 4,47.10^{-6} M[/tex]

Now, pH is calculated as:

[tex]pH = - log [H_{3} O^{+}]\\ = - log (4,47.10^{-6} )\\= 5,35[/tex]

The pH value of the solution before the start of titration is 5,35.

A typical laboratory technique for quantitative chemical analysis to ascertain the concentration of a recognized analyte is titration. A reagent, also known as a titrant or titrator, is created as a standard solution with a specified volume and concentration.

The following is the fundamental titration principle: The sample being studied is given a solution, referred to as a titrant or standard solution. A chemical that reacts with the substance to be tested is present in the titrant in known concentration. Using a burette, the titrant is added.

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The chelator EDTA which binds magnesium, is added to an ATP-dependent reaction. What important role played by magnesium is now absent? OThe oxidation of oxygen atoms on phosphate groups Formation of magnesium phosphate with inorganic phosphate after hydrolysis OThe charge shielding on deprotonated oxygen atoms of ATP or ADP OThe formation of hydrogen bonds with other molecules

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The important role played by magnesium that is now absent when EDTA binds to it in an ATP-dependent reaction is the charge shielding on deprotonated oxygen atoms of ATP or ADP.


When EDTA, a chelator that binds magnesium, is added to an ATP-dependent reaction, it effectively removes magnesium ions from the reaction. Magnesium plays a crucial role in stabilizing the negative charges on deprotonated oxygen atoms of ATP or ADP. Without magnesium, this charge shielding is absent, which can lead to reduced efficiency or inhibition of the ATP-dependent reaction.The important role played by magnesium that is now absent when EDTA is added to an ATP-dependent reaction. The charge shielding on deprotonated oxygen atoms of ATP or ADP.

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the light reactions produce atp and nadph h and this process also results in the release of

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The light reactions produce ATP and NADPH, and this process also results in the release of oxygen.

Here's a step-by-step explanation of how this occurs:

1. Light reactions occur in the thylakoid membranes of chloroplasts in photosynthetic organisms.


2. When light photons are absorbed by pigments like chlorophyll, they excite electrons to a higher energy state.


3. These high-energy electrons are transferred through a series of proteins called the electron transport chain (ETC).


4. As electrons move through the ETC, they release energy, which is used to pump protons (H+) across the thylakoid membrane, creating a proton gradient.


5. This proton gradient drives the enzyme ATP synthase to produce ATP from ADP and inorganic phosphate (Pi).


6. Meanwhile, the electrons are ultimately passed to NADP+ (nicotinamide adenine dinucleotide phosphate) along with a proton (H+), reducing it to NADPH.


7. The loss of electrons from chlorophyll is replenished by splitting water molecules, a process called photolysis. This results in the release of oxygen gas (O2) as a byproduct.

In summary, the light reactions produce ATP and NADPH, and the process results in the release of oxygen.


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The circle at right represents a portion of a mixture of four gases: Gas A (purple), Gas B (brown), Gas C (green), and Gas D: (orange). The circle contains 4 purple spheres, 3 brown spheres, 5 green spheres, and 4 pairs of orange spheres. (a) Which gas has the highest partial pressure? O Gas A has the highest partial pressure O Gas B has the highest partial pressure O Gas C has the highest partial pressure O Gas D has the highest partial pressure ces (b) Which gas has the lowest partial pressure? O Gas A has the lowest partial pressure O Gas B has the lowest partial pressure O Gas C has the lowest partial pressure O Gas D; has the lowest partial pressure (c) If the total pressure is 0.916 atm, what is the partial pressure of D? atm

Answers

(a) Gas C (green) has the highest partial pressure because it has the most spheres in the circle, indicating a larger proportion of the mixture.

(b) Gas A (purple) has the lowest partial pressure because it has the fewest spheres in the circle, indicating a smaller proportion of the mixture.

(c) To find the partial pressure of Gas D (orange), we need to first determine how many individual spheres are present. The circle contains 4 pairs of orange spheres, so there are a total of 8 orange spheres. The total number of spheres in the circle is 4 + 3 + 5 + 8 = 20.

To calculate the partial pressure of Gas D, we can use the formula:

Partial pressure of Gas D = Total pressure x (Number of Gas D spheres / Total number of spheres)

Partial pressure of Gas D = 0.916 atm x (8/20)

Partial pressure of Gas D = 0.3664 atm

Hence, partial pressure will be 0.3664atm.

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write the empirical formula of copper chloride based on the experimental data. express your answer as a chemical formula. is the formula cucl3 reasonable?

Answers

Based on the experimental data, the empirical formula of copper chloride is CuCl2.

The formula CuCl3 is not reasonable because copper chloride typically forms compounds with a 1:1 or 1:2 ratio of copper to chlorine.

To determine the empirical formula of copper chloride based on the experimental data, you'll need to follow these steps:

1. Obtain the mass or percentage composition of each element in the compound, which are copper (Cu) and chlorine (Cl).
2. Convert the mass or percentage composition to moles by dividing each value by their respective atomic masses (Cu: 63.55 g/mol, Cl: 35.45 g/mol).
3. Divide the moles of each element by the smallest mole value obtained in step 2.
4. Round the resulting ratios to the nearest whole number to obtain the mole ratio of each element in the empirical formula.

After performing these steps with your experimental data, you'll arrive at the empirical formula of copper chloride. If the formula CuCl3 is reasonable, the empirical formula you obtain should be CuCl3.

However, without specific data, I cannot confirm if CuCl3 is indeed reasonable.

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. hydrogen cyanide is prepared commercially by the reaction of methane, ch4(g), ammonia, nh3(g), and oxygen, o2(g), at high temperature. the other product is gaseous water. a. write a chemical equation for the reaction. b. what volume of hcn(g) can be obtained from 20.0 l ch4(g), 20.0 l nh3(g), and 20.0 l o2(g)? the volumes of all g

Answers

a) CH₄(g) + NH₃(g) + O₂(g) → HCN(g) + 3H₂O(g) ; b) Volume of HCN(g) that can be obtained from 20.0 L CH₄(g), 20.0 L NH3(g), and 20.0 L O2(g) is 23.4 L.

a. The chemical equation for the reaction of methane, ammonia, and oxygen to form hydrogen cyanide and water is: CH₄(g) + NH₃(g) + O₂(g) → HCN(g) + 3H₂O(g)

b. To determine the volume of HCN(g) that can be obtained from 20.0 LCH₄(g), 20.0 L NH3(g), and 20.0 L O₂ g), we first need to determine the limiting reactant.

The balanced chemical equation shows that for every 1 mole of CH₄, 1 mole of NH₃, and 1 mole of O₂, we can produce 1 mole of HCN. Therefore, the mole ratio of CH₄: NH₃: O₂: HCN is 1:1:1:1.

We can use the ideal gas law to convert the given volumes of CH₄, NH₃, and O2 to moles:

n(CH₄) = PV/RT = (1 atm)(20.0 L)/(0.0821 L•atm/mol•K)(298 K) = 0.965 mol
n(NH₃) = PV/RT = (1 atm)(20.0 L)/(0.0821 L•atm/mol•K)(298 K) = 0.965 mol
n( O₂) = PV/RT = (1 atm)(20.0 L)/(0.0821 L•atm/mol•K)(298 K) = 0.965 mol

Since the mole ratio of the reactants is 1:1:1, the limiting reactant is CH₄ because it has the lowest number of moles.

Therefore, we can only produce 0.965 moles of HCN. To determine the volume of HCN, we can use the ideal gas law again:

V(HCN) = n(HCN)RT/P = (0.965 mol)(0.0821 L•atm/mol•K)(298 K)/(1 atm) = 23.4 L

Therefore, the volume of HCN(g) that can be obtained from 20.0 L CH₄(g), 20.0 L  NH₃(g), and 20.0 L  O₂(g) is 23.4 L.

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what are the configurations of the chiral carbon atoms in this compound? carbon atom number 1 is the carbon containing the aldehyde. (2s,3s,4r)(2s,3r,4s)(2r,3s,4r)(2r,3r,4r)(2s,3s,4s)(2r,3r,4s)(2s,3r,4r)(2r,3s,4s)

Answers

The compound has eight chiral carbon atoms, numbered 2 through 9. The configurations of each chiral carbon atom can be indicated by the stereochemical designations (R) or (S).

Using the numbering system provided, the configurations of the chiral carbon atoms are as follows:

- Carbon atom number 2: (2S)
- Carbon atom number 3: (3S) in configurations (1), (3), (5), and (7), and (3R) in configurations (2), (4), (6), and (8).
- Carbon atom number 4: (4R) in configurations (1), (3), (5), and (7), and (4S) in configurations (2), (4), (6), and (8).
- Carbon atom number 5: (5S) in configurations (1), (2), (5), and (6), and (5R) in configurations (3), (4), (7), and (8).
- Carbon atom number 6: (6R) in configurations (1), (2), (5), and (6), and (6S) in configurations (3), (4), (7), and (8).
- Carbon atom number 7: (7S) in configurations (1), (4), (5), and (8), and (7R) in configurations (2), (3), (6), and (7).
- Carbon atom number 8: (8R) in configurations (1), (4), (5), and (8), and (8S) in configurations (2), (3), (6), and (7).
- Carbon atom number 9: (9S) in configurations (1), (2), (3), and (4), and (9R) in configurations (5), (6), (7), and (8).

Therefore, the configurations of the chiral carbon atoms in this compound are:

(2S,3S,4R,5S,6R,7S,8R,9S) in configuration (1)
(2S,3R,4S,5R,6S,7R,8S,9R) in configuration (2)
(2R,3S,4R,5S,6S,7S,8R,9S) in configuration (3)
(2R,3R,4S,5R,6R,7R,8S,9R) in configuration (4)
(2S,3S,4S,5R,6S,7R,8R,9S) in configuration (5)
(2R,3R,4S,5S,6R,7S,8S,9R) in configuration (6)
(2S,3R,4R,5S,6R,7R,8R,9S) in configuration (7)
(2R,3S,4S,5R,6R,7S,8S,9R) in configuration (8)

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